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We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

Interfacial hydration structures are crucial in wide-ranging applications, including battery, colloid, lubrication etc. Multivalent ions like Mg2+ and La3+ show irreplaceable roles in these applications, which are hypothesized due to their…

Chemical Physics · Physics 2024-06-28 Han Li , Zhi Xu , Jiacheng Li , Alessandro Siria , Ming Ma

The ionization of atoms and molecules by strong laser fields has been studied extensively, both theoretically and experimentally. The strong-field approximation (SFA) allows for the analytical solution of the Schr\"{o}dinger equation and…

Atomic Physics · Physics 2023-04-24 Danish Furekh Dar , Björn Minneker , Stephan Fritzsche

A simple, analytical, nonrelativistic ionization rate formula for atoms and positive ions in intense ultraviolet and x-ray electromagnetic fields is derived. The rate is valid at arbitrary values of the Keldysh parameter and confirmed by…

Atomic Physics · Physics 2009-11-13 S. V. Popruzhenko , V. D. Mur , V. S. Popov , D. Bauer

Interfacial thermal transport between electrodes and polymer electrolytes can play a crucial role in the thermal management of solid-state lithium-ion batteries (SLIBs). Modifying the electrode surface with functional molecules can…

Mesoscale and Nanoscale Physics · Physics 2021-07-22 Siyu Tian , Dezhao Huang , Zhihao Xu , Shiwen Wu , Tengfei Luo , Guoping Xiong

Recent high-resolution observations of metal absorption lines in high-redshift damped Ly-alpha systems have shown that Al III, a tracer of moderately-ionized gas, very often has a velocity structure indistinguishable from that of…

Astrophysics · Physics 2009-10-31 J. Christopher Howk , Kenneth R. Sembach

The solid acids CsH$_2$PO$_4$ and Cs$_7$(H$_4$PO$_4$)(H$_2$PO$_4$)$_8$ pose significant challenges for the simulation of proton transport phenomena. In this work, we use the recently developed machine-learned force field (MLFF) MACE to…

Ionic liquids are solvent-free electrolytes, some of which possess an intriguing self-assembly property. Using a mean-field framework (based on Onsager's relations) we show that bulk nano-structures arise via type-I and II phase transitions…

Soft Condensed Matter · Physics 2017-06-07 Sariel Bier , Nir Gavish , Hannes Uecker , Arik Yochelis

The Poisson-Boltzmann mean-field description of ionic solutions has been successfully used in predicting charge distributions and interactions between charged macromolecules. While the electrostatic model of charged fluids, on which the…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Daniel Harries , Rudi Podgornik

The main focus of this review is on magnetically induced anions. Before discussing these new anionic states which exclusively exist in the presence of magnetic fields, we review in some detail the anionic physics without external field. For…

Atomic Physics · Physics 2017-08-23 Victor Bezchastnov , Peter Schmelcher , Lorenz S. Cederbaum

Ionic liquids, salts in the liquid state under ambient conditions, are of great interest as precision lubricants. Ionic liquids form layered structures at surfaces, yet it is not clear how this nano-structure relates to their lubrication…

Materials Science · Physics 2017-09-13 Alexander M. Smith , Kevin R. J. Lovelock , Nitya Nand Gosvami , Tom Welton , Susan Perkin

We study the effective forces acting between colloidal particles trapped at a fluid interface which itself is exposed to a pressure field. To this end we apply what we call the ``force approach'', which relies solely on the condition of…

Soft Condensed Matter · Physics 2008-03-31 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

Electrode-electrolyte interfaces are crucial for electrochemical energy conversion and storage. At these interfaces, the liquid electrolytes form electrical double layers (EDLs). However, despite more than a century of active research, the…

Water scarcity is a dilemma facing much of the global population. Cation intercalation desalination (CID) cells, which use intercalation host compounds (IHCs) in combination with ion-exchange membranes (IEMs), could aid in addressing this…

Chemical Physics · Physics 2016-12-28 Kyle C. Smith

We present a continuum theory of electrolytes composed of a waterlike solvent and univalent ions. First, we start with a density functional $\cal F$ for the coarse-grained solvent, cation, and anion densities, including the Debye-H\"uckel…

Soft Condensed Matter · Physics 2020-08-20 Ryuichi Okamoto , Kenichiro Koga , Akira Onuki

Fundamental mechanisms of energy storage, corrosion, sensing, and multiple biological functionalities are directly coupled to electrical processes and ionic dynamics at solid-liquid interfaces. In many cases, these processes are spatially…

Materials Science · Physics 2017-01-25 Liam Collins , Jason Kilpatrick , Sergei V. Kalinin , Brian J. Rodriguez

We develop of a field-theoretic approach for the treatment of both the non-local and the non-linear response of structured liquid dielectrics. Our systems of interest are composed of dipolar solvent molecules and simple salt cations and…

Soft Condensed Matter · Physics 2022-02-01 Ralf Blossey , Rudolf Podgornik

An electron-impact ion source based on photoelectron emission was developed for ionization of gases at pressures below 1e-4 mbar in an axial magnetic field in the order of 5 T. The ion source applies only DC fields, which makes it suitable…

Instrumentation and Detectors · Physics 2011-01-25 S. Lukic , B. Bornschein , G. Drexlin , F. Glück , O. Kazachenko , M. Schöppner , Ch. Weinheimer , M. C. R. Zoll

The origin of enhanced reactivity in aqueous microdroplets remains debated, with interfacial electric fields (IEFs) often invoked as catalytic drivers. Here, we provide a quantum-mechanical, spatially resolved characterization of the…

We present a theoretical study of the influence of the molecular geometry of the cation on the response of ionic liquid (IL) to confinement and mechanical strain. The so-called {\it tailed} model includes a large spherical anion and…

Soft Condensed Matter · Physics 2019-03-27 Miljan Dašić , Igor Stanković , Konstantinos Gkagkas