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We report on the mechanical properties of few-layer black phosphorus (BP) nanosheets, in high vacuum and as a function of time of exposure to atmospheric conditions [1]. BP flakes with thicknesses ranging from 4 to 30 nm suspended over…

We report the fabrication and the electrical characterization of back-gated field effect transistors with black phosphorus channel. We show that the hysteresis of the transfer characteristic, due to intrinsic defects, can be exploited to…

Recent experimental measurements of light absorption in few-layer black phosphorus (BP) reveal a series of high and sharp peaks, interspersed by pairs of lower and broader features. Here, we propose a theoretical model for these excitonic…

Mesoscale and Nanoscale Physics · Physics 2021-05-12 A. Chaves , G. O. Sousa , K. Khaliji , D. R. da Costa , G. A. Farias , Tony Low

Black phosphorus is a layered semiconductor that is intensely researched in view of applications in optoelectronics. In this Letter, we investigate a multi-layer black phosphorus photo-detector that is capable of acquiring high-contrast…

Materials Science · Physics 2016-01-12 Michael Engel , Mathias Steiner , Phaedon Avouris

Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we…

Materials Science · Physics 2014-07-08 Jingsi Qiao , Xianghua Kong , Zhi-Xin Hu , Feng Yang , Wei Ji

The recent renaissance of black phosphorus (BP) as a two-dimensional 2D layered material has generated tremendous interest in its tunable electronic band gap and highly anisotropic transport properties that offer new opportunities for…

Mesoscale and Nanoscale Physics · Physics 2016-03-08 Shan Dong , Anmin Zhang , Kai Liu , Jianting Ji , Y. G. Ye , X. G. Luo , X. H. Chen , Xiaoli Ma , Yinghao Jie , Changfeng Chen , Xiaoqun Wang , Qingming Zhang

The strong interlayer coupling in black phosphorus (BP), arising from wavefunction overlap between layers, is critical for understanding its electronic and optical properties. Here, we utilize terahertz (THz) spectroscopy to study phonon…

Strongly Correlated Electrons · Physics 2025-09-08 Haiyun Huang , Cheng Chen , Yuxin Zhai , Xiu Zhang , Junzhi Zhu , Junyong Wang , Kai Zhang , Qihua Xiong , Haiyun Liu

Discovery of atomically thin black phosphorus (called phosphorene) holds promise to be used as an alternative two-dimensional material to graphene and transition metal dichalcogenides especially as an anode material for lithium-ion…

We report record performance for black phosphorus p-MOSFETs. The devices have locally patterned back gates and 20-nm-thick HfO2 gate dielectrics. Devices with effective gate length, Leff = 1.0 um display extrinsic transconductance, gm, of…

Mesoscale and Nanoscale Physics · Physics 2014-10-01 Nazila Haratipour , Matthew C. Robbins , Steven J. Koester

Black phosphorus stands out from the family of two-dimensional materials as a semiconductor with a direct, layer-dependent bandgap in energy corresponding to the spectral range from the visible to the mid-infrared (mid-IR), as well as many…

Optics · Physics 2017-10-10 Ruoming Peng , Kaveh Khaliji , Nathan Youngblood , Roberto Grassi , Tony Low , Mo Li

Phosphorene, an elemental 2D material, which is the monolayer of black phosphorus, has been mechanically exfoliated recently. In its bulk form, black phosphorus shows high carrier mobility (~10000 cm2/Vs) and a ~0.3 eV direct bandgap.…

Mesoscale and Nanoscale Physics · Physics 2014-10-30 Yexin Deng , Zhe Luo , Nathan J. Conrad , Han Liu , Yongji Gong , Sina Najmaei , Pulickel M. Ajayan , Jun Lou , Xianfan Xu , Peide D. Ye

Field-effect transistors made of wide-bandgap semiconductors can operate at high voltages, temperatures and frequencies with low energy losses, and have been of increasing importance in power and high-frequency electronics. However, the…

Ambipolar black phosphorus MOSFETs with record n-channel extrinsic transconductance are reported. The devices consist of multi-layer black phosphorus aligned to a local back-gate electrode with 10-nm-thick HfO2 gate dielectric. Before…

Mesoscale and Nanoscale Physics · Physics 2015-12-01 Nazila Haratipour , Steven J. Koester

Through infrared spectroscopy, we systematically study the pressure effect on electronic structures of few-layer black phosphorus (BP) with layer number ranging from 2 to 13. We reveal that the pressure-induced shift of optical transitions…

An optical phonon limited velocity model has been employed to investigate high-field transport in a selection of layered 2D materials for both, low-power logic switches with scaled supply voltages, and high-power, high-frequency…

We present polarization-resolved transient transmission measurements on multi-layer black phosphorus. Background free two-color pump-probe spectroscopy measurements are carried out on mechanically exfoliated black phosphorus flakes that…

Materials Science · Physics 2015-08-25 Ryan J. Suess , Mohammad M. Jadidi , Thomas E. Murphy , Martin Mittendorff

The continuous down-scaling of transistors has been the key to the successful development of current information technology. However, with Moore's law reaching its limits, the development of alternative transistor architectures is urgently…

We have fabricated black phosphorus photodetectors and characterized their full spectral responsivity. These devices, which are effectively in the bulk thin film limit, show broadband responsivity ranging from <400 nm to the ~3.8 $\mu$m…

Few-layer black phosphorus (FLBP), a recently discovered two-dimensional semiconductor, has attracted substantial attention in the scientific and technical communities due to its great potential in electronic and optoelectronic…

Chemical doping of bulk black phosphorus is a well-recognized way to reduce surface oxidation and degradation. Here, we report on the fabrication of terahertz frequency detectors consisting of an antenna-coupled field-effect transistor…

Mesoscale and Nanoscale Physics · Physics 2019-03-08 Leonardo Viti , Antonio Politano , Kai Zhang , Miriam Serena Vitiello
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