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Correlated ab-initio ground-state calculations, using relativistic energy-consistent pseudopotentials, are performed for six II-VI semiconductors. Valence ($ns,np$) correlations are evaluated using the coupled cluster approach with single…

Materials Science · Physics 2009-10-30 Martin Albrecht , Beate Paulus , Hermann Stoll

We present a quantum-classical hybrid algorithm that simulates electronic structures of periodic systems such as ground states and quasiparticle band structures. By extending the unitary coupled cluster (UCC) theory to describe crystals in…

Quantum Physics · Physics 2022-02-16 Nobuyuki Yoshioka , Takeshi Sato , Yuya O. Nakagawa , Yu-ya Ohnishi , Wataru Mizukami

We propose a new treatment of the Hubbard model that is based both on the coherent-potential approximation (CPA) and the virtual-crystal approximation (VCA). It is well known that the equilibrium found using the one-particle CPA Green's…

Strongly Correlated Electrons · Physics 2007-05-23 A. Uldry , R. J. Elliott

The physical behaviour of a class of mesoscopic models for multiphase flows is analyzed in details near interfaces. In particular, an extended pseudo-potential method is developed, which permits to tune the equation of state and surface…

Cellular Automata and Lattice Gases · Physics 2015-06-26 M. Sbragaglia , R. Benzi , L. Biferale , S. Succi , K. Sugiyama , F. Toschi

It is possible to employ virtual decay paths, including two-particle transfer, to calculate the nuclear matrix element of neutrinoless double-beta decay under the closure approximation, in addition to the true double-beta path. In the…

Nuclear Theory · Physics 2016-03-02 Jun Terasaki

The transcorrelated (TC) method performs a similarity transformation on the electronic Schr\"odinger equation via Jastrow factorization of the wave function. This has demonstrated significant advancements in computational electronic…

Fully-nonlocal two-projector norm-conserving pseudopotentials are shown to be compatible with a systematic approach to the optimization of convergence with the size of the plane-wave basis. A new formulation of the optimization is…

Materials Science · Physics 2015-06-16 D. R. Hamann

We present an investigation into the transferability of pseudopotentials (PPs) with a nonlinear core correction (NLCC) using the Goedecker, Teter, and Hutter (GTH) protocol across a range of pure GGA, meta-GGA and hybrid functionals, and…

Chemical Physics · Physics 2023-07-20 Wan-Lu Li , Kaixuan Chen , Elliot Rossomme , Martin Head-Gordon , Teresa Head-Gordon

A new method is presented for obtaining all-electron results from a pseudopotential calculation. This is achieved by carrying out a localised calculation in the region of an atomic nucleus using the embedding potential method of Inglesfield…

Materials Science · Physics 2015-05-14 J. R. Trail , D. M. Bird

The scattering properties of any complex scattering potential, v:R -> C, can be obtained from the dynamics of a particular non-unitary two-level quantum system S_v. The application of the adiabatic approximation to S_v yields a…

Quantum Physics · Physics 2015-03-16 Ali Mostafazadeh

The increasing use of high-throughput density-functional theory (DFT) calculations in the computational design and optimization of materials requires the availability of a comprehensive set of soft and transferable pseudopotentials. Here we…

Materials Science · Physics 2013-12-10 Kevin F. Garrity , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

I introduce Virtual Parameter Sharpening (VPS), an inference-time technique that augments frozen transformer linear layers with dynamic, activation-conditioned low-rank perturbations. Unlike parameter-efficient fine-tuning methods such as…

Machine Learning · Computer Science 2026-02-24 Saba Kublashvili

Classical effective potentials are indispensable for any large-scale atomistic simulations, and the relevance of simulation results crucially depends on the quality of the potentials used. For complex alloys like quasicrystals, however,…

Materials Science · Physics 2009-07-07 Peter Brommer , Franz Gähler

A scheme is developed for creating pseudopotentials for use in correlated-electron calculations. Pseudopotentials for the light elements H, Li, Be, B, C, N, O, and F, are reported, based on data from high-level quantum chemical…

Materials Science · Physics 2014-05-05 J. R. Trail , R. J. Needs

The atomic cluster expansion is a general polynomial expansion of the atomic energy in multi-atom basis functions. Here we implement the atomic cluster expansion in the performant C++ code \verb+PACE+ that is suitable for use in large scale…

Coherent potential approximation (CPA) has widely been used for studying residual resistivity of bulk alloys and electrical conductivity in inhomogeneous systems with structural disorder. Here we revisit the single-site CPA within the…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 M. Ye. Zhuravlev , A. V. Vedyayev , K. D. Belashchenko , E. Y. Tsymbal

The dynamical cluster approximation (DCA) is a systematic extension beyond the single site approximation in dynamical mean field theory (DMFT), to include spatially non-local correlations in quantum many-body simulations of strongly…

Strongly Correlated Electrons · Physics 2013-11-27 Peter Staar , Thomas Maier , Thomas C. Schulthess

The coherent potential approximation (CPA) is extended to describe satisfactorily the motion of particles in a random potential which is spatially correlated and smoothly varying. In contrast to existing cluster-CPA methods, the present…

Disordered Systems and Neural Networks · Physics 2009-10-20 Roland Zimmermann , Christoph Schindler

Due to their diverse nature, the faithful description of excited states within electronic structure theory methods remains one of the grand challenges of modern theoretical chemistry. Quantum Monte Carlo (QMC) methods have been applied very…

Chemical Physics · Physics 2020-06-05 Anthony Scemama , Michel Caffarel , Anouar Benali , Denis Jacquemin , Pierre-François Loos

This paper considers the estimation and inference of the low-rank components in high-dimensional matrix-variate factor models, where each dimension of the matrix-variates ($p \times q$) is comparable to or greater than the number of…

Statistics Theory · Mathematics 2022-10-20 Elynn Y. Chen , Jianqing Fan