Related papers: Entropic pressure in lattice models for polymers
The equilibrium partitioning of linear polymer chains into flexible polymer networks is governed by intricate entropic constraints arising from configurational degrees of freedom of both chains and network, yet a quantitative understanding…
Understanding how topological constraints affect the dynamics of polymers in solution is at the basis of any polymer theory and it is particularly needed for melts of rings. These polymers fold as crumpled and space-filling objects and,…
Quantum many-body states that frequently appear in physics often obey an entropy scaling law, meaning that an entanglement entropy of a subsystem can be expressed as a sum of terms that scale linearly with its volume and area, plus a…
A self-interacting polymer can undergo an orientational ordering transition, depending on the magnitude of the nematic interaction. The effect of embedding such a polymer into a flexible surface on this transition is studied on the…
Loops undergoing thermal fluctuations are prevalent in nature. Ring-like or cross-linked polymers, cyclic macromolecules, and protein-mediated DNA loops all belong to this category. Stability of these molecules are generally described in…
Ordering at arbitrarily high temperature - entropic order - has been argued to take place in a class of generalized Ising models parameterised by a real interaction parameter $p$ when $p\ge 1$. We give a rigorous proof of this conjecture.…
We consider the number of configurations of a surface in two dimensions that has a prescribed length and encloses a prescribed perimeter with respect to a baseline. An approximate analytical treatment in a semi--continuum compares…
The paper contains the generalization of usual lattice model of multicomponent systems. The generalization is related to account the following factors: 1. The short-range parts of interatomic repulsions. These repulsions are not identical…
In this paper, we aim to address an important issue about the pseudopotential lattice Boltzmann (LB) model, which has attracted much attention as a mesoscopic model for simulating interfacial dynamics of complex fluids, but suffers from the…
We show that transport in the presence of entropic barriers exhibits peculiar characteristics which makes it distinctly different from that occurring through energy barriers. The constrained dynamics yields a scaling regime for the particle…
We consider the response of an adsorbed polymer that is pulled by an AFM within a simple geometric framework. We separately consider the cases of i) fixed polymer-surface contact point, ii) sticky case where the polymer is peeled off from…
The kinetic behavior of a three-dimensional off-lattice heteropolymer model is studied in terms of the time dependence of the average mean-square displacement between configurations. It is found that at short time-scales similar behavior is…
The statistical mechanics of a long knotted collapsed polymer is determined by a free-energy with a knot-dependent subleading term, which is linked to the length of the shortest polymer that can hold such knot. The only other parameter…
The effect of different move sets on the folding kinetics of the Monte Carlo simulations is analysed based on the conformation-network and the temperature-dependent folding kinetics. A new scheme of implementing Metropolis algorithm is…
We consider tiles of some fixed size, with an associated weighting on the shapes of tile, of total mass 1. We study the pressure, $p$, of tilings with those tiles; the pressure, one over the volume times the logarithm of the partition…
For a minimal inequality derived from a maximal lattice-free simplicial polytope in $\R^n$, we investigate the region where minimal liftings are uniquely defined, and we characterize when this region covers $\R^n$. We then use this…
The force-assisted desorption kinetics of a macromolecule from adhesive surface is studied theoretically, using the notion of tensile (Pincus) blobs, as well as by means of Monte-Carlo (MC) and Molecular Dynamics (MD) simulations. We show…
There have been separate studies of the polymer collapse transition, where the collapse was induced by two different types of attraction. In each case, the configurations of the polymer were given by the same subset of random walks being…
We demonstrate that the entropy of entanglement and the distillable entanglement of regions with respect to the rest of a general harmonic lattice system in the ground or a thermal state scale at most as the boundary area of the region.…
We consider the problem of an ideal polymer confined in a droplet. When the droplet radius is smaller than the (unconfined) polymer radius of gyration, the polymer entropy will depend on the droplet shape. We compute the resulting surface…