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Complete dissociation dynamics of low-energy electron attachment to carbon disulfide have been studied using the velocity slice imaging (VSI) technique. The ion yields of S- and CS- fragment ions as the function of incident electron energy…

Atomic and Molecular Clusters · Physics 2022-09-28 Anirban Paul , Dhananjay Nandi

In this paper, we discuss the dissociative electron attachment process in Ammonia. Kinetic energy and angular distributions of H^{-} and NH_{2}^{-} fragment anions across the two well known resonances at 5.5 eV and 10.5 eV are reported. The…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

In this paper, we discuss the dissociative electron attachment process in Methane. Kinetic energy and angular distributions of H^{-} and CH_{2}^{-} fragment anions across the broad resonance about 10 eV is reported. Angular distribution of…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

Complete dissociation dynamics of low energy electron attachment to ammonia molecule has been studied using velocity slice imaging (VSI) spectrometer. One low energy resonant peak around 5.5 eV and a broad resonance around 10.5 eV incident…

Atomic and Molecular Clusters · Physics 2019-09-11 Dipayan Chakraborty , Aranya Giri , Dhananjay Nandi

Exploring the molecular fragmentation dynamics induced by low-energy electrons offers compelling insights into the complex interplay between the projectile and target. In this study, we investigate the phenomenon of dissociative electron…

Atomic and Molecular Clusters · Physics 2024-01-05 Anirban Paul , Ian Carmichael , Dhananjay Nandi , Sylwia Ptasinska , Dipayan Chakraborty

Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…

Atomic Physics · Physics 2020-12-02 V. Laporta , I. F. Schneider , J. Tennyson

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

Atomic and Molecular Clusters · Physics 2015-02-10 Pamir Nag , Dhananjay Nandi

In this paper, we discuss the dissociative electron attachment process in Formic Acid and Propyl Amine. These are molecules containing more than one functional group and have low symmetry (Cs group). We measured the kinetic energy and…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

We report the detailed dynamics of the site selectivity observed in the dissociative electron attachment (DEA) process in ethanol based on the momentum images obtained using the velocity slice imaging technique. The H- dissociation channel…

Chemical Physics · Physics 2023-08-15 Sukanta Das , Suvasis Swain , Vaibhav S. Prabhudesai

We reported an imaging study of the dissociation dynamics of temporary negative ion N2O- formed in the low-energy electron attachment, e- + N2O -> N2O- -> N2 + O-. With the help of ab initio molecular dynamics calculations, the evolution of…

Chemical Physics · Physics 2015-06-11 Lei Xia , Bin Wu , Hong-Kai Li , Xian-Jin Zeng , Shan Xi Tian

Complete dissociation dynamics of low energy electron attachment to nitrogen dioxide around 8.5 eV resonance has been studied using a velocity map imaging (VMI) spectrometer. Besides the three prominent resonant peaks at around 1.4 eV, 3.1…

Atomic and Molecular Clusters · Physics 2023-04-25 Anirban Paul , Dipayan Biswas , Dhananjay Nandi

Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV…

Dissociative electron attachment, that is, the cleavage of chemical bonds induced by low-energy electrons, is difficult to model with standard quantum-chemical methods because the involved anions are not bound but subject to autodetachment.…

Chemical Physics · Physics 2022-10-03 Jerryman A. Gyamfi , Thomas -C. Jagau

In the present paper, we report the details of the kinetic energy and angular distributions of the H^{-}, S^{-}/SH^{-} fragment ions produced due to dissociative electron attachment in H_{2}S molecules at resonances peaking at 2.2 eV, 5.2…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , E. Krishnakumar

The optical emission spectrum of acetylene excited by monoenergetic electrons was studied in the range of 190 nm to 660 nm. The dissociative excitation and dissociative ionization associated with excitation of the ions initiated by electron…

Atomic Physics · Physics 2022-12-12 Juraj Országh , Marián Danko , Peter Čechvala , Štefan Matejčík

Using the velocity map imaging technique, we studied and characterized the process of Dissociative Electron Attachment (DEA) in polyatomic molecules like Water, Hydrogen Sulphide, Ammonia, Methane, Formic Acid and Propyl Amine. We present…

Chemical Physics · Physics 2010-07-30 N. Bhargava Ram , V. S. Prabhudesai , E. Krishnakumar

We study the electron-impact induced ionization of O$_{2}$ from threshold to 120 eV using the electron spectroscopy method. Our approach is simple in concept and embodies the ion source with a collision chamber and a mass spectrometer with…

Atomic Physics · Physics 2021-04-23 R. A. Lomsadze , M. R. Gochitashvili , R. Ya. Kezerashvili , M. Schulz

We experimentally probe electron collisions with HC$_3$N in the energy range from 0 to 10 eV with the focus on vibrational excitation and dissociative electron attachment. The vibrational excitation cross sections show a number of…

Chemical Physics · Physics 2018-12-04 M. Ranković , P. Nag , M. Zawadzki , L. Ballauf , J. Žabka , M. Polášek , J. Kočišek , J. Fedor

We present the development and performance of a newly built recoil ion momentum spectrometer to study the fragmentation dynamics of ionized molecules. The spectrometer is based on the two-stage Wiley-McLaren geometry and satisfies both time…

Atomic Physics · Physics 2022-11-23 Avijit Duley , Rohit Tyagi , Sandeep B. Bari , A. H. Kelkar

The fragmentation of 1-propanol resulting from dissociative electron attachment has been explored across an energy range of 3.5 to 16 eV. Four distinct ion species are identified: $\text{H}^{-}$, $\text{O}^{-}$, $\text{OH}^{-}$, and…

Atomic and Molecular Clusters · Physics 2026-02-06 Soumya Ghosh , Dipayan Chakraborty , Anirban Paul , Dhananjay Nandi
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