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Using the results of x-ray and neutron diffraction experiments, we show that the ferroelectric polarization, in ~22 nm particles of BiFeO3, exhibits a jump by ~30% around the magnetic transition point T_N (~635 K) and a suppression by ~7%…

Materials Science · Physics 2011-08-18 S. Goswami , Dipten Bhattacharya , P. Choudhury , B. Ouladdiaf , T. Chatterji

From an experimental point of view, room temperature ferroelectricity in BiFeO3 is raising many questions. Electric measurements made a long time ago on solid-solutions of BiFeO3 with Pb(Ti,Zr)O3 indicate that a spontaneous electric…

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

Materials Science · Physics 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

Multiferroicity in LiCu2O2 single crystals is studied using resonant soft x-ray magnetic scattering, hard x-ray diffraction, heat capacity, magnetic susceptibility, and electrical polarization. Two magnetic transitions are found at 24.6 K…

BaMF4 (M=Fe, Co, Ni and Mn) family are typical multiferroic materials, having antiferromagnetism at around liquid nitrogen temperature. In this work, polycrystalline BaFeF4 has been prepared by solid state reaction. The slight deficiency of…

Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper…

Materials Science · Physics 2009-11-13 Silvia Picozzi , Kunihiko Yamauchi , Biplab Sanyal , Ivan A. Sergienko , Elbio Dagotto

The thermodynamic, magnetic, dielectric, and magnetoelectric properties of HoFe$_3$(BO$_3$)$_4$ and Ho$_{0.5}$Nd$_{0.5}$Fe$_3$(BO$_3$)$_4$ are investigated. Both compounds show a second order Ne\'{e}l transition above 30 K and a first order…

Strongly Correlated Electrons · Physics 2009-09-24 R. P. Chaudhury , F. Yen , B. Lorenz , Y. Y. Sun , L. N. Bezmaternykh , V. L. Temerov , C. W. Chu

Antiferromagnetic Bi_{2}Fe_{4}O_{9} (BFO), lightly substituted by cobalt is studied for magnetodielectricity. The substitution causes a substantial decrease in the Neel temperature (T_N) from 250 K (in parent sample, BFO) to 152 K (in 2% Co…

Materials Science · Physics 2017-09-19 S. R. Mohapatra , P. N. Vishwakarma , S. D. Kaushik , R. J. Choudhary , N. Mohapatra , A. K. Singh

A re-entrant novel phase has been observed in the hexagonal ferroelectric HoMnO3 in the presence of magnetic fields, in the temperature ranges defined by the plateau of the dielectric constant anomaly. The dielectric plateau evolves with…

Strongly Correlated Electrons · Physics 2009-11-10 B. Lorenz , A. P. Litvinchuk , M. M. Gospodinov , C. W. Chu

We investigate the spin-induced polarization in the multiferroic compound Ba2CuGe2O7 using variarional and finite temperature mean field approaches. The compound is described by a spin-3/2 Heisenberg model extended with easy plane…

Strongly Correlated Electrons · Physics 2012-02-21 Judit Romhanyi , Miklos Lajko , Karlo Penc

The magnetic, thermodynamic, and pyroelectric properties of LiFeP$_2$O$_7$ single crystals are investigated with emphasis on the magnetoelectric interaction of the electrical polarization with the magnetic order parameter. The magnetic…

Strongly Correlated Electrons · Physics 2012-09-13 K. -C. Liang , W. Zhang , B. Lorenz , Y. Y. Sun , P. S. Halasyamani , C. W. Chu

The effect of the Fe-Ga ratio on the magnetic and electric properties of the multiferroic Ga2-xFexO3 compound has been studied in order to determine the composition range exhibiting magnetic and electric orders coexistence and their…

Materials Science · Physics 2016-07-18 B. Kundys , F. Roulland , C. Lefevre , C. Meny , A. Thomasson , N. Viart

The first switchable electric polarization in metals was recently discovered in bilayer and trilayer WTe2. Strangely, despite the tininess of the ordered polarization, the ferroelectricity survives up to 350 K, rendering the mechanism of…

Materials Science · Physics 2025-07-25 Fangyuan Gu , Ruoshi Jiang , Wei Ku

The magnetostructural transitions and magnetoelectric effects reported in TbMn2O5 are described theoretically and shown to correspond to two essentially different mechanisms for the induced ferroelectricity. The incommensurate and…

Materials Science · Physics 2010-01-22 P. Toledano , W. Schranz , G. Krexner

We have grown single crystals of multiferroic double-perovskite Lu2CoMnO6 and studied the directional dependence of their magnetic and dielectric properties. The ferromagnetic order emerges below TC ~ 48K along the crystallographic c axis.…

Strongly Correlated Electrons · Physics 2014-03-26 N. Lee , H. Y. Choi , Y. J. Jo , M. S. Seo , S. Y. Park , Y. J. Choi

In this paper we examine the role of crystal chemistry factors in creating conditions for formation of magnetoelectric ordering in BiFeO3. It is generally accepted that the main reason of the ferroelectric distortion in BiFeO3 is concerned…

Materials Science · Physics 2011-06-03 L. M. Volkova , D. V. Marinin

We present a new member of the multiferroic oxides, Lu$_2$MnCoO$_6$, which we have investigated using X-ray diffraction, neutron diffraction, specific heat, magnetization, electric polarization, and dielectric constant measurements. This…

We report the observation of electric polarization in the magnetically ordered state of the Haldane chain compound, Gd$_2$BaNiO$_5$, with strongly correlated magnetic and dielectric properties. The results of dc magnetic susceptibility and…

Materials Science · Physics 2015-06-22 S. Chowki , Tathamay Basu , K. Singh , N. Mohapatra , E. V. Sampathkumaran

Recent interests towards novel functionalities arising at domain walls of ferroic materials naturally call for a microscopic understanding. To this end, first-principles calculations have been performed in order to provide solid evidence of…

Materials Science · Physics 2014-04-09 Paolo Barone , Domenico Di Sante , Silvia Picozzi

Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

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