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We investigate the adsorption of cobalt phthalocyanine (CoPc) molecules on a thin layer of cobalt oxide grown on Ir(100). To that end we compare the results of low-temperature scanning tunneling microscopy (STM) with those of ab-initio…

Mesoscale and Nanoscale Physics · Physics 2018-10-24 Tobias Schmitt , Pascal Ferstl , Lutz Hammer , M. Alexander Schneider , Josef Redinger

Well-ordered organic molecular layers on oxide surfaces are key for organic electronics. Using a combination of scanning tunneling microscopy (STM) and non-contact atomic force microscopy (nc-AFM) we probe the structures of copper…

We present a comprehensive study of the adsorption of bis(phthalocyaninato)lutetium(III) (LuPc$_2$) on highly oriented pyrolytic graphite(0001) (HOPG). The growth and self-assembly of the molecular layers as well as the electronic structure…

Materials Science · Physics 2013-12-24 Lars Smykalla , Pavel Shukrynau , Michael Hietschold

We present a comprehensive study of the adsorption behavior of iron phthalocyanine on the low-index crystal faces of silver. By combining measurements of the reciprocal space by means of photoelectron momentum mapping and low energy…

Materials Science · Physics 2015-06-17 V. Feyer , M. Graus , P. Nigge , M. Wiessner , R. G. Acres , C. Wiemann , C. M. Schneider , A. Schöll , F. Reinert

Monolayers of the halomethane CF$_3$Br adsorbed on graphite have been investigated by x-ray diffraction. The layers crystallize in a commensurate triangular lattice. On cooling they approach a three-sublattice antiferroelectric pattern of…

Statistical Mechanics · Physics 2009-11-07 S. Faßbender , M. Enderle , K. Knorr , J. D. Noh , H. Rieger

Molecules intercalating two-dimensional (2D) materials form complex structures that have been mostly characterized by spatially averaged techniques. Here we use aberration-corrected scanning transmission electron microscopy and…

We demonstrate the growth of graphene nanocrystals by molecular beam methods that employ a solid carbon source, and that can be used on a diverse class of large area dielectric substrates. Characterization by Raman and Near Edge X-ray…

In order to investigate the orientational ordering of molecular dipoles and the associated electronic properties, we studied the adsorption of chlorogallium phthalocyanine molecules (GaClPc, Pc=C_32N_8H_16) on Cu(111) using the X-ray…

Materials Science · Physics 2015-03-19 A. Gerlach , T. Hosokai , S. Duhm , S. Kera , O. T. Hofmann , E. Zojer , J. Zegenhagen , F. Schreiber

We discuss Molecular Dynamics (MD) computer simulations of tetracosane (C24H50) monolayer physisorbed onto a graphite surface. The alkane molecules are simulated with explicit hydrogens, and the graphite substrate is represented as an…

Materials Science · Physics 2008-10-29 L. Firlej , B. Kuchta , M. W. Roth , M. J. Connolly , Carlos Wexler

The electronic structure of few-layer graphene (FLG) samples with crystalline order was investigated experimentally by infrared absorption spectroscopy for photon energies ranging from 0.2 - 1 eV. Distinct optical conductivity spectra were…

Materials Science · Physics 2015-05-18 Kin Fai Mak , Jie Shan , Tony F. Heinz

The induction of unconventional superconductivity by twisting two layers of graphene a small angle was groundbreaking1, and since then has attracted widespread attention to novel phenomena caused by lattice or angle mismatch between…

Mesoscale and Nanoscale Physics · Physics 2020-09-21 Yuqi Wang , Soroush Arabi , Klaus Kern , Markus Ternes

The fluorination of mono- and bi-layer graphene have been studied by means of ab-initio DFT calculations. The stability of CF$_x$ systems are found to depend on both the F coverage and on the position of the F atoms regarding the C…

Materials Science · Physics 2016-04-28 Hernán Santos , Luc Henrard

The study of the adsorption phenomenon of helium began many decades ago with the discovery of graphite as a homogeneous substrate for investigation of physically adsorbed monolayer films. In particular, helium monoatomic layers on graphite…

Materials Science · Physics 2016-02-17 R. Burganova , Y. Lysogorskiy , O. Nedopekin , D. Tayurskii

In this paper, we have done a comparative study of electronic and magnetic properties of iron phthalocyanine (FePc) and cobalt phthalocyanine (CoPc) molecules physisorbed on monolayer of MoS$_2$ and graphene by using density functional…

Materials Science · Physics 2018-09-05 Soumyajyoti Haldar , Sumanta Bhandary , Hakkim Vovusha , Biplab Sanyal

We present scanning tunneling microscopy (STM) images of single-layer graphene crystals examined under ultrahigh vacuum conditions. The samples, with lateral dimensions on the micron scale, were prepared on a silicon dioxide surface by…

In this work, we investigate the adsorption of a single cobalt atom (Co) on graphene by means of the complete active space self-consistent field approach, additionally corrected by the second-order perturbation theory. The local structure…

Materials Science · Physics 2012-08-15 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Graphene-based nanostructured systems and van-der-Waals heterostructures comprise a material class of growing technological and scientific importance. Joining materials with vastly different properties, polymer-graphene heterosystems…

Soft Condensed Matter · Physics 2020-08-26 Max Gulde , Anastassia N. Rissanou , Vagelis Harmandaris , Marcus Müller , Sascha Schäfer , Claus Ropers

While preserving many of the unusual features of single-layer graphene, few-layer graphene (FLG) provides a richness and flexibility of electronic structure that render this set of materials of great interest for both fundamental studies…

Mesoscale and Nanoscale Physics · Physics 2009-08-04 Kin Fai Mak , Matthew Y. Sfeir , James A. Misewich , Tony F. Heinz

Monolayer Tellurium (Te) or tellurene has been suggested by a recent theory as a new two-dimensional (2D) system with great electronic and optoelectronic promises. Here we present an experimental study of epitaxial Te deposited on highly…

Materials Science · Physics 2017-04-26 Jinglei Chen , Yawei Dai , Yaqiang Ma , Xianqi Dai , Wingkin Ho , Maohai Xie

We study the growth and microscopic structure of large-area graphene monolayers, grown on copper single crystals by chemical vapor deposition (CVD) in ultra-high vacuum (UHV). Using atomic-resolution scanning tunneling microscopy (STM), we…

Mesoscale and Nanoscale Physics · Physics 2010-08-23 L. Zhao , K. T. Rim , H. Zhou , R. He , T. F. Heinz , A. Pinczuk , G. W. Flynn , A. N. Pasupathy
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