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This is a preliminary article stating and proving a new maximum entropy theorem. The entropies that we consider can be used as measures of biodiversity. In that context, the question is: for a given collection of species, which frequency…

Information Theory · Computer Science 2011-01-14 Tom Leinster

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

Statistical physics aims to describe properties of macroscale systems in terms of distributions of their microscale agents. Its central tool is the maximization of entropy, a variational principle. We review the history of this principle,…

Statistical Mechanics · Physics 2023-10-11 Jonathan Asher Pachter , Ying-Jen Yang , Ken A. Dill

Maximum entropy estimation is of broad interest for inferring properties of systems across many different disciplines. In this work, we significantly extend a technique we previously introduced for estimating the maximum entropy of a set of…

Data Analysis, Statistics and Probability · Physics 2016-01-05 Elliot A. Martin , Jaroslav Hlinka , Alexander Meinke , Filip Děchtěrenko , Jörn Davidsen

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

Statistical Mechanics · Physics 2019-02-04 David M. Rogers , Susan B. Rempe

A brief discussion is given of the traditional version of the Maximum Entropy Method, including a review of some of the criticism that has been made in regard to its use in statistical inference. Motivated by these questions, a modified…

Data Analysis, Statistics and Probability · Physics 2007-09-12 Robert Kariotis

In this paper, I expand Shannon's definition of entropy into a new form of entropy that allows integration of information from different random events. Shannon's notion of entropy is a special case of my more general definition of entropy.…

Machine Learning · Computer Science 2008-11-04 Stefan Jaeger

The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…

Statistical Mechanics · Physics 2018-11-14 Dragos-Victor Anghel , Alexandru S. Parvan

We discuss the entropic criterion for separability of compound quantum systems for general non-additive entropic forms based on arbitrary concave functions $f$. For any separable state, the generalized entropy of the whole system is shown…

Quantum Physics · Physics 2015-05-20 R. Rossignoli , N. Canosa

Maximum-entropy distributions are shown to appear in the probability calculus as approximations of a model by exchangeability or a model by sufficiency, the former model being preferable. The implications of this fact are discussed,…

Data Analysis, Statistics and Probability · Physics 2017-06-27 P. G. L. Porta Mana

In this paper, we will use the entropy approach to derive a necessary and sufficient condition for the existence of an element that belongs to at least half of the sets in a finite family of sets.

Combinatorics · Mathematics 2024-12-30 Veronica Phan

This paper derives an objective Bayesian "prior" based on considerations of entropy/information. By this means, it produces a quantitative measure of goodness of fit (the "H-statistic") that balances higher likelihood against the number of…

Astrophysics · Physics 2008-11-26 Rafael D. Sorkin

Increasingly encompassing models have been suggested for our world. Theories range from generally accepted to increasingly speculative to apparently bogus. The progression of theories from ego- to geo- to helio-centric models to universe…

Information Theory · Computer Science 2010-11-04 Marcus Hutter

The macro-to-micro transition in a heterogeneous material is envisaged as the selection of a probability distribution by the Principle of Maximum Entropy (MAXENT). The material is made of constituents, e.g. given crystal orientations. Each…

Classical Physics · Physics 2007-05-23 Mayeul Arminjon , Didier Imbault

Maximum entropy principle identifies forces conjugated to observables and the thermodynamic relations between them, independent upon their underlying mechanistic details. For data about state distributions or transition statistics, the…

Statistical Mechanics · Physics 2023-12-08 Ying-Jen Yang , Hong Qian

In an essential and quite general setup, based on networks, we identify Schnakenberg's observables as the constraints that prevent a system from relaxing to equilibrium, showing that, in the linear regime, steady states satisfy a minimum…

Statistical Mechanics · Physics 2015-05-28 Matteo Polettini

The phenomenon of entropy concentration provides strong support for the maximum entropy method, MaxEnt, for inferring a probability vector from information in the form of constraints. Here we extend this phenomenon, in a discrete setting,…

Information Theory · Computer Science 2021-01-11 Kostas N. Oikonomou

Dissipative quantum systems are frequently described within the framework of the so-called "system-plus-reservoir" approach. In this work we assign their description to the Maximum Entropy Formalism and compare the resulting thermodynamic…

Statistical Mechanics · Physics 2017-01-04 Lisan M. M. Durão , Amir O. Caldeira

We develop a maximum relative entropy formalism to generate optimal approximations to probability distributions. The central results consist in (a) justifying the use of relative entropy as the uniquely natural criterion to select a…

Statistical Mechanics · Physics 2008-10-17 Chih-Yuan Tseng , Ariel Caticha
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