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Accurately describing strong electron correlation in complex systems remains a prominent challenge in computational chemistry as near-term quantum algorithms treating total correlation often require prohibitively deep circuits. Here we…

Computational Engineering, Finance, and Science · Computer Science 2026-04-21 Zhanou Liu , Yuhao Chen , Yingjin Ma , Xiao He , Yuxin Deng

Four point correlation functions for many electrons at finite temperature in periodic lattice are analyzed by the perturbation theory with respect to the coupling constant. The correlation functions are characterized as a limit of finite…

Mathematical Physics · Physics 2015-05-13 Yohei Kashima

We present a low-scaling diagrammatic Monte Carlo approach to molecular correlation energies. Using combinatorial graph theory to encode many-body Hugenholtz diagrams, we sample the M{\o}ller-Plesset (MPn) perturbation series, obtaining…

Strongly Correlated Electrons · Physics 2023-07-26 G. Bighin , Q. P. Ho , M. Lemeshko , T. V. Tscherbul

Multiple spin density waves and related vortex-type magnetic structures in the itinerant electron system with inversion symmetry have been investigated on the basis of the Hubbard model and the generalized Hartree-Fock approximation…

Strongly Correlated Electrons · Physics 2020-02-19 Yoshiro Kakehashi

The perturbation method is an approximation scheme with a solvable leading order. The standard way is to choose a non-interacting sector for the leading order. The adaptive perturbation method improves the solvable part by using all…

High Energy Physics - Theory · Physics 2022-10-17 Chen-Te Ma

We introduce a new variant of the complete active space second-order perturbation theory (CASPT2) method that performs similarly to multistate CASPT2 (MS-CASPT2) in regions of the potential energy surface where the electronic states are…

Chemical Physics · Physics 2022-04-12 Stefano Battaglia , Roland Lindh

Electron density distribution plays an essential role in predicting molecular properties. It is also a simple observable from which machine-learning models for molecular electronic structure can be derived. In the present work, we present…

Chemical Physics · Physics 2022-04-01 Lan Nguyen Tran

We present a workflow of practical calculations of electron-phonon (e-ph) coupling with many-electron correlation effects included using the GW perturbation theory (GWPT). This workflow combines BerkeleyGW, ABINIT, and EPW software packages…

Materials Science · Physics 2024-09-20 Zhenglu Li , Gabriel Antonius , Yang-Hao Chan , Steven G. Louie

A critical challenge for density functional theory (DFT) in practice is its limited ability to treat static electron correlation, leading to errors in its prediction of charges, multiradicals, and reaction barriers. Recently, we combined…

Chemical Physics · Physics 2024-11-05 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

We present an extension of the canonical coupled mode theory of electromagnetic waves to the case of pulses and spatio-temporal perturbations in complex media. Unlike previous attempts to derive such a model, our approach involves no…

Optics · Physics 2016-05-04 Y. Sivan , S. Rozenberg , A. Halstuch

The dual boson approach [Ann. Phys. 327, 1320 (2012)] provides a means to construct a diagrammatic expansion around the extended dynamical mean-field theory (EDMFT). In this paper, we present the numerical implementation of the approach and…

Materials with correlated electrons often respond very strongly to external or internal influences, leading to instabilities and states of matter with broken symmetry. This behavior can be studied theoretically either by evaluating the…

Strongly Correlated Electrons · Physics 2017-08-15 J. Kunes , I. Leonov , P. Augustinsky , V. Krapek , M. Kollar , D. Vollhardt

Electron magnetohydrodynamic (EMHD) turbulence in two dimensions is studied via high-resolution numerical simulations with a normal diffusivity. The resulting energy spectra asymptotically approach a $k^{-5/2}$ law with increasing $R_B$,…

Plasma Physics · Physics 2009-05-01 C. J. Wareing , R. Hollerbach

We explore the possibility of calculating electronic excited states by using perturbation theory along a range-separated adiabatic connection. Starting from the energies of a partially interacting Hamiltonian, a first-order correction is…

Chemical Physics · Physics 2014-12-15 Elisa Rebolini , Julien Toulouse , Andrew M. Teale , Trygve Helgaker , Andreas Savin

Electromagnetic waves interacting with three--dimensional periodic structures occur in many applications of great scientific and engineering interest. These three dimensional interactions are extremely complicated and subtle, so it is…

Numerical Analysis · Mathematics 2024-07-08 David Nicholls , Liet Vo

We present a computational protocol, based on density matrix perturbation theory, to obtain non-adiabatic, frequency-dependent electron-phonon self-energies for molecules and solids. Our approach enables the evaluation of electron-phonon…

Materials Science · Physics 2023-05-09 Han Yang , Marco Govoni , Arpan Kundu , Giulia Galli

We derive the second-order approximation (PT2) to the ensemble correlation energy functional by applying the G\"{o}rling-Levy perturbation theory on the ensemble density-functional theory (EDFT). Its performance is checked by calculating…

Computational Physics · Physics 2021-11-17 Zeng-hui Yang

We investigate nonlinear magnetoelastic wave dynamics and electrically tunable soliton excitations in hexagonal multiferroic media. By varying the magnetoelastic coupling strength and using a coupled magnetoelastic-ferroelectric continuum…

Mesoscale and Nanoscale Physics · Physics 2026-03-09 Saumen Acharjee , Kallol Kavas Hazarika , Rajneesh Kakoti

The coherence time of an electron spin decohered by the nuclear spin environment in a quantum dot can be substantially increased by subjecting the electron to suitable dynamical decoupling sequences. We analyze the performance of high-level…

Mesoscale and Nanoscale Physics · Physics 2008-03-27 Wenxian Zhang , N. P. Konstantinidis , V. V. Dobrovitski , B. N. Harmon , Lea F. Santos , Lorenza Viola

A two-field Hamiltonian gyrofluid model for kinetic Alfv\'en waves retaining ion finite Larmor radius corrections, parallel magnetic field fluctuations and electron inertia, is used to study turbulent cascades from the MHD to the sub-ion…

Plasma Physics · Physics 2019-05-29 T. Passot , P. L. Sulem