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Electric field dependent mechanical properties of relaxor ferroelectric material Pb(Mn1/3Nb2/3)O3-PbTiO3 are investigated with the nanoindentation technique. Giant electric-field-tunable apparent elastic modulus (up to -39%), hardness (-9%…

Mesoscale and Nanoscale Physics · Physics 2014-02-12 Hao Zhou , Yongmao Pei , Faxin Li , Haosu Luo , Daining Fang

Through infrared spectroscopy, we systematically study the pressure effect on electronic structures of few-layer black phosphorus (BP) with layer number ranging from 2 to 13. We reveal that the pressure-induced shift of optical transitions…

Optical and electronic properties of black phosphorus strongly depend on the number of layers and type of stacking. Using first-principles calculations within the framework of density functional theory, we investigate the electronic…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 Cem Sevik , John R. Wallbank , Oguz Gulseren , Francois M. Peeters , Deniz Cakır

In order to understand the relation of strain and material properties, both a microscopic model connecting a given strain to the displacement of atoms, and a macroscopic model relating applied stress to induced strain, are required.…

Mesoscale and Nanoscale Physics · Physics 2016-08-11 Daniel Midtvedt , Alexander Croy

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Andrey Chaves , W. Ji , J. Maassen , T. Dumitrica , T. Low

We have performed accurate ab initio total energy calculations using the full-potential linearized augmented plane wave (FP-LAPW) method with the generalized gradient approximation (GGA) for the exchange-correlation potential to…

Materials Science · Physics 2009-11-13 I. R. Shein , A. L. Ivanovskii

We provide a tight-binding model parametrization for black phosphorus (BP) with an arbitrary number of layers. The model is derived from partially self-consistent $GW_0$ approach, where the screened Coulomb interaction $W_0$ is calculated…

Materials Science · Physics 2015-08-19 A. N. Rudenko , Shengjun Yuan , M. I. Katsnelson

Most recently, a brand new phosphorus allotrope called green phosphorus has been predicted, which has a direct band gap up to 2.4 eV, and its single-layer form termed green phosphorene shows high stability. Here the mechanical properties…

Materials Science · Physics 2018-06-18 Guang Yang , Tianxing Ma , Xihong Peng

Black phosphorus (BP) is a two-dimensional layered material composed of phosphorus atoms. Recently, it was demonstrated that external perturbations such as an electric field close the band gap in few-layer BP, and can even induce a band…

Mesoscale and Nanoscale Physics · Physics 2019-03-11 Jiho Jang , Seongjin Ahn , Hongki Min

We propose here a two-dimensional material based on a single layer of violet or Hittorf's phosphorus. Using first-principles density functional theory, we find it to be energetically very stable, comparable to other previously proposed…

Materials Science · Physics 2016-06-13 Georg Schusteritsch , Martin Uhrin , Chris J. Pickard

The electronic structure and functionality of 2D materials is highly sensitive to structural morphology, opening the possibility for manipulating material properties, but also making predictable and reproducible functionality challenging.…

Mesoscale and Nanoscale Physics · Physics 2022-10-26 Prakriti P. Joshi , Ruiyu Li , Joseph L. Spellberg , Liangbo Liang , Sarah B. King

Thermal conductivity of single layer black phosphorus (BP) is investigated by combining density functional calculations and Peierls-Boltzmann transport equation. Differing from isotropic and divergent thermal conductivities in…

Materials Science · Physics 2015-02-06 Liyan Zhu , Gang Zhang , Baowen Li

The energy bandgap is an intrinsic character of semiconductors, which largely determines their properties. The ability to continuously and reversibly tune the bandgap of a single device during real time operation is of great importance not…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 Shi-Li Yan , Zhi-Jian Xie , Jian-Hao Chen , Takashi Taniguchi , Kenji Watanabe

Using an innovative combination of multi-beam-optical stress-sensor (MOSS) curvature and X-ray diffraction (XRD) techniques, the Young's modulus (E) of polycrystalline MAPbI3 metal-halide perovskite (MHP) thin films attached to Si…

The elastic property of membranes self-assembled from AB diblock and ABA triblock copolymers, as coarse-grained model of lipids and the bolalipids, are studied using the self-consistent field theory (SCFT). Specifically, solutions of the…

Soft Condensed Matter · Physics 2019-05-17 Rui Xu , Ashkan Dehghan , An-Chang Shi , Jiajia Zhou

Black phosphorus (BP) has emerged as a promising material candidate for next generation electronic and optoelectronic devices due to its high mobility, tunable band gap and highly anisotropic properties. In this work, polarization resolved…

Based on experiments and 3-D simulations, we show that a soft elastic film during adhesion and debonding from a rigid flat surface undergoes morphological transitions to pillars, labyrinths and cavities, all of which have the same lateral…

Soft Condensed Matter · Physics 2009-11-11 Manoj Gonuguntla , Ashutosh Sharma , Jayati Sarkar , Subash A. Subramanian , Moniraj Ghosh , Vijay Shenoy

We present a theory for the elasticity of cross-linked stiff polymer networks. Stiff polymers, unlike their flexible counterparts, are highly anisotropic elastic objects. Similar to mechanical beams stiff polymers easily deform in bending,…

Soft Condensed Matter · Physics 2007-11-26 C. Heussinger , B. Schaefer , E. Frey

Stacking two-dimensional (2D) materials into multi-layers or heterostructures, known as van der Waals (vdW) epitaxy, is an essential degree of freedom for tuning their properties on demand. Few-layer black phosphorus (FLBP), a material with…

Materials Science · Physics 2016-02-17 Zhi-Xin Hu , Xianghua Kong , Jingsi Qiao , Bruce Normand , Wei Ji