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Silicon materials play a key role in many technologically relevant fields, ranging from the electronic to the photovoltaic industry. A systematic search for silicon allotropes was performed by employing a modified ab initio minima hopping…

We present state-of-the-art first-principle calculations of the electronic and optical properties of silicon allotropes with interesting characteristics for applications in thin-film solar cells. These new phases consist of distorted sp$^3$…

Despite the recent progress on two-dimensional multilayer materials (2DMM) with weak interlayer interactions, the investigation on 2DMM with strong interlayer interactions is far from its sufficiency. Here we report on first-principles…

Mesoscale and Nanoscale Physics · Physics 2015-11-26 Zhi-Xin Guo , Yue-Yu Zhang , Hongjun Xiang , Xin-Gao Gong , Atsushi Oshiyama

Silicene, the silicon equivalent of graphene, is attracting increasing scientific and technological attention in view of the exploitation of its exotic electronic properties. This novel material has been theoretically predicted to exist as…

Materials Science · Physics 2023-06-30 Paolo Moras , Tevfik Onur Menteş , Polina M. Sheverdyaeva , Andrea Locatelli , Carlo Carbone

This article reviews silicene, a relatively new allotrope of silicon, which can also be viewed as the silicon version of graphene. Graphene is a two-dimensional material with unique electronic properties qualitatively different from those…

Materials Science · Physics 2014-04-24 L. C. Lew Yan Voon , G. G. Guzmán-Verri

Silicene, the two-dimensional allotrope of silicon, is predicted to exist in a low-buckled honeycomb lattice, characterized by semimetallic electronic bands with graphenelike energy-momentum dispersions around the Fermi level (represented…

Materials Science · Physics 2018-01-10 A. Sindona , A. Cupolillo , F. Alessandro , M. Pisarra , D. C. Coello Fiallos , S. M. Osman , L. S. Caputi

Layered IV-VI$_2$ compounds often exist in the CdI$_2$ structure. Using the evolution algorithm and first-principles calculations, we predict a novel layered structure of silicon ditelluride (SiTe$_2$) that is more stable than the CdI$_2$…

Materials Science · Physics 2020-04-27 Romakanta Bhattarai , Xiao Shen

Silicene, a monolayer of silicon atoms tightly packed into a two-dimensional honeycomb lattice, is the challenging hypothetical reflection in the silicon realm of graphene, a one-atom thick graphite sheet, presently the hottest material in…

Materials Science · Physics 2008-11-18 A. Kara , C. Leandri , M. E. Davila , P. de Padova , B. Ealet , H. Oughaddou , B. Aufray , G. Le Lay

Silicon (Si) is one of the most extensively studied materials owing to its significance to semiconductor science and technology. While efforts to find a new three-dimensional (3D) Si crystal with unusual properties have made some progress,…

Materials Science · Physics 2018-02-23 Kisung Chae , Duck Young Kim , Young-Woo Son

Silicene, the two-dimensional (2D) allotrope of silicon has very recently attracted a lot of attention. It has a structure that is similar to graphene and it is theoretically predicted to show the same kind of electronic properties which…

Materials Science · Physics 2017-12-07 W. Wang , W. Olovsson , R. I. G. Uhrberg

Successful isolation of graphene from graphite opened a new era for material science and con- densed matter physics. Due to this remarkable achievement, there has been an immense interest to synthesize new two dimensional materials and to…

Mesoscale and Nanoscale Physics · Physics 2016-08-11 Mehmet Yagmurcukardes , Cihan Bacaksiz , Fadıl Iyikanat , Engin Torun , R. Tugrul Senger , Francois M. Peeters , Hasan Sahin

Low-buckled silicene, germanene, and stanene are group$-IV$ graphene allotropes. They form a honeycomb lattice out of two interpenetrating ($A$ and $B$) triangular sublattices that are vertically separated by a small distance $\Delta_z$.…

Materials Science · Physics 2023-06-02 John M. Davis , Gustavo S. Orozco-Galvan , Salvador Barraza-Lopez

We report the prediction of metallic quasione-dimensional $sp^{3}$-hybridized silicon allotropes in the form of prismanes. Silicon prismanes or polysilaprismanes are the silicon nanotubes of a special type constructed from the…

Materials Science · Physics 2019-02-26 Konstantin Katin , Konstantin Grishakov , Margarita Gimaldinova , Mikhail Maslov

In our present work, five previously proposed sp$^3$ carbon crystals were suggested as silicon allotropes and their stabilities, electronic and optical properties were investigated by first-principles method. We find that these allotropes…

Materials Science · Physics 2017-01-19 Chaoyu He , Jin Li , xiangyang Peng , Lijun Meng , Chao Tang , Jianxin Zhong

Silicon, one of the most abundant elements found on Earth, has been an excellent choice of the semiconductor industry for ages. Despite it's remarkable applications in modern semiconductor-based electronic devices, the potential of cubic…

Superconductivity · Physics 2022-06-29 Monika Moun , Goutam Sheet

Silica or SiO$_2$, the main constituent of earth's rocks has several 3D complex crystalline and amorphous phases, but it does not have a graphite like layered structure in 3D. Our theoretical analysis and numerical calculations from the…

Mesoscale and Nanoscale Physics · Physics 2014-06-24 V. Ongun Özçelik , S. Cahangirov , S. Ciraci

The interaction of silicene with Si, C, H, O, Ti atoms along with H$_2$, H$_2$O and O$_2$ molecules are investigated and the induced functionalities thereof are analyzed using first principles density functional theory. Si adatom initially…

Materials Science · Physics 2013-11-27 V. Ongun Özçelik , S. Ciraci

Silicene, as the silicon analog of graphene, has been successfully fabricated by epitaxial growing on various substrates. Similar to free-standing graphene, free-standing silicene possesses a honeycomb structure and Dirac-cone-shaped energy…

Materials Science · Physics 2015-09-02 Hongxia Zhong , Ruge Quhe , Yangyang Wang , Junjie Shi , Jing Lu

Silicene, an analogue of graphene, was so far predicted to be the only two-dimensional silicon (2D-Si) with massless Dirac fermions. Here we predict a brand new 2D-Si Dirac semimetal, which we name siliconeet [silik'ni:t]. Unexpectedly, it…

On basis of the first principle calculation we show that a crystalline structure of silicon, as a novel allotrope with nanotubular holes along two perpendicular directions, is stable. The calculations on geometrical and electronic…

Materials Science · Physics 2011-06-16 Chi-Pui Tang , Jie Cao , Shi-Jie Xiong
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