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Evidences of a monoclinic phase in unpoled (PbMg1/3Nb2/3O3)1-x-(PbTiO3)x with x=0.35 (PMN-PT 35%) and unpoled (PbZn1/3Nb2/3O3)1-x-(PbTiO3)x with x=0.09 (PZN-PT 9%) are presented from a neutron Rietveld analysis. This monoclinic phase is…

Materials Science · Physics 2009-11-07 J-M. Kiat , Y. Uesu , B. Dkhil , MX. Matsuda , C. Malibert , G. Calvarin

A previously unreported ferroelectric phase has been revealed on a highly homogeneous sample of Pb(Zr0.52Ti0.48)O3 by high-resolution synchrotron x-ray powder diffraction measurements. At ambient temperature the sample has tetragonal…

Materials Science · Physics 2009-10-31 B. Noheda , D. E. Cox , G. Shirane , J. A. Gonzalo , L. E. Cross , S-E. Park , .

A ferroelectric monoclinic phase of space group $Cm$ ($M_A$ type) has been discovered in 0.65Pb(Mg$_{1/3}$Nb$_{2/3})O_3$-0.35PbTiO$_3$ by means of high resolution synchrotron X-ray diffraction. It appears at room temperature in a single…

Materials Science · Physics 2009-11-07 Z. -G. Ye , B. Noheda , M. Dong , D. Cox , G. Shirane

We present here the results of structural studies on multiferroic (1-x)Bi(Ni1/2Ti1/2)O3-xPbTiO3 solid solution using Rietveld analysis on powder x-ray diffraction data in the composition range 0.35 to 0.55. We have determined precisely the…

Materials Science · Physics 2014-07-28 Rishikesh Pandey , Akhilesh Kumar Singh

<001> oriented 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were poled under different electric fields, i.e. Epoling=4 kV/cm and Epoling=13 kV/cm. In addition to the temperature-dependent dielectric constant measurement, X-ray diffraction…

Materials Science · Physics 2009-11-07 Ke-Pi Chen , Xiao-Wen Zhang , Hao-Su Luo

Structural phase transformations of [110] electric field cooled Pb(Mg1/3Nb2/3)O3-30%PbTiO3 (PMN-30%PT) crystals have been performed by x-ray diffraction in a field-cooled (FC) condition. A phase sequence of…

Materials Science · Physics 2009-11-11 Hu Cao , Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , Guangyong Xu , Gen Shirane

A monoclinic phase was recently discovered near the morphotropic phase boundary in several high-performance piezoelectric perovskite solid solutions, but its properties have not been reported. In this paper the dielectric, piezo- and…

Materials Science · Physics 2016-08-31 A. A. Bokov , Z. -G. Ye

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

Materials Science · Physics 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

Neutron and x-ray diffraction techniques have been used to study the competing long and short-range polar order in the relaxor ferroelectric Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) under a [111] applied electric field. Despite reports of a…

Materials Science · Physics 2009-11-13 C. Stock , Guangyong Xu , P. M. Gehring , H. Luo , X. Zhao , H. Cao , J. F. Li , D. Viehland , G. Shirane

Polarization hysteresis loops, x-ray diffraction (XRD) and temperature dependent dielectric constant under different electric fields for <110> oriented 0.7 Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were measured. The field-induced phase…

Materials Science · Physics 2007-05-23 Ke-Pi Chen , Xiao-Wen Zhang , Fei Fang , Hao-Su Luo

Information about the crystal structures in the range of morphotropic phase boundary of ferroelectric perovskite solid solutions is important for understanding their intricate properties which result in wide opportunities for practical…

Materials Science · Physics 2025-11-04 Alexei A. Bokov , Haiyan Guo , Zuo-Guang Ye

The domain structure of (1-x)Pb(Mg1/3Nb2/3)O3- xPbTiO3 single crystals with composition x ~ 0.33 in the range of the morphotropic phase boundary (MPB) was studied. Based on the analysis of spontaneous strain compatibility and charge of…

Materials Science · Physics 2009-11-10 A. A. Bokov , Z. -G. Ye

Properties of Pb(Zr_{1-x}Ti_x)O_3 (PZT) for compositions x near the morphotropic phase boundary and under an electric field are simulated using an ab-initio based approach. Applying an electric field of [111] orientation to tetragonal PZT…

Materials Science · Physics 2009-11-07 L. Bellaiche , A. Garcia , David Vanderbilt

The origin of ultrahigh piezoelectricity in the relaxor ferroelectric PbZn1/3Nb2/3O3-PbTiO3 was studied with an electric field applied along the [001] direction. The zero-field rhombohedral R phase starts to follow the direct polarization…

Materials Science · Physics 2009-10-31 B. Noheda , D. E. Cox , G. Shirane , S-E. Park , L. E. Cross , Z. Zhong

Solid solution BiFe1-xCoxO3 shows anti-ferromagnetic order and pyroelectric order, simultaneously. It has been known that BiFe1-xCoxO3 exhibits a structural phase transition between monoclinic and tetragonal phases as x increases. This…

Materials Science · Physics 2021-12-15 Hiroshi Katsumoto , Kunihiko Yamauchi , Tamio Oguchi

The successful synthesis of few-layer CrI3 has opened new avenues for research in two-dimensional magnetic materials. Owing to its simple crystal structure and excellent physical properties, layered CrI3 has been extensively studied in…

Materials Science · Physics 2026-01-09 Xianzhe Zhu , Pu Liu , Wence Ding , Benhu Zhou , Xiaoying Zhou , Guanghui Zhou

We combine high-pressure x-ray diffraction, high-pressure Raman scattering, and optical microscope to investigate a series of PMN-xPT solid solutions (x=0.2, 0.3, 0.33, 0.35, 0.37, 0.4) in diamond anvil cells up to 20 GPa at 300 K. The…

We have studied electric-field-induced symmetry lowering in the tetragonal (001)-oriented heteroepitaxial (Ba$_{0.8}$Sr$_{0.2}$)TiO$_3$ thin film deposited on (001)MgO substrate. Polarized micro-Raman spectra were recorded from the film…

Materials Science · Physics 2015-05-20 A. S. Anokhin , Yu. I. Yuzyuk , Yu. I. Golovko , V. M. Mukhortov , M. El Marssi

Recently a new monoclinic phase in the PbZr(1-x)TixO3 ceramic system has been reported by Noheda et al. for the composition x= 0.48. In the present work, samples with Ti contents of x= 0.47 and 0.50, which are both tetragonal below their…

Materials Science · Physics 2007-05-23 B. Noheda , J. A. Gonzalo , A. Caballero , C. Moure , D. E. Cox , G. Shirane

The symmetric studies on the structure-property relationship of the unpoled and poled states of 0.67BiFeO3-0.33BaTiO3 (0.67BF-0.33BT) were conducted to understand the origin of the morphotropic phase boundary (MPB) in BF-BT. A typical…

Materials Science · Physics 2020-03-24 Yongxing Wei , Jiahao Shen , Chenxing Bai , Changqing Jin , Weitong Zhu , Ye Tian , Gang Xu
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