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The multi-layer multiconfiguration time-dependent Hartree (ML-MCTDH) approach suffers from numerical instabilities whenever the wavefunction is weakly entangled. These instabilities arise from singularities in the equations of motion (EOMs)…

Chemical Physics · Physics 2024-06-19 Lachlan P. Lindoy , Benedikt Kloss , David R. Reichman

We present a new charge self-consistent scheme combining Density Functional and Dynamical Mean Field Theory, which uses Green's function of multiple scattering-type. In this implementation the many-body effects are incorporated into the…

Strongly Correlated Electrons · Physics 2017-10-11 A. Östlin , L. Vitos , L. Chioncel

Ground-state properties of the non-interacting symmetric single-impurity Anderson model (SIAM) are derived from the corresponding eigenenergy equation. Explicit formulae are given for the ground-state energy, the hybridization, and the…

Strongly Correlated Electrons · Physics 2015-12-02 Zakaria M. M. Mahmoud , Florian Gebhard

We present an embedding approach based on localized basis functions which permits an efficient application of the dynamical mean field theory (DMFT) to inhomogeneous correlated materials, such as semi-infinite surfaces and heterostructures.…

Strongly Correlated Electrons · Physics 2009-11-13 H. Ishida , A. Liebsch

The Ziegler-Rauk-Baerends multiplet sum method (MSM) assumes that density-functional theory (DFT) provides a good description of states dominated by a single determinant. It then uses symmetry to add static correlation to DFT. In our…

Chemical Physics · Physics 2025-04-15 Mark E. Casida , Abraham Ponra , Carolyne Bakasa , Anne Justine Etindele

The formalism for exactly calculating the retarded and advanced Green's functions of strongly correlated lattice models in a uniform electric field is derived within dynamical mean-field theory. To illustrate the method, we solve for the…

Strongly Correlated Electrons · Physics 2009-07-09 A. V. Joura , J. K. Freericks , Th. Pruschke

In this paper we consider the numerical solution of the Hamiltonian wave equation in two spatial dimension. We use the Mimetic Finite Difference (MFD) method to approximate the continuous problem combined with a symplectic integration in…

Numerical Analysis · Mathematics 2016-08-04 Lourenco Beirao da Veiga , Luciano Lopez , Giuseppe Vacca

DFT calculations have become widespread in both chemistry and materials, because they usually provide useful accuracy at much lower computational cost than wavefunction-based methods. All practical DFT calculations require an approximation…

Chemical Physics · Physics 2022-03-15 Eunji Sim , Suhwan Song , Stefan Vuckovic , Kieron Burke

In this contribution, we extend our framework for analyzing and visualizing correlated many-electron dynamics to non-variational, highly scalable electronic structure method. Specifically, an explicitly time-dependent electronic wave packet…

Chemical Physics · Physics 2017-04-27 Gunter Hermann , Vincent Pohl , Jean Christophe Tremblay

Time-dependent density-functional theory (TDDFT) is a central tool for studying the dynamical electronic structure of molecules and solids, yet aspects of its mathematical foundations remain insufficiently understood. In this work, we…

For classical many-body systems subject to Brownian dynamics we develop a superadiabatic dynamical density functional theory (DDFT) for the description of inhomogeneous fluids out-of-equilibrium. By explicitly incorporating the dynamics of…

Soft Condensed Matter · Physics 2022-12-20 S. M. Tschopp , J. M. Brader

We generalized the recently introduced new impurity solver based on the diagrammatic expansion around the atomic limit and Quantum Monte Carlo summation of the diagrams. We present generalization to the cluster of impurities, which is at…

Strongly Correlated Electrons · Physics 2009-11-11 Kristjan Haule

The $N$-particle wavefunction has too many dimensions for a direct time propagation of a many-body system according to the time-dependent Schr\"odinger equation (TDSE). On the other hand, time-dependent density functional theory (TDDFT)…

Computational Physics · Physics 2017-11-21 M. Brics , J. Rapp , D. Bauer

We study the effect of spatially nonlocal correlations on the nonequilibrium dynamics of interacting fermions by constructing the nonequilibrium dynamical cluster theory, a cluster generalization of the nonequilibrium dynamical mean-field…

Strongly Correlated Electrons · Physics 2015-07-13 Naoto Tsuji , Peter Barmettler , Hideo Aoki , Philipp Werner

We present a numerical method for the study of correlated quantum impurity problems out of equilibrium, which is particularly suited to address steady state properties within Dynamical Mean Field Theory. The approach, recently introduced in…

Strongly Correlated Electrons · Physics 2014-04-08 Antonius Dorda , Martin Nuss , Wolfgang von der Linden , Enrico Arrigoni

We present a new continuous time solver for quantum impurity models such as those relevant to dynamical mean field theory. It is based on a stochastic sampling of a perturbation expansion in the impurity-bath hybridization parameter.…

Strongly Correlated Electrons · Physics 2009-11-11 Philipp Werner , Armin Comanac , Luca De Medici , Matthias Troyer , Andrew J. Millis

The development of polynomial cost solvers for correlated quantum impurity models, with controllable errors, is a central challenge in quantum many-body physics, where these models find applications ranging from nano-science to the…

Strongly Correlated Electrons · Physics 2012-12-21 Dominika Zgid , Emanuel Gull , Garnet Chan

The time-dependent Hartree-Fock (TDHF) method is an approach to simulate the mean field dynamics of electrons within the assumption that the electrons move independently in their self-consistent average field and within the space of single…

Quantum Physics · Physics 2023-09-06 Sahil Gulania , Stephen K. Gray , Yuri Alexeev , Bo Peng , Niranjan Govind

We use analytic (current) density-potential maps of time-dependent (current) density functional theory (TD(C)DFT) to inverse engineer analytically solvable time-dependent quantum problems. In this approach the driving potential (the control…

Quantum Physics · Physics 2016-06-01 Mehdi Farzanehpour , I. V. Tokatly

This chapter concerns with the recent development of a new DFT methodology for accurate, reliable prediction of many-electron systems. Background, need for such a scheme, major difficulties encountered, as well as their potential remedies…

Chemical Physics · Physics 2019-04-19 Amlan K. Roy