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The Legendre transform is an important tool in theoretical physics, playing a critical role in classical mechanics, statistical mechanics, and thermodynamics. Yet, in typical undergraduate or graduate courses, the power of motivation and…

Physics Education · Physics 2015-05-13 R. K. P. Zia , Edward F. Redish , Susan R. McKay

The Legendre transformation is a crucial tool in theoretical physics, known for its symmetry, especially when applied to multivariate functions. In statistical mechanics, ensembles represent the central focus. Leveraging the dimensionless…

Statistical Mechanics · Physics 2024-04-04 Jingxu Wu , Chenjia Li , Zhenzhou Lei , Tuerdi Wumaier , Congyu Li , Yan Wang , Zekun Wang

We present an argument which purports to show that the use of the standard Legendre transform in non-additive Statistical Mechanics is not appropriate. For concreteness, we use as paradigm, the case of systems which are conjecturally…

Statistical Mechanics · Physics 2017-08-02 Nikolaos Kalogeropoulos

This paper offers a pedestrian guide from the fundamental properties of entropy to the axioms of thermodynamics, which are a consequence of the axiom of statistical physics. It also dismantles flawed concepts, such as assigning physical…

Statistical Mechanics · Physics 2024-07-08 Mario Graml , Michael Riedl

Legendre invariant metrics have been introduced in Geometrothermodynamics to take into account the important fact that the thermodynamic properties of physical systems do not depend on the choice of thermodynamic potential from a geometric…

Index transforms with the product of the associated Legendre functions are introduced. Mapping properties are investigated in the Lebesgue spaces. Inversion formulas are proved. The results are applied to solve a boundary value problem in a…

Classical Analysis and ODEs · Mathematics 2019-04-16 Semyon Yakubovich

We show the robustness of the structure of Legendre transform in thermodynamics against the replacement of the standard linear average with the Kolmogorov-Nagumo nonlinear average to evaluate the expectation values of the macroscopic…

Statistical Mechanics · Physics 2022-06-10 A. M. Scarfone , H. Matsuzoe , T. Wada

An extensive table of pairs of functions linked by the Legendre transformation is presented. Many special functions and formulas that are used in the sciences are included in the pairs. Formulations are provided for finding the Legendre…

Classical Analysis and ODEs · Mathematics 2022-08-11 Quinn T. Kolt , Steven J. Kilner , David L. Farnsworth

We investigate the dependence of thermodynamic properties of black holes on the choice of statistical ensemble for a particular class of Einstein-Maxwell-Gauss-Bonnet black holes with cosmological constant. We use partial Legendre…

General Relativity and Quantum Cosmology · Physics 2015-06-15 Hernando Quevedo , Alberto Sanchez , Safia Taj

We address the problem of the foundation of generalized ensembles in statistical physics. The approach is based on Boltzmann's concept of orthodes. These are the statistical ensembles that satisfy the heat theorem, according to which the…

Statistical Mechanics · Physics 2007-09-23 Michele Campisi

Based on the properties of exponential distribution families we analyze the Fisher information of the Gibbs canonical ensemble to construct a new state function for simple systems with no mechanical work. Such a function possesses nice…

Classical Physics · Physics 2015-06-17 Amilcare Porporato

This work extends a recently developed mathematical theory of thermodynamics for Markov processes with, and more importantly, without detailed balance. We show that the Legendre transform in connection to ensemble changes in Gibbs'…

Statistical Mechanics · Physics 2015-10-28 Moisés Santillán , Hong Qian

Nonstationary thermodynamic quantities depend on the full details of nonstationary probability distributions, making them difficult to measure directly in experiments and numerics. We propose a method to infer thermodynamic quantities in…

Statistical Mechanics · Physics 2024-04-04 Naruo Ohga , Sosuke Ito

We study new Legendre transforms in classical mechanics and investigate some of their general properties. The behaviour of the new functions is analyzed under coordinate transformations.When invariance under different kinds of…

General Relativity and Quantum Cosmology · Physics 2013-10-23 Ginés R. Pérez Teruel

Legendre transform between thermodynamic quantities such as the Helmholtz free energy and entropy plays a key role in the formulation of the canonical ensemble. In the standard treatment, the transform exchanges the independent variable…

Statistical Mechanics · Physics 2025-01-24 Ramandeep S. Johal

The inequivalence of thermodynamical ensembles related by a Legendre transformation is manifest in self-gravitating systems and in black hole thermodynamics. Using the Poincare's method of the linear series, we describe the mathematical…

General Relativity and Quantum Cosmology · Physics 2009-09-25 Parentani Renaud

For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that…

Statistical Mechanics · Physics 2007-05-23 R. P. Venkataraman

Combining intuitive probabilistic assumptions with the basic laws of classical thermodynamics, using the latter to express probabilistic parameters in terms of the thermodynamic quantities, we get a simple unified derivation of the…

Probability · Mathematics 2022-05-03 Vassili N. Kolokoltsov

The nonextensive thermodynamic relations are expressed under the assumption of temperature duality, endowing the "physical temperature" and the "Lagrange temperature" in different physical sense. Based on this assumption, two sets of…

Statistical Mechanics · Physics 2016-10-18 Yahui Zheng , Jiulin Du

We geometrically study the Legendre duality relation that plays an important role in statistical physics with the standard or generalized entropies. For this purpose, we introduce dualistic structure defined by information geometry, and…

Statistical Mechanics · Physics 2015-05-13 Atsumi Ohara
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