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In statistical thermodynamics the 2nd law is properly spelled out in terms of conditioned probabilities. As such it makes the statement, that `entropy increases with time' without preferring a time direction. In this paper I try to explain…

General Physics · Physics 2022-06-27 Domenico Giulini

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

We extend stochastic thermodynamics by relaxing the two assumptions that the Markovian dynamics must be linear and that the equilibrium distribution must be a Boltzmann distribution. We show that if we require the second law to hold when…

Statistical Mechanics · Physics 2021-05-26 Jan Korbel , David H. Wolpert

It is shown that the structure of thermodynamics is "form invariant", when it is derived using maximum entropy principle for various choices of entropy and even beyond equilibrium. By the form invariance of thermodynamics, it is meant that…

Quantum Physics · Physics 2015-11-12 Avijit Misra , Uttam Singh , Manabendra Nath Bera , A. K. Rajagopal

Several comments are given to previous proofs of the generalised second law of thermodynamics: black hole entropy plus ordinary matter entropy never decreases for a thermally closed system. Arguments in favour of its truism are given in the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 S. -T. Sung

For a given topological dynamical system $(X,T)$ over a compact set $X$ with a metric $d$, the "variational principle" states that \begin{equation*} \sup_{\mu}h_\mu(T) = h(T) = h_d(T), \end{equation*} where $h_\mu(T)$ is the…

Dynamical Systems · Mathematics 2016-04-12 André Caldas , Mauro Patrão

We define the entropy S and uncertainty function of a squeezed system interacting with a thermal bath, and study how they change in time by following the evolution of the reduced density matrix in the influence functional formalism. As…

Quantum Physics · Physics 2014-11-18 D. Koks , A. Matacz , B. L. Hu

The dynamics of molecular collisions in a macroscopic body are encoded by the parameter Thermodynamic entropy - a statistical measure of the number of molecular configurations that correspond to a given macrostate. Directionality in the…

Populations and Evolution · Quantitative Biology 2020-05-22 Lloyd Demetrius , Christian Wolf

We improve on our version of the second law of thermodynamics as a deterministic theorem for quantum spin systems in two basic aspects. The first concerns the general statement of the second law: spontaneous changes in an adiabatically…

Quantum Physics · Physics 2026-04-14 Walter F. Wreszinski

Inspired by the second law of thermodynamics, we study the change in subsystem entropy generated by dynamical unitary evolution of a product state in a bipartite system. Working at leading order in perturbative interactions, we prove that…

High Energy Physics - Theory · Physics 2023-08-21 Clifford Cheung , Temple He , Allic Sivaramakrishnan

The time variation of entropy, as an alternative to the variance, is proposed as a measure of the diffusion rate. It is shown that for linear and time-translationally invariant systems having a large-time limit for the density, at large…

Statistical Mechanics · Physics 2013-05-24 Amir Aghamohammadi , Amir H. Fatollahi , Mohammad Khorrami , Ahmad Shariati

In a glassy system different degrees of freedom have well-separated characteristic times, and are described by different temperatures. The stationary state is essentially non-equilibrium. A generalized statistical thermodynamics is…

Disordered Systems and Neural Networks · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

The Second Law of Thermodynamics states that the entropy of a closed system is non-decreasing. Discussing the Second Law in the quantum world poses new challenges and provides new opportunities, involving fundamental…

Quantum Physics · Physics 2016-12-01 A. V. Lebedev , D. Oehri , G. B. Lesovik , G. Blatter

It is shown that the laws of thermodynamics are extremely robust under generalizations of the form of entropy. Using the Bregman-type relative entropy, the Clausius inequality is proved to be always valid. This implies that thermodynamics…

Statistical Mechanics · Physics 2009-11-13 Sumiyoshi Abe , Stefan Thurner

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

Statistical Mechanics · Physics 2017-10-18 Xiangjun Xing

We consider a system of two Brownian particles (say A and B), coupled to each other via harmonic potential of stiffness constant $k$. Particle-A is connected to two heat baths of constant temperatures $T_1$ and $T_2$, and particle-B is…

Statistical Mechanics · Physics 2018-07-04 Deepak Gupta , Sanjib Sabhapandit

We examine the minimization of information entropy for measures on the phase space of bounded domains, subject to constraints that are averages of grand canonical distributions. We describe the set of all such constraints and show that it…

Mathematical Physics · Physics 2019-10-02 Stamatis Dostoglou , Alexander Hughes , Jianfei Xue

In this paper, we investigate the asymptotic stability of finite-dimensional stochastic integrable Hamiltonian systems via information entropy. Specifically, we establish the asymptotic vanishing of Shannon entropy difference (with…

Dynamical Systems · Mathematics 2025-10-28 Chen Wang , Yong Li

D.J. Evans, et al., [Phys. Rev. Lett. 71, 2401 (1993)] discovered a relation, subsequently known as the Fluctuation Theorem (FT), which quantifies the probability of observing fluctuations violating the second law of thermodynamics in…

Statistical Mechanics · Physics 2017-05-19 A. Y. Gorobets , J. M. Borrero , S. Berdyugina

In the present paper, we introduce a natural extension of AKM-topological entropy for noncompact spaces and prove a variational principle which states that the topological entropy, the supremum of the measure theoretical entropies and the…

Dynamical Systems · Mathematics 2008-04-29 Mauro Patrão