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Related papers: Molecular Cluster Perturbation Theory. I. Formalis…

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An approach is developed, combining the ideas of quantum statistical mechanics and multichannel theory of scattering, for treating statistical systems whose constituents can possess different bound states realized as compact clusters. The…

Statistical Mechanics · Physics 2015-06-25 V. I. Yukalov , E. P. Yukalova

We derive the second-order approximation (PT2) to the ensemble correlation energy functional by applying the G\"{o}rling-Levy perturbation theory on the ensemble density-functional theory (EDFT). Its performance is checked by calculating…

Computational Physics · Physics 2021-11-17 Zeng-hui Yang

In this paper, we present a cluster algorithm for the simulation of hard spheres and related systems. In this algorithm, a copy of the configuration is rotated with respect to a randomly chosen pivot point. The two systems are then…

Statistical Mechanics · Physics 2008-02-03 Christophe Dress , Werner Krauth

Two-step hybrid methods specially adapted to the numerical integration of perturbed oscillators are obtained. The formulation of the methods is based on a refinement of classical Taylor expansions due to Scheifele [{\em Z. Angew. Math.…

Numerical Analysis · Mathematics 2007-05-23 Hans Van de Vyver

The QCD-coupling is a necessary input in the computation of many observables, and the parametric error on input parameters can be a dominant source of uncertainty. The coupling can be extracted by comparing high order perturbative…

High Energy Physics - Lattice · Physics 2022-03-16 Leonardo Chimirri , Rainer Sommer

Electronic resonances are metastable states with finite lifetimes, encountered in processes such as photodetachment, electron transmission, and Auger decay. Resonances appear in Hermitian quantum mechanics as increased density of states in…

Chemical Physics · Physics 2025-11-10 Cansu Utku , Garrette Pauley Paran , Thomas-C. Jagau

Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids…

Soft Condensed Matter · Physics 2019-04-16 W. R. C. Somerville , J. L. Stokes , A. M. Adawi , T. S. Horozov , A. J. Archer , D. M. A. Buzza

In this contribution we present calculations performed for interacting electron systems within a non-perturbative formulation of the cluster theory. Extrapolation of the model to describe the time dependence of the interacting systems is…

Atomic Physics · Physics 2009-11-13 M. Tomaselli , T. Kuehl , D. Ursescu , S. Fritzsche

We introduce a general procedure for computing higher-order moments of correlation functions in open quantum systems, extending the scope of our recent work on Memory Kernel Coupling Theory (MKCT) [W. Liu, Y. Su, Y. Wang, and W. Dou,…

Quantum Physics · Physics 2025-06-12 Rui-Hao Bi , Wei Liu , Wenjie Dou

A novel reduced-scaling, general-order coupled-cluster approach is formulated by exploiting hierarchical representations of many-body tensors, combined with the recently suggested formalism of scale-adaptive tensor algebra. Inspired by the…

Chemical Physics · Physics 2018-03-14 Dmitry I. Lyakh

We present a measurement-cost efficient implementation of Strongly-Contracted $N$-Electron Valence Perturbation Theory (SC-NEVPT2) for use on near-term quantum devices. At the heart of our algorithm we exploit the properties of adaptive…

Quantum Physics · Physics 2024-05-27 Aaron Fitzpatrick , N. Walter Talarico , Roberto Di Remigio Eikås , Stefan Knecht

We present a fine-grained approach to identify clusters and perform percolation analysis in a 2D lattice system. In our approach, we develop an algorithm based on the linked-list data structure whereby the members of a cluster are nodes of…

Quantum Gases · Physics 2023-10-27 Hrushikesh Sable , Deepak Gaur , D. Angom

In recent years, a better understanding of the Monte Carlo method has provided us with many new techniques in different areas of statistical physics. Of particular interest are so called cluster methods, which exploit the considerable…

Statistical Mechanics · Physics 2007-05-23 Werner Krauth

The chemical and physical properties of molecular clusters can heavily depend on their size, which makes them very attractive for the design of new materials with tailored properties. Deriving the structure and dynamics of clusters is…

Recent years have seen the development of two types of non-local extensions to the single-site dynamical mean field theory. On one hand, cluster approximations, such as the dynamical cluster approximation, recover short-range…

Strongly Correlated Electrons · Physics 2018-03-21 Sergei Iskakov , Hanna Terletska , Emanuel Gull

Present atomic theory provides accurate and reliable results for atoms with a small number of valence electrons. However, most current methods of calculations fail when the number of valence electrons exceeds four or five. This means that…

Atomic Physics · Physics 2024-07-10 M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev , D. V. Mironova

Ballistic Macroscopic Fluctuation Theory (BMFT) captures the evolution of fluctuations and correlations in systems where transport is strictly ballistic. We show that, for \emph{generic integrable models}, BMFT can be constructed through a…

Statistical Mechanics · Physics 2025-05-26 Jitendra Kethepalli , Andrew Urilyon , Tridib Sadhu , Jacopo De Nardis

Coupled cluster theory is one of the most popular post-Hartree-Fock methods for ab initio molecular quantum chemistry. The finite-size error of the correlation energy in periodic coupled cluster calculations for three-dimensional insulating…

Numerical Analysis · Mathematics 2024-04-02 Xin Xing , Lin Lin

We present an accurate method for calculating hyperfine coupling constants (HFCCs) based on the complete active space second-order perturbation theory (CASPT2) with full internal contraction. The HFCCs are computed as a first-order property…

Chemical Physics · Physics 2017-03-20 Toru Shiozaki , Takeshi Yanai

Intermolecular charge-transfer (xCT) excited states important for various practical applications are challenging for many standard computational methods. It is highly desirable to have an affordable method that can treat xCT states…

Chemical Physics · Physics 2024-11-04 Nhan Tri Tran , Lan Nguyen Tran