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We review different computational methods for the calculation of photoelectron spectra and angular distributions of atoms and molecules when excited by laser pulses using time-dependent density-functional theory (TDDFT) that are suitable…

Chemical Physics · Physics 2017-03-28 Philipp Wopperer , Umberto De Giovannini , Angel Rubio

For a variant of the algorithm in [Pit19] (arXiv:1903.10816) to compute the approximate density or distribution function of a linear mixture of independent random variables known by a finite sample, it is presented a proof of the functional…

Statistics Theory · Mathematics 2019-06-19 Thomas Pitschel

The van Leeuwen proof of linear-response time-dependent density functional theory (TDDFT) is generalized to thermal ensembles. This allows generalization to finite temperatures of the Gross-Kohn relation, the exchange-correlation kernel of…

Chemical Physics · Physics 2016-06-15 Aurora Pribram-Jones , Paul E. Grabowski , Kieron Burke

Density-functional theory (DFT) has revolutionized computer simulations in chemistry and material science. A faithful implementation of the theory requires self-consistent calculations. However, this effort involves repeatedly diagonalizing…

Quantum Physics · Physics 2023-07-17 Taehee Ko , Xiantao Li , Chunhao Wang

Classical density functional theory (DFT) is a statistical mechanical theory for calculating the density profiles of the molecules in a liquid. It is widely used, for example. to calculate the density distribution of the molecules in the…

Statistical Mechanics · Physics 2015-07-08 Adam P. Hughes , Uwe Thiele , Andrew J. Archer

The determination of the elements of the S-matrix within the framework of time-dependent density-functional theory (TDDFT) has remained a widely open question. We explore two different methods to calculate state-to-state transition…

Quantum Physics · Physics 2007-05-23 Nina Rohringer , Simone Peter , Joachim Burgdörfer

We demonstrate the capabilities of time-dependent density functional theory (TDDFT) for strong-field, short wavelength (soft X-ray) physics, as compared to a formalism based on rate equations. We find that TDDFT provides a very good…

We present a versatile density functional approach (DFT) for calculating the depletion potential in general fluid mixtures. In contrast to brute force DFT, our approach requires only the equilibrium density profile of the small particles…

Soft Condensed Matter · Physics 2009-10-31 R. Roth , R. Evans , S. Dietrich

In three-dimensional systems of the Ising universality class the ratio of correlation length amplitudes for the high- and low-temperature phases is a universal quantity. Its field theoretic determination apart from the $\epsilon$-expansion…

High Energy Physics - Lattice · Physics 2010-12-23 Gernot Muenster , Jochen Heitger

Ensemble Density Functional Theory (EDFT) is a generalization of ground-state Density Functional Theory (GS DFT), which is based on an exact formal theory of finite collections of a system's ground and excited states. EDFT in various forms…

Materials Science · Physics 2024-08-27 Remi J. Leano , Aurora Pribram-Jones , David A. Strubbe

Designing efficient and accurate numerical solvers for high-dimensional partial differential equations (PDEs) remains a challenging and important topic in computational science and engineering, mainly due to the "curse of dimensionality" in…

Numerical Analysis · Mathematics 2025-08-20 Senwei Liang , Haizhao Yang

Density Functional Theory calculations traditionally suffer from an inherent cubic scaling with respect to the size of the system, making big calculations extremely expensive. This cubic scaling can be avoided by the use of so-called linear…

The unitarity method for calculating one-loop amplitudes provides algorithms of polynomial complexity. This is primarily beneficial for the computation of multi-leg one loop amplitudes and it is therefore of great interest to develop a…

High Energy Physics - Phenomenology · Physics 2009-04-14 R. Keith Ellis , Walter T. Giele , Zoltan Kunszt

The response of an extended periodic system to a homogeneous field (of wave-vector $q=0$) cannot be obtained from a $q=0$ time-dependent density functional theory (TDDFT) calculation, because the Runge-Gross theorem does not apply.…

Materials Science · Physics 2016-08-31 Neepa T. Maitra , Ivo Souza , Kieron Burke

We develop a finite volume method for Maxwell's equations in materials whose electromagnetic properties vary in space and time. We investigate both conservative and non-conservative numerical formulations. High-order methods accurately…

Computational Physics · Physics 2023-07-25 Damian P. San Roman Alerigi , David I. Ketcheson , Boon S. Ooi

In the present work we propose a theory for obtaining successively better approximations to the linear response functions of time-dependent density or current-density functional theory. The new technique is based on the variational approach…

Statistical Mechanics · Physics 2007-05-23 Ulf von Barth , Nils Erik Dahlen , Robert van Leeuwen , Gianluca Stefanucci

The knowledge of effective masses is a key ingredient to analyze numerous properties of semiconductors, like carrier mobilities, (magneto-)transport properties, or band extrema characteristics yielding carrier densities and density of…

The nuclear collective response at finite temperature is investigated for the first time in the quantum framework of the small amplitude limit of the extended TDHF approach, including a non-Markovian collision term. It is shown that the…

Nuclear Theory · Physics 2008-11-26 Denis Lacroix , Philippe Chomaz , Sakir Ayik

The nuclear time-dependent density functional theory (TDDFT) is a tool of choice for describing various dynamical phenomena in atomic nuclei. In a recent study, we reported an extension of the framework - the multiconfigurational TDDFT…

Nuclear Theory · Physics 2024-01-24 Petar Marević , David Regnier , Denis Lacroix

We introduce the multivariate decomposition finite element method for elliptic PDEs with lognormal diffusion coefficient $a=\exp(Z)$ where $Z$ is a Gaussian random field defined by an infinite series expansion $Z(\boldsymbol{y}) =…

Numerical Analysis · Mathematics 2021-09-28 Dong T. P. Nguyen , Dirk Nuyens