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The behavior as a function of temperature of very thin films (10 to 200 nm) of pentylcyanobiphenyl (5CB) on silicon substrates is reported. In the vicinity of the nematic/isotropic transition we observe a coexistence of two regions of…

Soft Condensed Matter · Physics 2009-11-07 D. van Effenterre , R. Ober , M. P. Valignat , A. M. Cazabat

A series of asymmetric dimers with an odd number of atoms in the spacer were found to form different types of twisted structures despite being achiral. The formation of a variety of helical structures is accompanied by a gradual freezing of…

The short-range order which remains when the isotropic to smectic-A transition is perturbed by a gel of silica nanoparticles (aerosils) has been studied using high-resolution synchrotron x-ray diffraction. The gels have been created…

Soft Condensed Matter · Physics 2009-11-10 M. K. Ramazanoglu , P. S. Clegg , R. J. Birgeneau , C. W. Garland , M. E. Neubert , J. M. Kim

Ferroelectric nematic (NF) phase and related polar liquid-crystalline phases form a new class of strongly polarized yet fluid soft matter. Well-recognized heliconical ferroelectric phases such as NTBF and SmC_P^H exist, but their…

Soft Condensed Matter · Physics 2026-05-01 Hiroya Nishikawa , Dennis Kwaria , Atsuko Nihonyanagi , Koki Sano , Hiroyuki Yoshida , Fumito Araoka

We present a statistical mechanics approximation scheme for the explicit treatment of spacer-mediated configurational correlations among the mesogenic units that form a dimer molecule. The approximation is applied to the description of the…

Soft Condensed Matter · Physics 2007-05-23 P. K. Karahaliou , A. G. Vanakaras , D. J. Photinos

Optical birefringence and light absorption measurements reveal four regimes for the thermotropic behavior of a nematogen liquid (7CB) upon sequential filling of parallel-aligned capillaries of 12 nm diameter in a monolithic, mesoporous…

Soft Condensed Matter · Physics 2013-04-08 Patrick Huber , Mark Busch , Sylwia Calus , Andriy V. Kityk

The effects of multiwalled carbon nanotubes (NTs) on low-temperature phase transformations in 5CB were studied by means of differential scanning calorimetry (DSC), low-temperature photoluminescence and measurements of electrical…

Soft Condensed Matter · Physics 2015-06-15 N. Lebovka , V. Melnyk , Ye. Mamunya , G. Klishevich , A. Goncharuk , N. Pivovarova

The intrinsic property of proteins to form structural motifs such as alpha-helices and beta-sheets leads to a complex phase behavior in which proteins can assemble into various types of aggregates including crystals, liquidlike phases of…

Biomolecules · Quantitative Biology 2010-06-08 Stefan Auer , Dimo Kashchiev

The recently discovered heliconical ferroelectric nematic (NTBF) phase is a unique example of spontaneous chiral symmetry breaking in a proper ferroelectric fluid. In this study, we investigate four homologous series of mesogenic compounds,…

Soft Condensed Matter · Physics 2025-08-12 Grant J. Strachan , Ewa Górecka , Damian Pociecha

A differential scanning calorimetric technique has been used to obtain solid-liquid equilibrium temperatures for the mixtures naphthalene or biphenyl + 1-tetradecanol, or + 1-hexadecanol. All the systems show a simple eutectic point, whose…

We propose an approach to a multiscale problem in the theory of thermotropic uniaxial nematics based on the method of statistical field theory. This approach enables us to relate the coefficients $A$, $B$, $C$, $L_1$ and $L_2$ of the…

Statistical Mechanics · Physics 2018-01-29 Bing-Sui Lu

Hexakis(n-alkyloxy)triphenylene) (HATn) consisting of an aromatic triphenylene core and alkyl side chains are model discotic liquid crystal (DLC) systems forming a columnar mesophase. In the mesophase, the molecules of HATn self-assemble in…

Soft Condensed Matter · Physics 2022-05-06 Arda Yildirim , Christina Krause , Patrick Huber , Andreas Schönhals

NMR measurements on a selectively deuteriated liquid crystal dimer CB-C9-CB exhibiting two nematic phases show that the molecules in the lower temperature nematic phase, Nx, experience a chiral environment and are ordered about a unique…

Soft Condensed Matter · Physics 2014-07-09 Anke Hoffmann , Alexandros G. Vanakaras , Alexandra Kohlmeier , Georg H. Mehl , Demetri J. Photinos

Molecular nitrogen exhibits remarkable structural diversity near the polymeric transition, where multiple phases are metastable. Here, we report two new molecular phases. The first, $t\zeta$-N$_2$, is a polytype of monoclinic $C2/c$…

Investigations of the phase diagram of biaxial liquid crystal systems through analyses of general Hamiltonian models within the simplifications of mean-field theory (MFT), as well as by computer simulations based on microscopic models, are…

Soft Condensed Matter · Physics 2015-09-15 B. Kamala Latha , Regina Jose , K. P. N. Murthy , V. S. S. Sastry

We study the phase diagram of isospin-asymmetrical nuclear matter in the density-temperature plane, allowing for four competing phases of nuclear matter: (i) the unpaired phase, (ii) the translationally and rotationally symmetric, but…

Nuclear Theory · Physics 2014-12-19 Martin Stein , Armen Sedrakian , Xu-Guang Huang , John W. Clark

Aiming to simulate the radiation damage effect on a dual alpha+beta phase Ti-6Al-4V alloy utilized as high-intensity accelerator beam window material, a series of irradiation experiments were conducted with a 2.8 MeV-Fe^2+ ion beam in…

Materials Science · Physics 2024-09-04 Taku Ishida , Sho Kano , Eiichi Wakai , Tamaki Shibayama , Shunsuke Makimura , Hiroaki Abe

Ionic liquid crystals (ILCs) are anisotropic mesogenic molecules which carry charges and therefore combine properties of liquid crystals, e.g., the formation of mesophases, and of ionic liquids, such as low melting temperatures and tiny…

Soft Condensed Matter · Physics 2017-10-31 Hendrik Bartsch , Markus Bier , Siegfried Dietrich

The discovery of the ferroelectric nematic phase has brought with it a plethora of new polar liquid crystalline phases. One in particular is the anti-ferroelectric smectic A SmA\textsubscript{AF} phase. In this letter we show via…

We report the synthesis, and structural and physical properties of CaFe4As3 single crystals. Needle-like single crystals of CaFe4As3 were grown out of Sn flux and the compound adopts an orthorhombic structure as determined by X-ray…

Superconductivity · Physics 2015-05-27 A. B. Karki , G. T. McCandless , S. Stadler , Y. M. Xiong , J. Li , Julia Y. Chan , R. Jin