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The third law of thermodynamics dictates that the entropy of materials becomes zero as temperature ($T$) approaches zero. Contrarily, glass and other similar materials exhibit nonzero entropy at $T=0$, which contradicts the third law. For…

Statistical Mechanics · Physics 2026-02-25 Koun Shirai

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

Quantum Physics · Physics 2015-03-30 David M. Rogers

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

Von Neumann entropy rate for open quantum systems is, in general, written in terms of entropy production and entropy flow rates, encompassing the second law of thermodynamics. When the open-quantum-system evolution corresponds to a quantum…

Quantum Physics · Physics 2022-01-05 Fabricio Toscano , Gustavo M. Bosyk , Steeve Zozor , Mariela Portesi

Classical thermodynamics treats temperature as a state variable characterizing systems in equilibrium with idealized infinite reservoirs. We argue that this framing, while computationally exact, obscures an essential physical reality: any…

Quantum Physics · Physics 2026-04-14 David Vaknin

Fluid dynamics accompanies with the entropy production thus increases the local temperature, which plays an important role in charged systems such as the ion channel in biological environment and electrodiffusion in capacitors/batteries. In…

Fluid Dynamics · Physics 2017-11-09 Pei Liu , Simo Wu , Chun Liu

The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…

Classical Physics · Physics 2007-05-23 B. Crosignani , P. Di Porto , C. Conti

Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their…

Quantum Physics · Physics 2024-10-07 Kacper Prech , Patrick P. Potts

We consider a finite chain of non-linear oscillators coupled at its ends to two infinite heat baths which are at different temperatures. Using our earlier results about the existence of a stationary state, we show rigorously that for…

chao-dyn · Physics 2015-06-24 Jean-Pierre Eckmann , Claude-Alain Pillet , Luc Rey-Bellet

Based on trajectory dependent path probability formalism in state space, we derive generalized entropy production fluctuation relations for a quantum system in the presence of measurement and feedback. We have obtained these results for…

Statistical Mechanics · Physics 2015-06-04 Shubhashis Rana , Sourabh Lahiri , A. M. Jayannavar

We consider a system of $M$ particles in contact with a heat reservoir of $N\gg M$ particles. The evolution in the system and the reservoir, together with their interaction, are modeled via the Kac's Master Equation. We chose the initial…

Mathematical Physics · Physics 2021-09-01 Federico Bonetto , Rui Han , Michael Loss

The second law of thermodynamics imposes an increase of macroscopic entropy with time in an isolated system. Microscopically, however, the entropy production can be negative for a single, microscopic realization of a thermodynamic process.…

Solar and Stellar Astrophysics · Physics 2018-12-07 Andrei Gorobets , Svetlana Berdyugina

Temperature is an outsider in the laws of motion given by Newton and Einstein and this oversight is the source of the predictions of time-reversal-invariance made by these two great systems of motion. By taking into consideration Planck's…

General Physics · Physics 2012-06-15 Randy Wayne

We calculate the net change in generalized entropy occurring when one carries out the gedanken experiment in which a box initially containing energy $E$, entropy $S$ and charge $Q$ is lowered adiabatically toward a Reissner-Nordstr\"{o}m…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Takeshi Shimomura , Shinji Mukohyama

Landauer's principle, a cornerstone of quantum information and thermodynamics, appears to be violated when the thermal reservoir is replaced by a squeezed thermal state (STS), owing to the additional thermodynamic resources inherently…

Quantum Physics · Physics 2026-05-08 Hao Xu

We review on a recently proposed quantum exception to the second law of thermodynamics. We emphasize that $^4$He superflows, like any other forms of flows, shall carry entropy or heat in a thermal environment. Following that, one can use a…

General Physics · Physics 2016-11-09 Yongle Yu

We propose a mathematical formulation of the zeroth law of thermodynamics and develop a stochastic dynamical theory, with a consistent irreversible thermodynamics, for systems possessing sustained conservative stationary current in phase…

Mathematical Physics · Physics 2014-01-27 Hong Qian

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that…

Quantum Physics · Physics 2021-10-12 Yu-Han Ma , C. L. Liu , C. P. Sun

We consider a theory of quantum thermodynamics with multiple conserved quantities (or charges). To this end, we generalize the seminal results of Sparaciari et al. [PRA 96:052112, 2017] to the case of multiple, in general non-commuting…