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In this work, the structural, optical, and electronic properties of rare-earth perovskites of the general formula RCrO3, where R represents the rare-earth Gd, Tb, Dy, Ho, Er, and Tm, have been studied in detail. These compounds were…

Materials Science · Physics 2022-04-27 Jianhang Shi , Gayanath W. Fernando , Yanliu Dang , Steven L. Suib , Menka Jain

The rare-earth-metal-oxide based electronic materials were produced via a conventional mixed-oxide route. Thermal analysis, XRD and SEM were used to follow phase evolution and demonstrate the phase purity. Analytical TEM were used to…

Materials Science · Physics 2023-01-31 Kouros Khamoushi

Rare earth Manganite Nickelite double perovskites are prepared by solgel assisted combustion route, where, R varies from La, Pr, Nd, Sm, Gd, Tb, Dy, Y, and Ho. The samples have been systematically investigated using powder xray diffraction,…

We report here the structural, micro-structural/morphological and detailed magnetic properties of RECrO3 (RE = La, Nd, Sm, Eu and Gd) Orthocromites. A series of RECrO3 (RE = La, Nd, Sm, Eu and Gd) Orthocromites polycrystalline samples with…

Materials Science · Physics 2024-09-24 Anurag Yadav , Anuj Kumar

The results of studies of Y$_{2}$Ti$_2$O$_7$ single crystals doped with Er$^{3+}$ and Yb$^{3+}$ ions by means of electron paramagnetic resonance (EPR) and dc-magnetometry are reported. EPR signals of the trigonal centers with the…

Strongly Correlated Electrons · Physics 2020-01-15 R. G. Batulin , M. A. Cherosov , I. F. Gilmutdinov , A. G. Kiiamov , V. V. Klekovkina , B. Z. Malkin , A. A. Rodionov , R. V. Yusupov

We studied the electronic structure of rare-earth ditelluride (ReTe_2 : Re = La, Pr, Sm, and Gd) using photoemission spectroscopy. From the x-ray photoelectron spectroscopy (XPS) study of the 3d core levels of rare-earth elements, we found…

Strongly Correlated Electrons · Physics 2007-05-23 Jaegwan Chung , Junghwan Park , J. G. Park , Byung-Hee Choi , S. J. Oh , E. J. Cho , H. D. Kim , Y. S. Kwon

We report a combined experimental and theoretical study on intriguing magnetic properties of quasiferroelectric orthochromates. Large single crystals of the family of RECrO$_3$ (RE = Y, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) compounds were…

We present the crystal structures and magnetic properties of RE3Sb3Mg2O14 (La3Sb3Mg2O14, Pr3Sb3Mg2O14, Sm3Sb3Mg2O14, Eu3Sb3Mg2O14, Tb3Sb3Mg2O14, and Ho3Sb3Mg2O14), a family of novel materials based on a perfect geometry 2D rare earth Kagome…

Strongly Correlated Electrons · Physics 2016-01-28 Marisa B. Sanders , Kristen M. Baroudi , Jason W. Krizan , Omar A. Mukadam , Robert J. Cava

The electronic properties of transition-metal oxides with highly correlated electrons are of central importance in modern condensed matter physics and chemistry, both for their fundamental scientific interest, and for their potential for…

The present work reports results of the electron paramagnetic resonance (EPR), optical absorption, radio- and photoluminescence (RL and PL) complex study of the Lu2Si2O7:Pr and Lu2Si2O7:Ce pyrosilicate crystals. In both crystals, the EPR…

Materials Science · Physics 2020-07-15 M. Buryi , V. Laguta , V. Babin , O. Laguta , M. G. Brik , M. Nikl

Nanoparticles of Cr3+-substituted Ni-Zn ferrites with a general formula Ni0.4Zn0.6-xCrxFe2O4 (x = 0.0 - 0.6) have been synthesized via a facile microwave combustion route. The crystalline phase has been characterized by XRD, TEM, FT-I and…

Materials Science · Physics 2026-04-21 Abdulaziz Abu El-Fadl , Azza M. Hassan , Mohamed A. Kassem

La$_{0.7}$Sr$_{0.3}$MnO$_3$ polycrystalline samples have been prepared using different synthesis routes. X-ray Diffraction (XRD) confirms that the samples are of single phase with R$\bar{3}$c space group. The surface morphology and particle…

Materials Science · Physics 2016-05-25 Ashutosh Kumar , Himanshu Sharma , C. V. Tomy , Ajay D. Thakur

The synthesis and structural studies on the polycrystalline La1-xBixCrO3 (x =0, 0.2, 0.25, 0.3, 0.35) have been done using XRD and TEM. The results of the Reitveld refinement of XRD data shows that these compounds crystallize in an…

Strongly Correlated Electrons · Physics 2014-03-17 Aga Shahee , Dhirendra Kumar , N. P. Lalla

The synthesis, structural description, temperature dependent magnetic susceptibilities and field dependent magnetizations of a series of rare earth garnets of the form Li3RE3Te2O12 (RE = Y, La, Pr, Nd, Sm-Lu) are reported. The structure of…

Materials Science · Physics 2018-10-16 F. Alex Cevallos , R. J. Cava

Using density functional theory plus self-consistent Hubbard $U$ (DFT$+U_{sc}$) calculations, we have investigated the structural and electronic properties of the rare-earth cobaltites \textit{R}CoO$_3$ (\textit{R} = Pr -- Lu). Our…

Strongly Correlated Electrons · Physics 2016-07-27 M. Topsakal , C. Leighton , R. M. Wentzcovitch

We report on the electronic structure of the perovskite oxide CaCrO3 using valence-band, core-level, and Cr 2p - 3d resonant photoemission spectroscopy (PES). Despite its antiferromagnetic order, a clear Fermi edge characteristic of a metal…

Strongly Correlated Electrons · Physics 2025-08-20 P. A. Bhobe , A. Chainani , M. Taguchi , R. Eguchi , M. Matsunami , T. Ohtsuki , K. Ishizaka , M. Okawa , M. Oura , Y. Senba , H. Ohashi , M. Isobe , Y. Ueda , S. Shin

Hard x-ray scattering (HXS) experiments with a photon energy of 100keV were performed as a function of temperature and applied magnetic field on selected compounds of the RFe$_3$(BO$_3$)$_4$ family. The results show the presence of several…

Strongly Correlated Electrons · Physics 2010-09-09 J. E. Hamann-Borrero , M. Philipp , O. Kataeva , M. v. Zimmermann , J. Geck , R. Klingeler , A. Vasiliev , L. Bezmaternykh , B. Büchner , C. Hess

Recent advances in quantum crystallography have shown that, beyond conventional charge density refinement, a one-electron reduced density matrix (1-RDM) satisfying N-representability conditions can be reconstructed using jointly…

Quantum Physics · Physics 2024-03-04 Sizhuo Yu , Jean-Michel Gillet

Ruthenates comprise an interesting class of materials with a wide range of extremely exciting properties, and thus the discovery of new stable ruthenates remains an active area of investigation. We report the crystal growth and…

Three-dimensional electron diffraction (3DED) is a powerful technique providing for crystal structure solutions of sub-micron sized crystals too small for structure determination via X-ray techniques. The entry requirement, however, of a…

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