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We consider the complex polymer system, consisting of ring polymer connected to the $f_1$-branched star-like structure, in good solvent in presence of structural inhomogeneities. We assume, that structural defects are correlated at large…

Soft Condensed Matter · Physics 2018-03-14 K. Haydukivska , V. Blavatska

In the present work, the cyclic polymer chains (rings) in structurally disordered environment (e.g. in the cross-linked polymer gel) are studied exploiting the model of closed self-avoiding walks (SAWs) trajectories on $d=3$-dimensional…

Soft Condensed Matter · Physics 2020-11-04 K. Haydukivska , V. Blavatska

We study the influence of structural obstacles in a disordered environment on the size and shape characteristics of long flexible polymer macromolecules. We use the model of self-avoiding random walks on diluted regular lattices at the…

Soft Condensed Matter · Physics 2010-11-22 Viktoria Blavatska , Wolfhard Janke

We analyze the conformational properties of polymer macromolecules in solutions in presence of extended structural obstacles of (fractal) dimension $\varepsilon_d$ causing the anisotropy of environment. Applying the pruned-enriched…

Soft Condensed Matter · Physics 2014-07-14 K. Haydukivska , V. Blavatska

We analyze the probability of a single loop formation in a long flexible polymer chain in disordered environment in $d$ dimensions. The structural defects are considered to be correlated on large distances $r$ according to a power law $\sim…

Soft Condensed Matter · Physics 2016-04-14 K. Haydukivska , V. Blavatska

It is nontrivial whether the average size of a ring polymer should become smaller or larger under a topological constraint. Making use of some knot invariants, we evaluate numerically the mean square radius of gyration for ring polymers…

Statistical Mechanics · Physics 2016-08-31 Miyuki K. Shimamura , Tetsuo Deguchi

In this paper, we show how the method of field theoretical renormalization group may be used to analyze universal shape properties of long polymer chains in porous environment. So far such analytical calculations were primarily focussed on…

Soft Condensed Matter · Physics 2012-02-22 V. Blavatska , C. von Ferber , Yu. Holovatch

In this paper, we employ Molecular Dynamics computer simulations to study and compare the statics and dynamics of linear and circular (ring) polymer chains in entangled solutions of different densities. While we confirm that linear chain…

Soft Condensed Matter · Physics 2016-02-17 Negar Nahali , Angelo Rosa

We determine the density expansion of the radius of gyration, of the hydrodynamic radius, and of the end-to-end distance for a monodisperse polymer solution in good-solvent conditions. We consider the scaling limit (large degree of…

Statistical Mechanics · Physics 2007-05-23 Sergio Caracciolo , Bortolo Matteo Mognetti , Andrea Pelissetto

The conformational properties of flexible polymers in d dimensions in environments with extended defects are analyzed both analytically and numerically. We consider the case, when structural defects are correlated in \varepsilon_d…

Disordered Systems and Neural Networks · Physics 2013-02-06 V. Blavatska , K. Haydukivska

The effects of entanglement in solutions and melts of unknotted ring polymers have been addressed by several theoretical and numerical studies. The system properties have been typically profiled as a function of ring contour length at fixed…

Soft Condensed Matter · Physics 2011-11-29 Angelo Rosa , Enzo Orlandini , Luca Tubiana , Cristian Micheletti

Inspired by how the shape deformations in active organisms help them to migrate through disordered porous environments, we simulate active ring polymers in two-dimensional random porous media. Flexible and inextensible active ring polymers…

Soft Condensed Matter · Physics 2022-08-16 Ligesh Theeyancheri , Subhasish Chaki , Tapomoy Bhattacharjee , Rajarshi Chakrabarti

Ring polymers remain a major challenge to our current understanding of polymer dynamics. Experimental results are difficult to interpret because of the uncertainty in the purity and dispersity of the sample. Using both equilibrium and…

Soft Condensed Matter · Physics 2015-06-03 Jonathan D. Halverson , Gary S. Grest , Alexander Y. Grosberg , Kurt Kremer

We study the conformational properties of complex polymer macromolecules, consisting in general of $n$ subsequently connected chains (blocks) of different lengths and distinct chemical structure. Depending on the solvent conditions, the…

Soft Condensed Matter · Physics 2019-12-03 V. Blavatska , K. Haydukivska

The conformational statistics of ring polymers in melts or dense solutions is strongly affected by their quenched microscopic topological state. The effect is particularly strong for non-concatenated unknotted rings, which are known to…

Soft Condensed Matter · Physics 2015-06-17 Angelo Rosa , Ralf Everaers

Several nontrivial properties are shown for the mean square radius of gyration $R_K^2$ of ring polymers with a fixed knot type K. Through computer simulation, we discuss both finite-size and asymptotic behaviors of the gyration radius under…

Soft Condensed Matter · Physics 2009-11-07 Miyuki K. Shimamura , Tetsuo Deguchi

We study the universal characteristics of the shape of a polymer chain in an environment with correlated structural obstacles, applying the field-theoretical renormalization group approach. Our results qualitatively indicate an increase of…

Soft Condensed Matter · Physics 2010-06-03 Viktoria Blavatska , Christian von Ferber , Yurij Holovatch

We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…

Soft Condensed Matter · Physics 2015-10-21 Eunsang Lee , YounJoon Jung

Understanding how topological constraints affect the dynamics of polymers in solution is at the basis of any polymer theory and it is particularly needed for melts of rings. These polymers fold as crumpled and space-filling objects and,…

Soft Condensed Matter · Physics 2017-11-15 D. Michieletto , N. Nahali , A. Rosa

The conformational statistics of ring polymers in melts or dense solutions is strongly affected by their quenched microscopic topological state. The effect is particularly strong for untangled (i.e. non-concatenated and unknotted) rings,…

Soft Condensed Matter · Physics 2019-03-14 Raoul D. Schram , Angelo Rosa , Ralf Everaers
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