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We present first-principles calculations of the vibrational properties of the transition metal dichalcogenide 1T-TaS$_2$ for various thicknesses in the high-temperature (undistorted) phase and the low-temperature commensurate charge density…

A number of intriguing phenomena, including exciton condensation, orbital ordering, and emergence of chirality, have been proposed to accompany charge-density-wave (CDW) formation in the layered transition metal dichalcogenide…

Strongly Correlated Electrons · Physics 2025-02-18 Wei Wang , Patrick Liu , Lijun Wu , Jing Tao , Genda Gu , Alfred Zong , Yimei Zhu

Single-layer TaS$_2$ is epitaxially grown on Au(111) substrates. The resulting two-dimensional crystals adopt the 1H polymorph. The electronic structure is determined by angle-resolved photoemission spectroscopy and found to be in excellent…

A charge density wave (CDW) of a nonzero ordering vector $\mathbf{q}$ couple electronic states at $\mathbf{k}$ and $\mathbf{k}+\mathbf{q}$ statically, giving rise to a reduced Brillouin zone (RBZ) due to the band folding effect. Its…

Materials Science · Physics 2021-09-20 Ming-Chien Hsu , Bahadur Singh , Chuang-Han Hsu , Su-Yang Xu , Hsin Lin , Shin-Ming Huang

Layered transition metal dichalcogenides (TMDs) provide an ideal platform for exploring the effects of dimensionality on correlated electronic phases such as charge density wave (CDW) order. When TMDs are reduced in thickness to the 2-D…

Mesoscale and Nanoscale Physics · Physics 2016-11-03 Linjun Li , WeiJie Zhao , Bo Liu , Tianhua Ren , Goki Eda , Kianping Loh

In the sake of connecting the charge-density-wave (CDW) of TaSe$_2$ and single-\emph{\textbf{q}} CDW-type distortion of TaTe$_2$, we present an overall electronic phase diagram of 1\emph{T}-TaSe$_{2-x}$Te$_x$ ($0 \leq x \leq 2$). In the…

Strongly Correlated Electrons · Physics 2020-02-07 Y. Liu , D. F. Shao , W. J. Lu , L. J. Li , H. Y. Lv , X. D. Zhu , S. G. Tan , B. Yuan , L. Zu , X. C. Kan , W. H. Song , Y. P. Sun

Single-layer transition metal dichalcogenides (TMDCs) can adopt two distinct structures corresponding to different coordination of the metal atoms. TMDCs adopting the T-type structure exhibit a rich and diverse set of phenomena, including…

Mesoscale and Nanoscale Physics · Physics 2020-07-29 Daniel T. Larson , Wei Chen , Steven B. Torrisi , Jennifer Coulter , Shiang Fang , Efthimios Kaxiras

Monolayers of transition metal dichalcogenides (TMDs) in the 2H structural phase have been recently classified as higher-order topological insulators (HOTI), protected by $C_3$ rotation symmetry. In addition, theoretical calculations show…

Understanding Mott insulators and charge density waves (CDW) is critical for both fundamental physics and future device applications. However, the relationship between these two phenomena remains unclear, particularly in systems close to…

Correlated two-dimensional (2D) layers, like 1T-phases of TaS2, TaSe2 and NbSe2, exhibit rich tunability through varying interlayer couplings, which promotes the understanding of electron-correlation in the 2D limit. However, the coupling…

For layered materials, the interlayer stacking is a critical degree of freedom tuning electronic properties, while its microscopic characterization faces great challenges. The transition-metal dichalcogenide 1T-TaS$_2$ represents a novel…

Materials Science · Physics 2025-08-01 Li Cheng , Linpeng Nie , Xuanyu Long , Li Liang , Dan Zhao , Jian Li , Zheng Liu , Tao Wu , Xianhui Chen , Xiaolong Zou

Electronic flat bands serve as a unique platform to achieve strongly-correlated phases. The emergence of a flat band around the Fermi level in 1T-TaS$_2$ in accompany with the development of a $\sqrt{13}\times\sqrt{13}$ charge density wave…

Materials Science · Physics 2022-01-13 Li Cheng , Xuanyu Long , Xiaobin Chen , Xiaolong Zou , Zheng Liu

Surface reconstruction plays a vital role in determining the surface electronic structure and chemistry of semiconductors and metal oxides. However, it has been commonly believed that surface reconstruction does not occur in van der Waals…

Materials Science · Physics 2023-09-19 Sung-Hoon Lee , Doohee Cho

Electronic liquid-crystal phases are observed in numerous strongly-correlated systems including high-temperature superconductors. However, identifying these exotic phases and understanding their interplay with superconductivity in…

In the present work, we study the magnetic properties of the NbS2 monolayer by first-principles calculations. The transition metal dichalcogenides (TMDC) are a family of laminar materials presenting exciting properties such as charge…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 F. Güller , V. L. Vildosola , A. M. Llois

We theoretically study the electronic and the thermal characteristics of Tantalum, Ta, doped Molybdenum disulfide, MoS$_2$, using density functional theory. It has been shown that the MoS$_2$ monolayer is not a good material for…

Mesoscale and Nanoscale Physics · Physics 2022-04-05 Nzar Rauf Abdullah , Botan Jawdat Abdullah , Hunar Omar Rashid , Chi-Shung Tang , Vidar Gudmundsson

We introduce ultrafast low-energy electron diffraction (ULEED) in backscattering for the study of structural dynamics at surfaces. Using a tip-based source of ultrashort electron pulses, we investigate the optically-driven transition…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 S. Vogelgesang , G. Storeck , S. Schramm , K. Rossnagel , S. Schäfer , C. Ropers

The layered transition metal dichalcogenide, TaSe2, exhibits rich electronic phenomena across its polymorphs, 1T, 2H, and 3R, largely driven by differences in atomic coordination and c-axis stacking. In the 1T phase, octahedral coordination…

Superconductivity · Physics 2026-02-13 Kusal Dharmasiri , Maxim Avdeev , Despina Louca

We investigate electronic instabilities in 2H-TaS\textsubscript{2} and a self-intercalated variant, 2H$^\dagger$-Ta\textsubscript{1+$\delta$}S\textsubscript{2}. In conventional samples, which we determine to be slightly hole-doped, spectral…

Correlated electron systems that host multiple electronic orders offer routes to multifunctional quantum materials, but strong competition between these orders often prevents their coexistence. Here we show that nanoscale, metastable…

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