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A considerable body of experimental and theoretical work claims the existence of negative absolute temperatures in spin systems and ultra-cold quantum gases. Here, we clarify that such findings can be attributed to the use of a popular yet…

Statistical Mechanics · Physics 2015-06-15 Jörn Dunkel , Stefan Hilbert

Do negative absolute temperatures matter physics and specifically Statistical Physics? We provide evidence that we can certainly answer positively to this vexata quaestio. The great majority of models investigated by statistical mechanics…

Statistical Mechanics · Physics 2021-07-07 Marco Baldovin , Stefano Iubini , Roberto Livi , Angelo Vulpiani

It is now widely accepted that the concept of negative absolute temperature is real one and not just theoretical curiosity. In this brief report, by combining the formalism used in the statistical mechanics and thermodynamics, we have…

Statistical Mechanics · Physics 2024-07-26 Anuradha Gupta , Deepak Jain

The concept of negative temperature has recently received renewed interest in the context of debates about the correct definition of the thermodynamic entropy in statistical mechanics. Several researchers have identified the thermodynamic…

Statistical Mechanics · Physics 2016-03-08 Robert H. Swendsen , Jian-Sheng Wang

In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a 'consistent thermostatistics' which forbids negative absolute temperatures. Here we argue that the Gibbs entropy…

Statistical Mechanics · Physics 2015-01-22 Daan Frenkel , Patrick B Warren

This paper is motivated by the recent paper M. Baldovin, S. Iubini, R. Livi and A. Vulpiani, Statistical mechanics of systems with negative temperature, arXiv:2103.12572. The authors suggest that negative absolute temperatures are…

General Relativity and Quantum Cosmology · Physics 2021-05-12 G. E. Volovik

We show that states of macroscopic systems with purported absolute negative temperatures are not stable under small, yet arbitrary, perturbations. We prove the previous statement using the fact that, in equilibrium, the entropy takes its…

Statistical Mechanics · Physics 2013-08-30 Victor Romero-Rochin

The concept of negative absolute temperature, introduced by Ramsey based on the study of a nuclear spin system by Purcell and Pound in 1951, has been subject to continued debate. According to a recent analysis by Struchtrup, the apparent…

Classical Physics · Physics 2019-10-07 Quanmin Guo

Absolute temperature, the fundamental temperature scale in thermodynamics, is usually bound to be positive. Under special conditions, however, negative temperatures - where high-energy states are more occupied than low-energy states - are…

This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature; being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs…

Statistical Mechanics · Physics 2016-04-06 Julian Poulter

The controversial existence of negative temperatures has stirred interesting debates that have reached the foundations of thermodynamics, including questions on the second law, the Carnot efficiency and the statistical definition of…

Statistical Mechanics · Physics 2019-06-26 Salvatore Calabrese , Amilcare Porporato

It has long been taken for granted that there is only one type of thermodynamic system near absolute zero temperature: the ordinary one compatible with all statements of the third law, with a fundamental yet tacit assumption that all heat…

Statistical Mechanics · Physics 2025-08-12 Q. H. Liu , S. F. Xiao , D. Guo , K. J. Yin

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez

Dunkel and Hilbert, "Consistent thermostatistics forbids negative absolute temperatures," Nature Physics, {\bf 10}, 67 (2014), and Hilbert, H\"anggi, and Dunkel, "Thermodynamic laws in isolated systems," Phys. Rev. E {\bf 90}, 062116 (2014)…

Statistical Mechanics · Physics 2015-07-09 Jian-Sheng Wang

'Relativistic thermodynamics' should be understood not as a generalization of a non-relativistic theory but as an application of a general thermodynamic framework, neutral as to spacetime setting and allowing arbitrary conserved quantities,…

Statistical Mechanics · Physics 2025-08-06 David Wallace

The existence of fluctuations of temperature has been a somewhat controversial topic in thermodynamics but nowadays it is recognized that they must be taken into account in small, finite systems. Although for nonequilibrium steady states…

Statistical Mechanics · Physics 2022-01-05 Sergio Davis

In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…

Statistical Mechanics · Physics 2015-08-26 Robert H. Swendsen , Jian-Sheng Wang

We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…

Statistical Mechanics · Physics 2009-11-13 A. Ramirez-Hernandez , H. Larralde , F. Leyvraz

Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…

Statistical Mechanics · Physics 2016-12-21 Pierfrancesco Buonsante , Roberto Franzosi , Augusto Smerzi

In this paper we discuss about the validity of the Shannon entropy functional in connection with the correct Gibbs-Hertz probability distribution function. We show that there is no contradiction in using the Shannon-Gibbs functional and…

Classical Physics · Physics 2015-03-11 Alessio Gagliardi , Alessandro Pecchia
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