Related papers: Deuterated methanol in the pre-stellar core L1544

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…

Pre-stellar cores represent the earliest stage of the star- and planet-formation process. By characterizing the physical and chemical structure of these cores we can establish the initial conditions for star and planet formation and…

Methanol is a seed species of complex organic molecules that is of fundamental importance in astrochemistry. Although various isotopologues of CH$_3$OH have been detected in the interstellar medium (ISM), CH$_{3}$$^{17}$OH is only…

Solar-type protostars harbor highly deuterated complex organics. While this degree of deuteration may provide important clues in studying the formation of these species, spectroscopic information on multiply deuterated isotopologs is often…

The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally…

The circumstellar environments of objects on the asymptotic giant branch and beyond are rich in molecular species. Nevertheless, methanol has never been detected in such an object, and is therefore often taken as a clear signpost for a…

We present 247-GHz molecular line observations of methanol (CH$_3$OH) toward sixteen massive star-forming regions, using the APEX telescope with an angular resolution of $25''$. The sample covers a range of evolutionary states, including…

The detection of complex organic molecules (COMs) toward cold sources such as pre-stellar cores (with T<10 K), has challenged our understanding of the formation processes of COMs in the interstellar medium. Recent modelling on COM chemistry…

Observations with the Short Wavelength Spectrometer (SWS) onboard the {\it Infrared Space Observatory} (ISO) have led to the first detection of the methyl radical ${\rm CH_3}$ in the interstellar medium. The $\nu_2$ $Q-$branch at 16.5…

Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…

The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice…

Methanol, one of the simplest complex organic molecules in the Interstellar Medium (ISM), has been shown to be present and extended in cold environments such as starless cores. We aim at studying methanol emission across several starless…

Solar-type prestellar cores and protostars display large amounts of deuterated organic molecules. Recent findings on CHD$_2$OH and CD$_3$OH toward IRAS 16293-2422 suggest that even fully deuterated methanol, CD$_3$OD, may be detectable as…

We have measured the deuterium fractionation (through the column density ratio N(N2D+)/N(N2H+)) and the CO depletion factor (ratio between expected and observed CO abundance) in a sample of 10 high-mass protostellar candidates, in order to…

Understanding the depletion of heavy elements is a fundamental step towards determining the structure of pre-protostellar cores just prior to collapse. We study the dependence of the NO abundance on position in the pre-protostellar cores…

The maps presented in Paper I are here used to infer the variation of the column densities of HCO+, DCO+, N2H+, and N2D+ as a function of distance from the dust peak. These results are interpreted with the aid of a crude chemical model…

We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um…

Recent studies suggest that infrared dark clouds (IRDCs) have the potential of harboring the earliest stages of massive star formation and indeed evidence for this is found toward distinct regions within them. We present a study with the…

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH$_3$OH) as an alternative route for the production of H$_3^+$ in dense clouds. The measurements were taken at…

We present observations of methanol lines in a sample of Class 0 low mass protostars. Using a 1-D radiative transfer model, we derive the abundances in the envelopes. In two sources of the sample, the observations can only be reproduced by…