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Undoped graphene (Gr) sheets at low temperatures are known, via Random Phase Approximation (RPA) calculations, to exhibit unusual van der Waals (vdW) forces. Here we show that graphene is the first known system where effects beyond the RPA…

Strongly Correlated Electrons · Physics 2014-06-03 John F. Dobson , Tim Gould , Giovanni Vignale

Two-dimensional (2D) graphene-like layered semiconductors provide a new platform for materials research because of their unique mechanical, electronic and optical attributes. Their in-plane covalent bonding and dangling-bond-free surface…

Materials Science · Physics 2018-08-29 Zhiming Shi , Xinjiang Wang , Yuanhui Sun , Yawen Li , Lijun Zhang

van der Waals (vdW) interaction plays a fundamental role in the surface-molecules related phenomena. Tuning of the correlated charge fluctuation in the vdW complex is a plausible way to modulate the molecules interaction at the atomic…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Manoharan Muruganathan , Jian Sun , Tomonori Imamura , Hiroshi Mizuta

The van der Waals interactions between two parallel graphitic nanowiggles (GNWs) are calculated using the coupled dipole method (CDM). The CDM is an efficient and accurate approach to determine such interactions explicitly by taking into…

Mesoscale and Nanoscale Physics · Physics 2013-07-29 Anh D. Phan , Lilia M. Woods , The-Long Phan

Interlayer interactions in 2D materials, also known as van der Waals (vdWs) interactions, play a critical role in the physical properties of layered materials. It is fascinating to manipulate the vdWs interaction, and hence to "redefine"…

Materials Science · Physics 2019-06-06 Shenyang Huang , Guowei Zhang , Fengren Fan , Chaoyu Song , Fanjie Wang , Qiaoxia Xing , Chong Wang , Hua Wu , Hugen Yan

Stacking-dependent interlayer interactions are important for understanding the structural and electronic properties in incommensurable two dimensional material assemblies where long-range moir\'e patterns arise due to small lattice constant…

Mesoscale and Nanoscale Physics · Physics 2017-12-06 Nicolas Leconte , Jeil Jung , Sébastien Lebègue , Tim Gould

Stacking and twisting 2D van der Waals (vdW) layers have become versatile platforms to tune electron correlation. These platforms rely on exfoliating vdW materials down to a single and few vdW layers. We calculate the intrinsic…

Different atomistic registry between the layers forming the inner and outer nanotubes can form one-dimensional (1D) van der Waals (vdW) moir\'e superlattices. Unlike the two-dimensional (2D) vdW moir\'e superlattices, effects of 1D vdW…

Mesoscale and Nanoscale Physics · Physics 2021-07-30 Sihan Zhao , Ryo Kitaura , Pilkyung Moon , Mikito Koshino , Feng Wang

Although density functional theory (DFT) in principle includes even long-range interactions, standard implementations employ local or semi-local approximations of the interaction energy and fail at describing the van der Waals interactions.…

Soft Condensed Matter · Physics 2007-05-23 S. D. Chakarova , E. Schroder

A density functional theory (DFT) that accounts for van der Waals (vdW) interactions in condensed matter, materials physics, chemistry, and biology is reviewed. The insights that led to the construction of the Rutgers-Chalmers van der Waals…

Multilayer van der Waals (vdWs) heterostructures assembled by diverse atomically thin layers have demonstrated a wide range of fascinating phenomena and novel applications. Understanding the interlayer coupling and its correlation effect is…

Mesoscale and Nanoscale Physics · Physics 2017-06-26 Liang Xu , Wei-Qing Huang , Wangyu Hu , Bing-Xin Zhou , Anlian Pan , Gui-Fang Huang

The experimental knowledge on interlayer potential of graphenites is summarized and compared with computational results based on phenomenological models. Besides Lennard-Jones approximation, the Mie potential is discussed, Kolmogorov-Crespy…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Zbigniew Koziol , Grzegorz Gawlik , Jacek Jagielski

Proper inclusion of van der Waals (vdW) interactions in theoretical simulations based on standard density functional theory (DFT) is crucial to describe the physics and chemistry of systems such as organic and layered materials. Many…

Materials Science · Physics 2023-07-19 Jinwoo Park , Byung Deok Yu , Suklyun Hong

The role of interlayer bonds in the two-dimensional (2D) materials "beyond graphene" and so-called van der Waals heterostructures is vital, and understanding the nature of these bonds in terms of strength and type is essential due to a wide…

Strongly Correlated Electrons · Physics 2023-04-26 Georgy V. Pushkarev , Vladimir G. Mazurenko , Vladimir V. Mazurenko , Danil W. Boukhvalov

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

Two dimensional van der Waals heterostructures (2D are of significant interest due to their intriguing physical properties that are critically defined by the constituent monolayers and their interlayer coupling . However, typical inorganic…

Ubiquitous Van der Waals interactions between atoms and molecules are important for many molecular and solid structures. These systems are often studied from first principles using the Density Functional Theory (DFT). However, the commonly…

Materials Science · Physics 2009-11-13 Pier Luigi Silvestrelli

The theoretical description of sparse matter attracts much interest, in particular for those ground-state properties that can be described by density functional theory (DFT). One proposed approach, the van der Waals density functional…

The dispersive interaction between nanotubes is investigated through ab initio theory calculations and in an analytical approximation. A van der Waals density functional (vdW-DF) [Phys. Rev. Lett. 92, 246401 (2004)] is used to determine and…

Materials Science · Physics 2009-11-13 Jesper Kleis , Elsebeth Schroder , Per Hyldgaard

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko