Related papers: Dynamics and Scission of Rodlike Cationic Surfacta…
Hypothesis Understanding the scission of rod-like micelles under mechanical forces is crucial for optimizing their stability and behavior in industrial applications. This study investigates how micelle length, flexibility, and external…
We present the first molecular dynamics study to probe the mechanisms of anomalous diffusion in cationic surfactant micelles in the presence of explicit salt and solvent-mediated interactions. Simulations show that when the counter ion…
We use coarse-grained molecular-dynamics (MD) simulations to investigate the structural and dynamical properties of micelles under non-equilibrium Poiseuille flow in a nano-confined geometry. The effects of flow, confinement, and the…
The past few years have seen many advances in our understanding of the dynamics of polymeric fluids. These include improvements on the successful reptation theory; an emerging molecular theory of semiflexible chain dynamics; and an…
In this review, we report recent developments on the shear-induced transitions and instabilities found in surfactant wormlike micelles. The survey focuses on the non-linear shear rheology and covers a broad range of surfactant…
Hypotheses: The aggregation number and length of spherocylindrical (rodlike, wormlike) micelles in solutions of an ionic surfactant and salt can be predicted knowing the molecular parameters and the input concentrations of the species. This…
We investigate the flow evolution of a linear and a branched wormlike micellar solution with matched rheology in a Taylor-Couette (TC) cell using a combination of particle-tracking velocimetry, birefringence, and turbidity measurements.…
In the past fifteen years, flow instabilities reminiscent of the Taylor-like instabilities driven by hoop stresses, have been observed in wormlike micelles based on surfactant molecules. In particular, purely elastic instabilities and…
We report on a non trivial dynamics of the interface between shear bands following a start-up of flow in a semi-dilute wormlike micellar system investigated using a combination of mechanical and optical measurements. During the building of…
We investigate the morphology and energetics of a self-associating model cationic surfactant in water using coarse-grained molecular dynamics simulations. We develop an algorithm to track micelles contours and quantify various…
We present an experimental study of the motion of a viscoelastic micellar material around a moving cylinder, which ranges in response from fluid-like flow to solid-like tearing and fracture, depending on the cylinder radius and velocity.…
We present a tensor constitutive model for predicting stress and flow-induced structure formation in dilute wormlike micellar solutions. The micellar solution is treated as a dilute suspension of rigid Brownian rods whose length varies…
Complex fluids containing low concentrations of slender colloidal rods can display a high viscosity, while little flow is needed to thin the fluid. This feature makes slender rods essential constituents in industrial applications and…
We study the dynamics of the Taylor-Couette flow of shear banding wormlike micelles. We focus on the high shear rate branch of the flow curve and show that for sufficiently high Weissenberg numbers, this branch becomes unstable. This…
The flow behavior of a semiflexible polymer in microchannels is studied using Multiparticle Collision Dynamics (MPC), a particle-based hydrodynamic simulation technique. Conformations, distributions, and radial cross-streamline migration…
We study the early stages of the shear banding instability in semidilute wormlike micelles using the non-local Johnson-Segalman model with a two-fluid coupling of the concentration (phi) to the shear rate (gamma_dot) and micellar strain…
Using Dynamic Light Scattering in heterodyne mode, we measure velocity profiles in a much studied system of wormlike micelles (CPCl/NaSal) known to exhibit both shear-banding and stress plateau behavior. Our data provide evidence for the…
The viscosity of suspensions of large ($\geq10{\mu m}$) particles diverges at high solid fractions due to proliferation of frictional particle contacts. Reducing friction, to allow or improve flowability, is usually achieved by tuning the…
We report the flow dynamics of two shear-banding wormlike micellar solutions with distinct surfactant chemistries in a Taylor-Couette (TC) setup following a startup shear. The solutions, formulated with CTAB/NaSal and CPyCl/NaSal, exhibit…
We report on an experimental investigation of the tumbling of microrods in the shear flow of a microchannel (40 x 2.5 x 0.4 mm). The rods are 20 to 30 microns long and their diameters are of the order of 1 micron. Images of the…