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This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…

Mathematical Physics · Physics 2009-10-31 Elliott H. Lieb , Jakob Yngvason

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

Legendre transform between thermodynamic quantities such as the Helmholtz free energy and entropy plays a key role in the formulation of the canonical ensemble. In the standard treatment, the transform exchanges the independent variable…

Statistical Mechanics · Physics 2025-01-24 Ramandeep S. Johal

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

A class of autonomous quantum heat baths satisfying the eigenstate thermalization hypothesis (ETH) criteria is proposed. We show that such systems are expected to cause thermal relaxation of much smaller quantum systems coupled to one of…

Quantum Physics · Physics 2015-08-10 O. Fialko

The theory of quantum thermodynamics investigates how the concepts of heat, work, and temperature can be carried over to the quantum realm, where fluctuations and randomness are fundamentally unavoidable. Of particular practical relevance…

Quantum Physics · Physics 2019-09-23 Patrick P. Potts

A general fluctuational-electrodynamic theory is developed to investigate radiative heat exchanges between objects which are assumed small compared with their thermal wavelength (dipolar approximation) in N-body systems immersed in a…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Riccardo Messina , Maria Tschikin , Svend-Age Biehs , Philippe Ben-Abdallah

For classical discrete systems under constant composition typically refferred to substitutional alloys, we propose calculation method of Helmholtz free energy based on a set of special microscopic states. The advantage of the method is that…

Statistical Mechanics · Physics 2021-10-22 Ryogo Miyake , Subaru Sugie , Koretaka Yuge

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

We investigate the overdamped stochastic dynamics of a particle in an asymptotically flat external potential field, in contact with a thermal bath. For an infinite system size, the particles may escape the force field and diffuse freely at…

Statistical Mechanics · Physics 2020-06-24 Erez Aghion , David A. Kessler , Eli Barkai

Classical thermodynamics treats temperature as a state variable characterizing systems in equilibrium with idealized infinite reservoirs. We argue that this framing, while computationally exact, obscures an essential physical reality: any…

Quantum Physics · Physics 2026-04-14 David Vaknin

In the last years new interdisciplinary approaches to economics and social science have been developed. A Thermodynamic approach to socio-economics has brought to a new interdisciplinary scientific field called econophysics. Why…

Physics and Society · Physics 2016-10-26 S. Ripandelli , U. Lucia

In his Comment [1], Philip Strasberg (PS) argues from the analysis of different examples that the framework we have presented in [2] does not recover known results of macroscopic textbook thermodynamics. Here, we show that such apparent…

Quantum Physics · Physics 2023-09-18 Cyril Elouard , Camille Lombard Latune

Recent research on the fundamentals of statistical mechanics has led to an interesting discovery [1-3]: With locally nonchaotic barriers, as Boltzmann's H-theorem is inapplicable, there exist nontrivial non-thermodynamic systems that can…

Statistical Mechanics · Physics 2025-05-27 Yu Qiao

An attempt toward the operational formulation of quantum thermodynamics is made by employing the recently proposed operations forming positive operator-valued measures for generating thermodynamic processes. The quantity of heat as well as…

Statistical Mechanics · Physics 2015-06-04 Sumiyoshi Abe , Yuki Aoyaghi

Thermodynamic quantities, like heat, entropy, or work, are random variables, in stochastic systems. Here, we investigate the statistics of the heat exchanged by a Brownian particle subjected to a logarithm-harmonic potential. We derive…

Statistical Mechanics · Physics 2021-12-08 Pedro V. Paraguassú , Welles A. M Morgado

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Parth Kumar , Charles A. Stafford

Quantum thermodynamics can be naturally phrased as a theory of quantum state transformation and energy exchange for small-scale quantum systems undergoing thermodynamical processes, thereby making the resource theoretical approach very well…

Quantum Physics · Physics 2023-07-19 Uttam Singh , Jarosław K. Korbicz , Nicolas J. Cerf

Adopting a resource theory framework of thermodynamics for quantum and nano systems pioneered by Janzing et al. [Int. J. Th. Phys. 39, 2717 (2000)], we formulate the cost in useful work of transforming one resource state into another as a…

Mathematical Physics · Physics 2017-07-06 Joseph M. Renes