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Combining in-depth neutron diffraction and systematic bulk studies, we discover that the $\sqrt{5}\times\sqrt{5}$ Fe vacancy order with its associated block antiferromagnetic order is the ground state, with varying occupancy ratio of the…

Strongly Correlated Electrons · Physics 2013-03-20 Wei Bao , G. N. Li , Q. Huang , G. F. Chen , J. B. He , M. A. Green , Y. Qiu , D. M. Wang , J. L. Luo

We have investigated the influence of Ca ions substitution on the structural and superconducting properties of (Nd1-xCax)(Ba1.6La0.4)Cu3Oz system. Magnetization, X-ray diffraction and neutron diffraction studies have been carried out on a…

Superconductivity · Physics 2010-05-14 Amish G. Joshi , R. G. Kulkarni , W. B. Yelon , Ram Prasad , M. R. Gonal

Plate-like single crystals of SrFe2As2 as large as 3x3x0.5 mm3 have been grown out of Sn flux. The SrFe2As2 single crystals show a structural phase transition from a high temperature tetragonal phase to a low temperature orthorhombic phase…

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

Superconductivity · Physics 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

We report the realization of superconductivity by 5d element Ir doping in LaFeAsO, a prototype parent compound of high-temperature iron based superconductors. X-ray diffraction patterns indicate that the material has formed the…

Superconductivity · Physics 2009-08-06 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Zhiyu Zhang , Yanwei Ma

A structural phase transition has been found using electron diffraction technique in PrRu4P12 accompanied by a metal - insulator (M - I) transition (TMI = 60K). Weak superlattice spots appeared at (H, K, L) (H + K + L = 2n + 1; n is an…

Strongly Correlated Electrons · Physics 2009-10-31 C. H. Lee , H. Matsuhata , A. Yamamoto , T. Ohta , H. Takazawa , K. Ueno , C. Sekine , I. Shirotani , T. Hirayama

The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is…

We report the results of our investigations on a polycrystalline sample of Lu$_2$Ir$_3$Si$_5$ which crystallizes in the U$_2$Co$_3$Si$_5$ type structure (Ibam). These investigations comprise powder X-ray diffraction, magnetic…

Strongly Correlated Electrons · Physics 2017-07-26 Yogesh Singh , Dilip Pal , S. Ramakrishnan , A. M. Awasthi , S. K. Malik

DyRh4B4 has been known to crystallize in the primitive tetragonal (pt)-structure and to exhibit a ferromagnetic transition at 12 K, the highest magnetic transition temperature in the entire series of the RRh4B4 materials [1]. We show here…

Superconductivity · Physics 2009-06-13 A. Köhler , G. Behr , G. Fuchs , K. Nenkov , L. C. Gupta

We report systematic investigation of high pressure crystal structures and structural phase transition upto 46 GPa in CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder synchrotron x-ray diffraction experiments and Rietveld analysis of the…

We present thermodynamic, structural and transport measurements on Ba(Fe0.973Cr0.027)2As2 single crystals. All measurements reveal sharp anomalies at ~ 112 K. Single crystal x-ray diffraction identifies the structural transition as a first…

Materials Science · Physics 2009-07-28 S. L. Bud'ko , S. Nandi , N. Ni , A. Thaler , A. Kreyssig , A. Kracher , J. -Q. Yan , A. I. Goldman , P. C. Canfield

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor, Ba1-xKxFe2As2, from x = 0 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. The…

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

Materials Science · Physics 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

The structural origin of Cu+ ions conductivity in Cu6PS5I single crystals is described in terms of structural phase transitions studied by X-ray diffraction, polarizing microscope and calorimetric measurements. Below the phase transition at…

Materials Science · Physics 2009-11-11 A. Gagor , A. Pietraszko , M. Drozd , M. Polomska , D. Kaynts

Neutron diffraction measurements of a high quality single crystal of CaFe2As2 are reported. A sharp transition was observed between the high temperature tetragonal and low temperature orthorhombic structures at TS = 172.5K (on cooling) and…

We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…

Superconductivity · Physics 2017-04-05 Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Si-Qi Wu , Guang-Han Cao

Neutron diffraction has been used to study the lattice and magnetic structures of the insulating and superconducting Rb$_y$Fe$_{1.6+x}$Se$_2$. For the insulating Rb$_{y}$Fe$_{1.6+x}$Se$_2$, neutron polarization analysis and single crystal…

We report the structural and magnetic phase transitions of triclinic Ca10(FeAs)10(Pt3As8). High-resolution X-ray powder diffraction reveals splitting of the in-plane (a,b) lattice parameters at Ts ~ 120 K. Platinum-doping weakens the…

Superconductivity · Physics 2013-03-05 T. Stürzer , G. M. Friederichs , H. Luetkens , A. Amato , H. -H. Klauss , F. Winter , R. Pöttgen , D. Johrendt

The effects of lithium absorption on the crystal structure and electronic properties of IrSi3, a binary silicide with a noncentrosymmetric crystal structure, were studied. X-ray and neutron diffraction experiments revealed that hexagonal…

Superconductivity · Physics 2014-08-27 S. Pyon , K. Kudo , J. Matsumura , H. Ishii , G. Matsuo , M. Nohara , H. Hojo , K. Oka , M. Azuma , V. O. Garlea , K. Kodama , S. Shamoto

We report superconductivity, physical and structural properties of Ir1-xRhxTe2 (0<=x<=0.3). Superconducting transition with maximum Tc~2.6 K appears when the doping content of Rh x is in between 0.15 and 0.3. Further increasing the content…

Superconductivity · Physics 2013-07-29 Hechang Lei , Kefeng Wang , Milinda Abeykoon , Emil Bozin , J. B. Warren , C. Petrovic