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We consider a model for a polymer chain interacting with a sequence of equispaced flat interfaces through a pinning potential. The intensity $\delta \in \mathbb {R}$ of the pinning interaction is constant, while the interface spacing…

Probability · Mathematics 2009-10-26 Francesco Caravenna , Nicolas Pétrélis

This work introduces a methodology for the statistical mechanical analysis of polymeric chains under tension controlled by optical or magnetic tweezers at thermal equilibrium with an embedding fluid medium. The response of single bonds…

Soft Condensed Matter · Physics 2020-02-26 Aaron C. Meyer , Yahya Öz , Norman Gundlach , Michael Karbach , Ping Lu , Gerhard Müller

We present an analytical theory for heteropolymer deformation, as exemplified experimentally by stretching of single protein molecules. Using a mean-field replica theory, we determine phase diagrams for stress-induced unfolding of typical…

Statistical Mechanics · Physics 2009-11-07 Phillip L. Geissler , Eugene I. Shakhnovich

We examine entanglements using monomer contacts between pairs of chains in a Brownian-dynamics simulation of a polymer melt. A map of contact positions with respect to the contacting monomer numbers (i,j) shows clustering in small regions…

Condensed Matter · Physics 2009-10-28 E. Ben-Naim , G. S. Grest , T. A. Witten , A. R. C. Baljon

The effects of two types of randomness on the behaviour of directed polymers are discussed in this chapter. The first part deals with the effect of randomness in medium so that a directed polymer feels a random external potential. The…

Statistical Mechanics · Physics 2007-05-23 Somendra M. Bhattacharjee

We consider a model of a polymer in $\mathbb{Z}^{d+1}$, constrained to join 0 and a hyperplane at distance $N$. The polymer is subject to a quenched nonnegative random environment. Alternatively, the model describes crossing random walks in…

Probability · Mathematics 2012-04-11 Dmitry Ioffe , Yvan Velenik

We study the so-called pinning model, which describes the behavior of a Markov chain interacting with a distinguished state. The interaction depends on an external source of randomness, called disorder, which can attract or repel the Markov…

Probability · Mathematics 2023-02-27 Niccolo Torri

Nanochains of atoms, molecules and polymers have gained recent interest in the experimental sciences. This article contributes to an advanced mathematical modeling of the mechanical properties of nanochains that allow for heterogenities,…

Analysis of PDEs · Mathematics 2019-09-17 Laura Lauerbach , Stefan Neukamm , Mathias Schäffner , Anja Schlömerkemper

In this chapter we review the rich behavior of polymer chains embedded in a quenched random environment. We first consider the problem of a Gaussian chain free to move in a random potential with short-ranged correlations. We derive the…

Disordered Systems and Neural Networks · Physics 2007-05-23 Yadin Y. Goldschmidt , Yohannes Shiferaw

We study the probability that two directed polymers in the same random potential do not intersect. We use the replica method to map the problem onto the attractive Lieb-Liniger model with generalized statistics between particles. We obtain…

Disordered Systems and Neural Networks · Physics 2016-05-03 Andrea De Luca , Pierre Le Doussal

A theory is presented for the binding of small molecules such as surfactants to semiflexible polymers. The persistence length is assumed to be large compared to the monomer size but much smaller than the total chain length. Such polymers…

Soft Condensed Matter · Physics 2009-09-25 Haim Diamant , David Andelman

The results obtained from molecular dynamics simulations of the friction at an interface between polymer melts and weakly attractive crystalline surfaces are reported. We consider a coarse-grained bead-spring model of linear chains with…

Soft Condensed Matter · Physics 2012-06-12 Nikolai V. Priezjev

There are many proteins or protein complexes which have multiple DNA binding domains. This allows them to bind to multiple points on a DNA molecule (or chromatin fibre) at the same time. There are also many proteins which have been found to…

Soft Condensed Matter · Physics 2020-06-24 C. A. Brackley

We study the influence of some quenched disorder in the sequence of monomers on the entropic elasticity of long polymeric chains. Starting from the Kratky-Porod model, we show numerically that some randomness in the favoured angles between…

Statistical Mechanics · Physics 2009-10-30 D. Bensimon , D. Dohmi , M. Mezard

After a general introduction to the field, we describe some recent results concerning disorder effects on both `random walk models', where the random walk is a dynamical process generated by local transition rules, and on `polymer models',…

Disordered Systems and Neural Networks · Physics 2007-05-23 Cecile Monthus

The dynamical response of a tethered semiflexible polymer with self-attractive interactions and subjected to an external force field is numerically investigated by varying stiffness and self-interaction strength. The chain is confined in…

Soft Condensed Matter · Physics 2022-11-09 A. Lamura

We propose a new toy model of a heteropolymer chain capable of forming planar secondary structures typical for RNA molecules. In this model the sequential intervals between neighboring monomers along a chain are considered as quenched…

Soft Condensed Matter · Physics 2014-01-07 S. K. Nechaev , A. N. Sobolevski , O. V. Valba

Topological entanglements in polymers are mimicked by sliding rings (slip-links) which enforce pair contacts between monomers. We study the force-extension curve for linear polymers in which slip-links create additional loops of variable…

Statistical Mechanics · Physics 2009-11-07 Ralf Metzler , Yacov Kantor , Mehran Kardar

These notes are devoted to the statistical mechanics of directed polymers interacting with one-dimensional spatial defects. We are interested in particular in the situation where frozen disorder is present. These polymer models undergo a…

Probability · Mathematics 2008-06-10 F. Toninelli

The equilibrium statistical mechanics of classical directed polymers in 2 dimensions is well known to be equivalent to the imaginary-time quantum dynamics of a 1+1-dimensional many-particle system, with polymer configurations corresponding…

Soft Condensed Matter · Physics 2013-05-30 D. Zeb Rocklin , Shina Tan , Paul M. Goldbart