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Phosphorene, a well-studied 2D allotrope of phosphorus, features unique properties such as widely tunable bandgap, high carrier mobility, and remarkable intrinsic in-plane anisotropy. Utilizing these structural and electronic properties, we…

Materials Science · Physics 2024-04-12 Saibabu Madas , Subhendu Kahaly , Mousumi Upadhyay Kahaly

The small difference between the rhombohedral phosphorus lattice ($A$-7 phase) and the simple cubic phase as well as between phosphorene and the cubic structure is used in order to construct their quasiparticle band dispersion. We exploit…

Mesoscale and Nanoscale Physics · Physics 2014-07-01 L. A. Falkovsky

We perform a systematic first-principles study of phosphorene in the presence of typical monovalent (hydrogen, fluorine) and divalent (oxygen) impurities. The results of our modeling suggest a decomposition of phosphorene into weakly bonded…

Materials Science · Physics 2015-05-01 D. W. Boukhvalov , A. N. Rudenko , D. A. Prishchenko , V. G. Mazurenko , M. I. Katsnelson

We report the results of density functional theory (DFT) based calculations on monolayer and bilayer green phosphorene and their heterostructures with MoSe2. Both monolayer and bilayer green phosphorene are direct band gap semiconductors…

Materials Science · Physics 2018-11-26 Sumandeep Kaur , Ashok Kumar , Sunita Srivastava , K. Tankeshwar , Ravindra Pandey

Phosphorene, a single layer of black phosphorous (BLK-P), has a significant potential for flexible and tunable electronics, but attempts to grow it epitaxially have been unsuccessful to date. Meanwhile, hexagonal blue phoshorous (BL-P) has…

Materials Science · Physics 2019-09-17 Daniel Hashemi , Gene Siegel , Michael Snure , Stefan C. Badescu

The monolayer of black phosphorous, or phosphorene, has recently emerged as a new 2D semiconductor with intriguing highly anisotropic transport properties. Existing calculations of its intrinsic phonon-limited electronic transport…

Materials Science · Physics 2015-06-24 Bolin Liao , Jiawei Zhou , Bo Qiu , Mildred S. Dresselhaus , Gang Chen

The band structure of single-layer black phosphorus and the effect of strain are predicted using density functional theory and tight-binding models. Having determined the localized orbital composition of the individual bands from…

Mesoscale and Nanoscale Physics · Physics 2014-08-26 A. S. Rodin , A. Carvalho , A. H. Castro Neto

Phosphorus is one of the most abundant elements preserved in earth, constructing with a fraction of ~0.1% of the earth crust. In general, phosphorus has several allotropes. The two most commonly seen allotropes, white and red phosphorus,…

Materials Science · Physics 2014-11-05 Han Liu , Yuchen Du , Yexin Deng , Peide D. Ye

A tight-binding model of a multi-leg ladder network with a continuous quasiperiodic modulation in both the site potential and the inter-arm hopping integral is considered. The model mimics optical lattices where ultra-cold fermionic or…

Mesoscale and Nanoscale Physics · Physics 2017-05-30 Santanu K. Maiti , Shreekantha Sil , Arunava Chakrabarti

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

Atomically thin layered black phosphorous (BP) has recently appeared as an alternative to the transitional metal di chalcogenides for future channel material in a MOS transistor due to its lower carrier effective mass. Investigation of the…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Anuja Chanana , Santanu Mahapatra

Ab initio investigations of structural, electronic, and dynamical properties of the high-temperature $\beta$ phase of copper pyrophosphate were performed using density functional theory. The electronic band structure shows the Mott…

We study the effect of surface adsorption of 27 different adatoms on the electronic and magnetic properties of monolayer black phosphorus using density functional theory. Choosing a few representative elements from each group, ranging from…

Mesoscale and Nanoscale Physics · Physics 2015-08-10 Priyank Rastogi , Sanjay Kumar , Somnath Bhowmick , Amit Agarwal , Yogesh Singh Chauhan

The discovery of topological phases of matter and topological boundary states had tremendous impact on condensed matter physics and photonics, where topological phases are defined via energy bands, giving rise to topological band theory.…

Materials exhibiting multiple stable phases can be used as functional components in electronic and optical applications if the phase transition is controllable. Group-VI transition metal dichalcogenides (TMDs, MX$_2$, where M=Mo, W and X =…

Materials Science · Physics 2019-08-21 Urvesh Patil , Nuala M. Caffrey

The van der Waals heterostructures of allotropes of phosphorene (${\alpha}$- and $\beta-P$) with MoSe2 (H-, T-, ZT- and SO-MoSe2) are investigated in the framework of state-of-the-art density functional theory. The semiconducting…

Materials Science · Physics 2017-08-02 Sumandeep Kaur , Ashok Kumar , Sunita Srivastava , K. Tankeshwar

We investigate the metal-to-insulator phase transition driven by the density-density electronic interaction in the quarter-filled model on a cubic lattice with two orbitals split by a crystal field. We show that a systematic consideration…

Strongly Correlated Electrons · Physics 2023-05-30 M. Vandelli , J. Kaufmann , V. Harkov , A. I. Lichtenstein , K. Held , E. A. Stepanov

We find that isoelectronic disorder destroys the spectral gap in a Mott-Hubbard insulator in 2D leading, most unexpectedly, to a new metallic phase. This phase is spatially inhomogeneous with metallic behavior coexisting with…

Strongly Correlated Electrons · Physics 2013-05-29 Dariush Heidarian , Nandini Trivedi

The results of first principles electronic structure calculations for the metallic rutile and the insulating monoclinic M1 phase of vanadium dioxide are presented. In addition, the insulating M2 phase is investigated for the first time. The…

Strongly Correlated Electrons · Physics 2017-09-27 Volker Eyert

We present a theoretical investigation of the voltage-driven metal insulator transition based on solving coupled Boltzmann and Hartree-Fock equations to determine the insulating gap and the electron distribution in a model system -- a one…

Strongly Correlated Electrons · Physics 2018-12-03 Giuliano Chiriacò , Andrew J. Millis