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In Born-Oppenheimer molecular dynamics (BOMD) simulations based on density functional theory (DFT), the potential energy and the interatomic forces are calculated from an electronic ground state density that is determined by an iterative…

Chemical Physics · Physics 2023-05-03 Anders M. N. Niklasson , Christian F. A. Negre

New, gauge-independent, second-order Lagrangian for the motion of classical, charged test particles is proposed. It differs from the standard, gauge-dependent, first order Lagrangian by boundary terms only. A new method of deriving…

Classical Physics · Physics 2015-06-26 D. Chruscinski , J. Kijowski

A Lagrangian formulation is constructed for particle interpretations of quantum mechanics, a well-known example of such an interpretation being the Bohm model. The advantages of such a description are that the equations for particle motion,…

Quantum Physics · Physics 2017-07-03 Roderick Sutherland

To leverage the redundancy between the electronic structure computed at each step of first-principles molecular dynamics, we present a data-driven modeling framework for Kohn-Sham Density Functional Theory that bypasses the explicit…

Numerical Analysis · Mathematics 2026-02-27 Siu Wun Cheung , Youngsoo Choi , Jean-Luc Fattebert , Jonas Kaufman , Daniel Osei-Kuffuor

Describing the dynamics of nuclei in molecules requires a potential energy surface, which is traditionally provided by the Born-Oppenheimer or adiabatic approximation. However, we also need to assign masses to the nuclei. There, the…

In the one-dimensional stationary case, we construct a mechanical Lagrangian describing the quantum motion of a non-relativistic spinless system. This Lagrangian is written as a difference between a function $T$, which represents the…

Quantum Physics · Physics 2009-11-07 A. Bouda

We present a rigorous formulation of generalized Kohn-Sham density-functional theory. This provides a straightforward Kohn-Sham description of many-body systems based not only on particle-density but also on any other observable. We…

Strongly Correlated Electrons · Physics 2008-02-03 M. Valiev , G. W. Fernando

Microscopic theory of Brownian motion of a particle of mass $M$ in a bath of molecules of mass $m\ll M$ is considered beyond lowest order in the mass ratio $m/M$. The corresponding Langevin equation contains nonlinear corrections to the…

Statistical Mechanics · Physics 2010-01-22 A. V. Plyukhin

A four-dimensional differential Euler-Lagrange equation for continuously distributed materials is derived based on the principle of least action, and instead of Lagrangian, this equation contains the Lagrangian density. This makes it…

General Physics · Physics 2024-05-02 Sergey G. Fedosin

The studies of the generalized Einstein Lagrangian densities without torsion are extended to those of the more generalized Lagrangian densities with torsion. The properties of the more generalized Lagrangian densities are studied…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Fang-Pei Chen

We present a numerical framework for modeling extended hyperelastic bodies based on a Lagrangian formulation of general relativistic elasticity theory. We use finite element methods to discretize the body, then use the semi--discrete action…

General Relativity and Quantum Cosmology · Physics 2023-10-18 Nishita Jadoo , J. David Brown , Charles R. Evans

Modeling many-body quantum systems with strong interactions is one of the core challenges of modern physics. A range of methods has been developed to approach this task, each with its own idiosyncrasies, approximations, and realm of…

Statistical Mechanics · Physics 2018-11-21 Brett Larder , Dirk Gericke , Scott Richardson , Paul Mabey , Thomas White , Gianluca Gregori

We present a macroscopic theory of electroencephalogram (EEG) dynamics based on the laws of motion that govern atomic and molecular motion. The theory is an application of Zwanzig-Mori projection operators. The result is a simple equation…

Neurons and Cognition · Quantitative Biology 2009-07-14 David Hsu , Murielle Hsu

Motivated by a similar approach for Born-Oppenheimer molecular dynamics, this paper proposes an extended "shadow" Lagrangian density for quantum states of superfluids. The extended Lagrangian contains an additional field variable that is…

Numerical Analysis · Mathematics 2021-01-13 Patrick Henning , Anders M. N. Niklasson

We construct the Lagrangian formulation of a micro-structured spinning, dilating and shearing (deformable) test body, moving in arbitrary non-Riemannian backgrounds possessing all geometrical entities of curvature, torsion and…

General Relativity and Quantum Cosmology · Physics 2025-09-19 Damianos Iosifidis

Equations of motion for a general relativistic post-Newtonian Lagrangian approach mainly refer to acceleration equations, i.e. differential equations of velocities. They are directly from the Euler-Lagrangian equations, and usually have…

General Relativity and Quantum Cosmology · Physics 2019-05-28 Dan Li , Yu Wang , Chen Deng , Xin Wu

We analyze the entanglement between electronic and nuclear motions in molecular wave functions, by using different widely used ansatzes in molecular Hamiltonian models (H$^+_2$ in 1D and the Shin-Metiu model); namely, i) Born-Oppenheimer…

Quantum Physics · Physics 2025-11-13 Juan F. P. Mosquera , Jose Luis Sanz-Vicario

We study the classical electrodynamics of extended bodies. Currently, there is no self-consistent dynamical theory of such bodies in the literature. Electromagnetic energy-momentum is not conserved in the presence of charge and some…

Classical Physics · Physics 2021-09-14 P. D. Flammer

We present the construction of an exponentially accurate time-dependent Born-Oppenheimer approximation for molecular quantum mechanics. We study molecular systems whose electron masses are held fixed and whose nuclear masses are…

Mathematical Physics · Physics 2009-10-31 George A. Hagedorn , Alain Joye

The Brownian motion of a particle immersed in a medium of charged particles is considered when the system is placed in magnetic or electric fields. Coming from the Zwanzig-Caldeira-Legget particle-bath model, we modify it so that not only…

Statistical Mechanics · Physics 2020-09-24 Vladimir Lisy , Jana Tothova