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We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the…

Atomic Physics · Physics 2021-12-14 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

We describe protocols for passive atomic clocks based on quantum interrogation of the atoms. Unlike previous techniques, our protocols are adaptive and take advantage of prior information about the clock's state. To reduce deviations from…

Quantum Physics · Physics 2014-10-15 Michael Mullan , Emanuel Knill

The blackbody radiation shift of the Ga$^+$ $4s^2 \ ^1S^e_0 \to 4s4p \ ^3P^o_0$ clock transition is computed to be $-$$0.0140 \pm 0.0048$ Hz at 300 K. The small shift is consistent with the blackbody shifts of the clock transitions of other…

Atomic Physics · Physics 2014-07-11 Yongjun Cheng , J. Mitroy

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy

We evaluate the electric quadrupole moments of the ${^1}\!S_0$ and ${^3}\!P_0$ clock states of $^{27}$Al$^+$ and $^{115}$In$^+$. To capture all dominant contributions, our analysis extends through third order of perturbation theory and…

Atomic Physics · Physics 2017-04-11 K. Beloy , D. R. Leibrandt , W. M. Itano

Motivated by the ideas of using cold alkaline earth atoms trapped in an optical lattice for realization of optical atomic clocks, we investigate theoretically the perturbative effects of atom-atom interactions on a clock transition…

Quantum Physics · Physics 2009-11-10 D. E. Chang , Jun Ye , M. D. Lukin

An ultra-stable optical clock based on coherent population trapping effect of alkaline-earth ions, such as Ca$^+$, Sr$^+$, Ba$^+$, is analyzed here. The proposed transitions use the odd isotopes, so that the frequency shift is insensitive…

Optics · Physics 2009-04-03 Z. H. Lu , L. J. Wang

Optical clocks based on atoms and ions probe relativistic effects with unprecedented sensitivity by resolving time dilation due to atom motion or different positions in the gravitational potential through frequency shifts. However, all…

Quantum Physics · Physics 2026-04-22 Gabriel Sorci , Joshua Foo , Dietrich Leibfried , Christian Sanner , Igor Pikovski

We report calculations designed to assess the ultimate precision of an atomic clock based on the 578 nm $6 ^1S_0 --> 6 ^3P^o_0$ transition in Yb atoms confined in an optical lattice trap. We find that this transition has a natural linewidth…

Atomic Physics · Physics 2009-11-10 Sergey Porsev , Andrei Derevianko , Norval Fortson

It is shown that the dynamic differential scalar polarisability of the $S_{1/2}-D_{5/2}$ transition in $^{138}$Ba$^+$ can be determined to an inaccuracy below $0.5\%$ across a wide wavelength range ($\lambda>700\,\mathrm{nm}$). This can be…

Atomic Physics · Physics 2019-10-30 M. D. Barrett , K. J. Arnold , M. S. Safronova

The light-induced frequency shift due to the hyperpolarizability (i.e. terms of second-order in intensity) is studied for a forbidden optical transition, $J$=0$\to$$J$=0. A simple universal dependence on the field ellipticity is obtained.…

Atomic Physics · Physics 2009-11-11 A. V. Taichenachev , V. I. Yudin , V. D. Ovsiannikov , V. G. Pal'chikov

We present non-standard optical Ramsey schemes that use pulses individually tailored in duration, phase, and frequency to cancel spurious frequency shifts related to the excitation itself. In particular, the field shifts and their…

Active atomic clocks are predicted to provide far better short-term stability and robustness against thermal fluctuations than typical feedback-based optical atomic clocks. However, continuous laser operation using an ensemble of clock…

Quantum Physics · Physics 2024-12-31 Anna Bychek , Laurin Ostermann , Helmut Ritsch

The differential polarizability, due to near-infrared light at 1126 nm, of the 27Al+ 1S0 -> 3P0 clock transition is measured to be 4\pi\epsilon_0 x (1.6 +/- 0.5) x 10^{-31} m^3. This measurement is combined with experimental oscillator…

Improvements in atom-light coherence are foundational to progress in quantum information science, quantum optics, and precision metrology. Optical atomic clocks require local oscillators with exceptional optical coherence due to the…

We propose a high-performance atomic clock based on the 1.81 PHz transition between the ground and first-excited state of doubly ionized lead. Utilizing an even isotope of lead, both clock states have $I=J=F=0$, where $I$, $J$, and $F$ are…

Atomic Physics · Physics 2021-07-08 K. Beloy

We report on a precision measurement of the differential static scalar polarizability $\Delta\alpha_0$ of the ${}^{2}\!S_{1/2} \rightarrow {}^{2}\!D_{5/2}$ optical clock transition in the $^{88}$Sr$^{+}$ ion. The polarizability was…

Atomic Physics · Physics 2025-07-04 T. Lindvall , K. J. Hanhijärvi , T. Fordell , A. E. Wallin

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

For the past 15 years, tremendous progress within the fields of laser stabilization, optical frequency combs and atom cooling and trapping have allowed the realization of optical atomic clocks with unrivaled performances. These instruments…

Atomic Physics · Physics 2018-04-09 Marion Delehaye , Clément Lacroûte