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This Perspective describes current computational efforts in the field of simulating photodynamics of transition metal complexes. We present the typical workflows and feature the strengths and limitations of the different contemporary…

Chemical Physics · Physics 2021-07-27 J. Patrick Zobel , Leticia Gonzalez

In this work, we implement a new method for imaging ultracold atoms with subwavelength resolution capabilities and determine its regime of validity. It uses the laser driven interaction between excited states to engineer hyperfine ground…

Observation of internal quantum dynamics relies on correlations between the system being observed and the measurement apparatus. We propose using the center-of-mass (c.m.) degrees of freedom of atoms and molecules as a "built-in" monitoring…

Atomic Physics · Physics 2020-07-01 A. W. Bray , U. Eichmann , S. Patchkovskii

We investigate a ionising electronic transition under resonant pumping. We demonstrate that, above a critical value of the pump intensity, a novel metastable electronic bound state is created, which can decay into the free electron…

Atomic Physics · Physics 2025-12-24 Erika Cortese , Simone De Liberato

In most cases, excited state quantum phase transitions can be associated with the existence of critical points (local extrema or saddle points) in a system's classical limit energy functional. However, an excited-state quantum phase…

Quantum Physics · Physics 2022-03-31 Jamil Khalouf-Rivera , Francisco Pérez-Bernal , Miguel Carvajal

We present precise, sub-wavelength optical intensity measurement using a single trapped $^{87}$Rb atom as a sensor. The intensity is measured by the scalar ac Stark shift it produces on the $F=1 \rightarrow F'=2$ hyperfine transition of the…

We demonstrate the effect of inter-atomic interaction in highly excited Rydberg atoms via Autler- Townes splitting in cold atoms. We measure the Autler-Townes (AT) splitting of the 5S1/2, F=2 to 5P3/2, F'=3 transition of 87Rb atoms arising…

Atomic Physics · Physics 2025-10-09 Silpa B S , Shovan Kanti Barik , Varna Shenoy , Soham Chandak , Rejish Nath , Sanjukta Roy

We investigate signatures of the excited-state quantum phase transition in the periodic dynamics of the Lipkin-Meshkov-Glick model and the Tavis-Cummings model. In the thermodynamic limit, expectation values of observables in eigenstates of…

Quantum Gases · Physics 2015-03-05 G. Engelhardt , V. M. Bastidas , W. Kopylov , T. Brandes

Direct frequency-comb spectroscopy is used to probe the absolute frequencies of $6S_{1/2}$-$8S_{1/2}$ two-photon transitions of atomic cesium in hot vapor environment. By utilizing the coherent control method of temporally splitting the…

Atomic Physics · Physics 2018-01-15 Kyung-tae Kim , Jaewook Ahn

The quantum phase transition in an atom-molecule conversion system with atomic hopping between different hyperfine states is studied. In mean field approximation, we give the phase diagram whose phase boundary only depends on the atomic…

Quantum Gases · Physics 2015-06-12 Ning-Ju Hui , Li-Hua Lu , Xiao-Qiang Xu , You-Quan Li

The two-photon transition $5S-5P-5D$ in rubidium vapor is investigated by detecting the fluorescence from the $6P_{3/2}$ state when the atomic system is excited by the combined action of a cw diode laser and a train of ultrashort pulses.…

Atomic Physics · Physics 2017-09-06 Marco P. Moreno , Giovana T. Nogueira , Daniel Felinto , Sandra S. Vianna

Based on numerical solutions of the time-dependent Schr\"odinger equation for either one or two active electrons, we propose a method for observing instantaneous level shifts in an oscillating strong infrared (IR) field in time, using a…

Atomic Physics · Physics 2015-05-28 Feng He , Camilo Ruiz , Andreas Becker , Uwe Thumm

We report on observations of coherent, sustained oscillations in the absorption of continuous-wave light at 388 nm that excites the $6S_{1/2}\rightarrow 8P_{3/2}$ transition in cesium vapor. The oscillation frequency is close to the spacing…

Atomic Physics · Physics 2024-06-18 X. Zhang , J. B. Kim , D. Antypas

A two-step, two-color laser spectroscopy technique has been used to measure the hyperfine splitting of the 7p$_{1/2}$ excited state in $^{203}$Tl and $^{205}$Tl, as well as the isotope shift within the 7s$_{1/2}$ - 7p$_{1/2}$ transition.…

Atomic Physics · Physics 2015-06-17 G. Ranjit , D. Kealhofer , G. D. Vukasin , P. K. Majumder

The ultrafast electronic structures of the charge density wave material 1T-TiSe$_2$ were investigated by high-resolution time- and angle-resolved photoemission spectroscopy. We found that the quasiparticle populations drove ultrafast…

Strongly Correlated Electrons · Physics 2023-06-02 Shaofeng Duan , Wei Xia , Chaozhi Huang , Shichong Wang , Lingxiao Gu , Haoran Liu , Dao Xiang , Dong Qian , Yanfeng Guo , Wentao Zhang

We use the density functional method to examine the properties of the nonuniform (two-phase) fluid of two-level atoms, a part of which is excited. Basing on the analysis of the equation of state of a gas of two-level atoms, a part of which…

Soft Condensed Matter · Physics 2007-05-23 Oleg Derzhko , Vasyl Myhal

We use the effective Hamiltonian that we recently fitted against the first 306 experimentally observed vibronic transitions of NO2 [J. Chem. Phys. 119, 5923 (2003)] to investigate the time domain nonadiabatic dynamics of this molecule on…

Chemical Physics · Physics 2011-11-09 Michaël Sanrey , Marc Joyeux

Quantum annealing is a way to prepare an eigenstate of the problem Hamiltonian. Starting from an eigenstate of a trivial Hamiltonian, we slowly change the Hamiltonian to the problem Hamiltonian, and the system remains in the eigenstate of…

Quantum Physics · Physics 2023-05-26 Takashi Imoto , Yuki Susa , Ryoji Miyazaki , Tadashi Kadowaki , Yuichiro Matsuzaki

We report electromagnetically induced transparency (EIT) in cold 85Rb atoms, trapped in the lower hyperfine level F = 2, of the ground state 5$^{2}S_{1/2}$ (Tiwari V B \textit{et al} 2008 {\it Phys. Rev.} A {\bf 78} 063421). Two steady…

Atomic Physics · Physics 2015-05-14 V. B. Tiwari , S. Singh , H. S. Rawat , Manoranjan P. Singh , S. C. Mehendale

Doppler-free two-photon spectroscopy is a standard technique for precision measurement of transition frequencies of dipole-forbidden transitions. The accuracy of such measurements depends critically on fitting of the spectrum to an…

Atomic Physics · Physics 2023-08-25 Bubai Rahaman , Sid C. Wright , Sourav Dutta
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