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We report on hydrogen adsorption and desorption on titanium-covered graphene in order to test theoretical proposals to use of graphene functionalized with metal atoms for hydrogen storage. At room temperature titanium islands grow with an…

Chemical Physics · Physics 2013-12-06 Torge Mashoff , Makoto Takamura , Shinichi Tanabe , Hiroki Hibino , Fabio Beltram , Stefan Heun

Poor quality interfaces between metal and graphene cause non-linearity and impair the carrier mobility in graphene devices. Here, we use aberration corrected scanning transmission electron microscopy to observe hexagonally close-packed Ti…

Mesoscale and Nanoscale Physics · Physics 2023-09-25 Georg Zagler , Alberto Trentino , Kimmo Mustonen , Clemens Mangler , Jani Kotakoski

We present detailed Raman studies of graphene deposited on gallium nitride nanowires with different variations in height. Our results show that different density and height of nanowires being in contact with graphene impact graphene…

Single layer graphene islands with a typical diameter of several nanometers were grown on a Pt (111) substrate. Scanning tunneling microscopy (STM) analysis showed most of islands are hexagonally shaped and the zigzag-type edge predominates…

Mesoscale and Nanoscale Physics · Physics 2011-01-21 Mayu Yamamoto , Seiji Obata , Koichiro Saiki

Titanium (Ti) is an adhesion and contact metal commonly used in nanoelectronics and two-dimensional (2D) materials research. However, when Ti is deposited on graphene (Gr), we obtain dramatically different film morphology depending on the…

The effects of Ga+ ion irradiation and high temperature annealing on behavior of nanocrystalline graphene directly grown on quartz and sapphire are presented. It is shown that nanocrystalline graphene stands fairly high doses of ion…

Mesoscale and Nanoscale Physics · Physics 2015-02-23 Maria Edera , Alexander M. Zaitsev

We use low-energy electron microscopy to investigate how graphene grows on Cu(111). Graphene islands first nucleate at substrate defects such as step bunches and impurities. A considerable fraction of these islands can be rotationally…

Materials Science · Physics 2011-10-20 S. Nie , J. M. Wofford , N. C. Bartelt , O. D. Dubon , K. F. McCarty

Graphene, a hexagonal sheet of $sp^2$-bonded carbon atoms, has extraordinary properties which hold immense promise for future nanoelectronic applications. Unfortunately, the popular preparation methods of micromechanical cleavage and…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Andrew Zangwill , Dimitri D. Vvedensky

We have developed a novel method for crystalline hydrogenation of graphene on the nanoscale. Molecular hydrogen was physisorbed at 5 K onto pristine graphene islands grown on Cu(111) in ultrahigh vacuum. Field emission local to the tip of a…

Mesoscale and Nanoscale Physics · Physics 2017-06-06 S. J. Tjung , S. M. Hollen , G. A. Gambrel , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

Many of the proposed future applications of graphene require the controlled introduction of defects into its perfect lattice. Energetic ions provide one way of achieving this challenging goal. Single heavy ions with kinetic energies in the…

Materials Science · Physics 2010-09-27 S. Akcöltekin , H. Bukowska , T. Peters , O. Osmani , I. Monnet , I. Alzaher , B. Ban d'Etat , H. Lebius , M. Schleberger

Being a true two-dimensional crystal, graphene has special properties. In particular, a point-like defect in graphene may have effects in the long range. This peculiarity questions the validity of using a supercell geometry in an attempt to…

Materials Science · Physics 2015-06-05 Philippe Lambin , Hakim Amara , François Ducastelle , Luc Henrard

Crystallographic defects play a key role in determining the properties of crystalline materials. The new class of two-dimensional materials, foremost graphene, have enabled atomically resolved studies of defects, such as vacancies, grain…

Materials Science · Physics 2015-06-22 Ossi Lehtinen , Nilesh Vats , Gerardo Algara-Siller , Pia Knyrim , Ute Kaiser

Graphene forms from a relatively dense, tightly-bound C-adatom gas, when elemental C is deposited on or segregates to the Ru(0001) surface. Nonlinearity of the graphene growth rate with C adatom density suggests that growth proceeds by…

Materials Science · Physics 2010-12-14 E. Loginova , N. C. Bartelt , P. J. Feibelman , K. F. McCarty

A constant height of gallium nitride (GaN) nanowires with graphene deposited on them is shown to have a strong enhancement of Raman scattering, whilst variable height nanowires fail to give such an enhancement. Scanning electron microscopy…

As the only icy satellite with a thick atmosphere and liquids on its surface, Titan represents a unique end-member to study the impact cratering process. Unlike craters on other Saturnian satellites, Titan's craters are preferentially…

Earth and Planetary Astrophysics · Physics 2023-06-12 Shigeru Wakita , Brandon C. Johnson , Jason M. Soderblom , Jahnavi Shah , Catherine D. Neish

We report nanocrystalline carbon impurities coexisting with graphene synthesized via chemical vapor deposition (CVD) on platinum. We observe micron-size island-like impurity layers, which can easily be mistaken for second graphene layers in…

Mesoscale and Nanoscale Physics · Physics 2014-08-04 Jinglei Ping , Michael S. Fuhrer

Graphene grown by chemical vapour deposition is transferred on top of flat gold nanoislands and characterized by scanning tunnelling microscopy (STM) and atomic force microscopy (AFM). Graphene bubbles are formed with lateral dimensions…

Mesoscale and Nanoscale Physics · Physics 2016-09-15 András Pálinkás , György Molnár , Chanyong Hwang , László Péter Biró , Zoltán Osváth

The formation of atomic nanoclusters on suspended graphene sheets have been investigated by employing a Molecular dynamics simulation at finite temperature. Our systematic study is based on temperature dependent Molecular dynamics…

Materials Science · Physics 2009-11-13 M. Neek-Amal , Reza Asgari , M. R. Rahimi Tabar

Hydrogen adsorption on graphene can be increased by functionalization with Ti. This requires dispersing Ti islands on graphene as small and dense as possible, in order to increase the number of hydrogen adsorption sites per Ti atom. In this…

Materials Science · Physics 2020-02-17 Yuya Murata , Stefano Veronesi , Dongmok Whang , Stefan Heun

One-dimensional defects in graphene have strong influence on its physical properties, such as electrical charge transport and mechanical strength. With enhanced chemical reactivity, such defects may also allow us to selectively…

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