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Related papers: Simple Formula for Marcus-Hush-Chidsey Kinetics

200 papers

The voltammetry for the reduction of oxygen at a microdisc electrode is reported in two room temperature ionic liquids: 1-butyl-1-methylpyyrolidinium bis(trifluoromethylsulfonyl) imide ([Bmpyrr][NTf2]) and trihexyltetradecylphosphonium…

Chemical Physics · Physics 2015-03-06 Eden E. L. Tanner , Linhongjia Xiong , Edward O. Barnes , Richard G. Compton

Density functionals with a range-separated treatment of the exchange energy are known to improve upon their semilocal forerunners and fixed-fraction hybrids. The conversion of a given semilocal functional into its short-range analog is not…

Chemical Physics · Physics 2019-09-09 Dimitri N. Laikov

We have studied theoretically the tunneling between two edges of Quantum Hall liquids (QHL) of different filling factors, $\nu_{0,1}=1/(2 m_{0,1}+1)$, with $m_0 \geq m_1\geq 0$, through two separate point contacts in the geometry of…

Strongly Correlated Electrons · Physics 2010-05-11 Vadim V. Ponomarenko , Dmitri V. Averin

Inclusive electron scattering off 4He is investigated for low and medium energy and momentum transfers. The final state interaction, given by the simple semirealistic Malfliet-Tjon potential, is treated rigorously applying the Lorentz…

We use the quantum threshold laws combined with a classical capture model to provide an analytical estimate of the chemical quenching cross sections and rate coefficients of two colliding particles at ultralow temperatures. We apply this…

Atomic Physics · Physics 2010-02-05 Goulven Quéméner , John L. Bohn

According to Landau's Fermi liquid theory, the main properties of the quasiparticle excitations of an electron gas are embodied in the effective mass $m^*$, which determines the energy of a single quasiparticle, and the Landau interaction…

Strongly Correlated Electrons · Physics 2021-08-25 Sam Azadi , N. D. Drummond , W. M. C. Foulkes

Marcus theory is the workhorse of theoretical chemistry for predicting the rates of charge and energy transfer. Marcus theory overwhelmingly agrees with experiment -- both in terms of electron transfer and triplet energy transfer -- for the…

Chemical Physics · Physics 2025-10-15 D. Vale Cofer-Shabica , Jennifer R. DeRosa , Joseph E. Subotnik

Context. We introduce a model for including accelerated particles in pure magnetohydrodynamics (MHD) simulations of the solar atmosphere. Aims. We show that the method is viable and produces results that enhance the realism of MHD…

Solar and Stellar Astrophysics · Physics 2018-12-05 Helle Bakke , Lars Frogner , Boris Vilhelm Gudiksen

Particle-in-cell with Monte Carlo collisions (PIC/MCC) is a fully kinetic, particle based numerical simulation method with increasing popularity in the field of low temperature gas discharge physics. Already in its simplest form…

Plasma Physics · Physics 2022-06-15 Mate Vass , Peter Palla , Peter Hartmann

A nonperturbative electron transfer rate theory is developed based on the reduced density matrix dynamics, which can be evaluated readily for the Debye solvent model without further approximation. Not only does it recover for reaction rates…

Quantum Physics · Physics 2007-05-23 Ping Han , Rui-Xue Xu , Baiqing Li , Jian Xu , Ping Cui , Yan Mo , YiJing Yan

A fast inverse heat conduction model (IHCM) is developed for estimating unknown properties of multi-layer composites considering internal heat generation. This work builds on the validated analytical forward models presented in Part I.…

Applied Physics · Physics 2025-07-10 Gan Fu , Mitrofan Curti , Calina Ciuhu , Elena A. Lomonova

We investigate the behavior of the kinetic and the exchange energy densities near the nuclear cusp of atomic systems. Considering hydrogenic orbitals, we derive analytical expressions near the nucleus, for single shells, as well as in the…

Other Condensed Matter · Physics 2016-04-01 L. A. Constantin , E. Fabiano , F. Della Sala

An ultracold gas of heteronuclear alkali dimer molecules with hyperfine structure loaded into a one-dimensional optical lattice is investigated. The \emph{Hyperfine Molecular Hubbard Hamiltonian} (HMHH), an effective low-energy lattice…

Quantum Gases · Physics 2015-03-13 M. L. Wall , L. D. Carr

In this paper we discuss two approximate methods previously suggested for modeling hyperfine spectral line emission for molecules whose collisional transitions rates between hyperfine levels are unknown. Hyperfine structure is seen in the…

Astrophysics of Galaxies · Physics 2015-05-18 Eric Keto , George Rybicki

We present a theory of out-of-equilibrium ultrafast spin dynamics in magnetic heterostructures based on the s-d model of ferromagnetism. Both in the bulk and across interfaces, the exchange processes between the itinerant s and the…

Mesoscale and Nanoscale Physics · Physics 2015-12-02 Erlend G. Tveten , Arne Brataas , Yaroslav Tserkovnyak

Electron transfer (ET) across molecular chains including an impurity is studied based on a recently improved real-time path integral Monte Carlo (PIMC) approach [J. Chem. Phys. {\bf 121}, 12696 (2004)]. The reduced electronic dynamics is…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Lothar Muehlbacher , Joachim Ankerhold

The recently introduced method of excess collisions (MEC) is modified to estimate diffusion-controlled reaction times inside systems of arbitrary size. The resulting MEC-E equations contain a set of empirical parameters, which have to be…

Biological Physics · Physics 2009-11-11 Holger Merlitz , Konstantin V. Klenin , Chen-Xu Wu , Jörg Langowski

Because of large spatial separation of the Mn atoms in Heusler alloys the Mn 3d states belonging to different atoms do not overlap considerably. Therefore an indirect exchange interaction between Mn atoms should play a crucial role in the…

Materials Science · Physics 2009-11-13 E. Sasioglu , L. M. Sandratskii , P. Bruno

This paper studies the nonlinear evolution of magnetic field turbulence in proximity of steady ideal MHD configurations characterized by a small electric current, a small plasma flow, and approximate flux surfaces, a physical setting that…

Plasma Physics · Physics 2024-09-12 Naoki Sato , Michio Yamada

Explicitly correlated quantum chemical calculations require calculations of five types of molecular integrals beyond the standard electron repulsion integrals. We present a novel scheme, which utilises general ideas of the…

Chemical Physics · Physics 2015-04-14 Michał Silkowski , Michał Lesiuk , Robert Moszynski