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We study the impact of electrode band structure on transport through single-molecule junctions by measuring the conductance of pyridine-based molecules using Ag and Au electrodes. Our experiments are carried out using the scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2023-07-19 Olgun Adak , Richard Korytár , Andrew Y. Joe , Ferdinand Evers , Latha Venkataraman

We investigate the striking absence of strong localisation observed in mesoscopic two-dimensional electron gases (2DEGs) (Baenninger et al 2008 Phys. Rev. Lett. 100 1016805, Backes et al 2015 Phys. Rev. B 92 235427) even when their…

Mesoscale and Nanoscale Physics · Physics 2016-05-25 Dirk Backes , Richard Hall , Michael Pepper , Harvey Beere , David Ritchie , Vijay Narayan

Ab initio calculations of phenyl dithiol connected to Au, Ag, Pd, and Pt electrodes are performed using non-equilibrium Green's functions and density functional theory. For each metal, the properties of the molecular junction are considered…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 John W. Lawson , Charles W. Bauschlicher

Molybdenum disulfide is a novel two-dimensional semiconductor with potential applications in electronic and optoelectronic devices. However, the nature of charge transport in back-gated devices still remains elusive as they show much lower…

The role of multimode vibrational dynamics in electron transport through single molecule junctions is investigated. The study is based on a generic model, which describes charge transport through a single molecule that is attached to metal…

Mesoscale and Nanoscale Physics · Physics 2010-10-26 R. Härtle , C. Benesch , M. Thoss

In dilute gases, transport properties such as the thermal conductivity, self-diffusion, and viscosity are significantly affected by interatomic collisions, which are determined by the potential form. This study explores these transport…

Statistical Mechanics · Physics 2025-10-17 Alejandro Alés , Juan Ignacio Cerato , Leandro Marchioni , Miguel Hoyuelos

We theoretically investigate the transport properties of a molecule embedded in one arm of a mesoscopic Aharonov-Bohm interferometer. Due to the presence of phonons the molecule level position ($\epsilon_d$) and the electron-electron…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Jong Soo Lim , Rosa Lopez , Gloria Platero , Pascal Simon

We present a systematic ab-initio study of the length dependence of the thermopower in molecular junctions. The systems under consideration are small saturated and conjugated molecular chains of varying length attached to gold electrodes…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon

We investigate molecular adsorption doping by electron withdrawing NO2 and electron donating NH3 on epitaxial graphene grown on C-face SiC substrates. Amperometric measurements show conductance changes upon introduction of molecular…

Materials Science · Physics 2012-01-24 B. K. Daas , W. K. Nomani , K. M. Daniels , T. S. Sudarshan , Goutam Koley , M. V. S. Chandrashekhar

Electron-electron (e-e) collisions can impact transport in a variety of surprising and sometimes counterintuitive ways. Despite strong interest, experiments on the subject proved challenging because of the simultaneous presence of different…

Charge and heat transport through a single molecule tunnel-coupled to external normal electrodes have been studied. The molecule with sufficiently strong interaction between lectrons and vibrational internal degrees of freedom can be…

Mesoscale and Nanoscale Physics · Physics 2012-04-16 Karol Izydor Wysokinski

We report that the electrical conductance between closely-spaced gold electrodes in acid solution can be turned from off [insulating; I] to on [conducting; C] to off again by monotonically sweeping a gate voltage applied to the solution. We…

Materials Science · Physics 2009-11-10 Jacob E. Grose , Burak Ulgut , Abhay N. Pasupathy , D. C. Ralph , Hector D. Abruna

We propose a model for a molecular junction with internal anharmonic torsional vibrations interacting with an electric current. The Wangsness-Bloch-Redfield master equation approach is used to determine the stationary reduced density matrix…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ivan A. Pshenichnyuk , Martin Čížek

We consider exciton- and light-induced current in molecular nanojunctions. Using a model comprising a two two-level sites bridge connecting free electron reservoirs we show that the exciton coupling between the sites of the molecular bridge…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 B. D. Fainberg , P. Hanggi , S. Kohler , A. Nitzan

We propose a new approach to coherent control of transport via molecular junctions, which bypasses several of the hurdles to experimental realization of optically manipulated nanoelectronics noted in the previous literature. The method is…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Boris D. Fainberg , Tamar Seideman

Transport measurements have revealed several exotic electronic properties of graphene. The possibility to influence the electronic structure and hence control the conductivity by adsorption or doping with adatoms is crucial in view of…

The simplicity of single-molecule junctions based on direct bonding of a small molecule between two metallic electrodes make them an ideal system for the study of fundamental questions related to molecular electronics. Here we study the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 O. Tal , M. Kiguchi , W. H. A. Thijssen , D. Djukic , C. Untiedt , R. H. M. Smit , J. M. van Ruitenbeek

Illumination is performed at low temperature on dopant-free two-dimensional electron gases (2DEGs) of varying depths, under unbiased (gates grounded) and biased (gates at a positive or negative voltage) conditions. Unbiased illuminations in…

We study dynamic nonequilibrium electron charging phenomena in ballistic molecular devices at room temperature that compromise their response to bias and whose nature is evidently distinguishable from static Schottky-type potential…

Mesoscale and Nanoscale Physics · Physics 2008-05-13 Ioannis Deretzis , Antonino La Magna

Electrophoretic (EP) mobility reversal is commonly observed for strongly charged macromolecules in multivalent salt solutions. This curious effect takes place, e.g., when a charged polymer, such as DNA, adsorbs excess counterions so that…

Soft Condensed Matter · Physics 2023-03-28 Xiang Yang , Sahin Buyukdagli , Alberto Scacchi , Maria Sammalkorpi , Tapio Ala-Nissila
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