Related papers: Restructuring and aging in a capillary suspension
The addition of small amounts of a secondary fluid to a suspension can, through the attractive capillary force, lead to particle bridging and network formation. The capillary bridging phenomenon can be used to stabilize particle suspensions…
The influence of an applied shear field on the dynamics of an aging colloidal suspension has been investigated by the dynamic light scattering determination of the density autocorrelation function. Though a stationary state is never…
Cracking of suspensions during drying is a common problem. While additives, e.g. binders and surfactants, can mitigate this problem, some applications, such as printing conductive pastes or sintering green bodies, do not lend themselves to…
In this work, we investigate the ageing behavior of soft glassy solids of aqueous suspension of laponite under shear flow. We observe that when an imposed time is normalized by a dominating relaxation time of the system, the rheological…
We present here a microscopic study of the effect of shear on a dense purely repulsive colloidal suspension. We use Multispeckle Diffusing Wave Spectroscopy to monitor the transient motions of colloidal particles after being submitted to an…
Hypothesis: Lateral accumulation and film defects during drying of hard particle coatings is a common problem, typically solved using polymeric additives and surface active ingredients, which require further processing of the dried film.…
Liquid-liquid-solid systems are becoming increasingly common in everyday life with many possible applications. Here, we focus on a special case of such liquid-liquid-solid systems, namely, capillary suspensions. These capillary suspensions…
In this paper, ageing behavior of suspensions of laponite with varying salt concentration is investigated using rheological tools. It is observed that the ageing is accompanied by an increase in the complex viscosity. The succeeding creep…
The aging dynamics after shear rejuvenation in a glassy, charged clay suspension have been investigated through dynamic light scattering (DLS). Two different aging regimes are observed: one is attained if the sample is rejuvenated before…
We study the solid mechanical properties of several thixotropic suspensions as a function of the shear stress history applied during their flow stoppage and their aging in their solid state. We show that their elastic modulus and yield…
Dense suspensions of soft colloidal particles display a broad range of physical and rheological properties which are still far from being fully understood. To elucidate the role of deformability on colloidal flow, we employ computer…
We investigate the nonlinear rheological behavior of colloidal suspensions of Laponite, a synthetic clay, driven by a steady and homogeneous shear strain. We show that the external drive leads to a drastic slowing down of the aging dynamics…
Oscillatory shear has been widely used to study the rheological properties of suspensions under unsteady shear. Furthermore, recent works have shown that oscillatory flows can improve the flowability of dense suspensions. While most studies…
Our understanding of both structure and dynamics of adsorbed liquids heavily relies on the capillary wave Hamiltonian, but a thorough test of this model is still lacking. Here we study the capillary wave fluctuations of a liquid film with…
Colloidal suspensions that are out of thermodynamic equilibrium undergo physical aging wherein their structure evolves to lower the free energy. In aqueous suspension of Laponite, physical aging accompanies increases of elastic and viscous…
The displacement of a suspension of particles by an immiscible fluid in a capillary tube or in a porous media is a canonical configuration that finds application in a large number of natural and industrial applications, including water…
In this work, we study ageing behavior of aqueous laponite suspension, a model soft glassy material, in creep. We observe that viscoelastic behavior is time dependent and is strongly influenced by the deformation field; the effect is known…
Flexible rings and rectangle structures floating at the surface of water are prone to deflect under the action of surface pressure induced by the addition of surfactant molecules on the bath. While the frames of rectangles bend inward or…
We investigate shear strength properties of wet granular materials in the pendular state (i.e. the state where the liquid phase is discontinuous) as a function of water content. Sand and glass beads were wetted and tested in a direct shear…
Hypothesis: Aging in colloidal suspensions manifests as a reduction in kinetic freedom of the colloids. In aqueous suspensions of charged colloids, the role of inter-particle electrostatics interactions on the aging dynamics is well…