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The tunability and twist engineering of van der Waals materials enable the emergence of electronic states not present in individual monolayers. Among them, monolayer 1T-TaS$_2$ is a well-known Mott insulating system, whose star-of-David…

Strongly Correlated Electrons · Physics 2026-04-03 Ana Vera Montoto , Jose L. Lado , Adolfo O. Fumega

We present a state-of-the-art density functional theory (DFT) study which models crucial features of the partially disordered orbital order stacking in the prototypical layered transition metal dichalcogenide 1T-TaS2 . Our results not only…

Strongly Correlated Electrons · Physics 2018-12-05 Tobias Ritschel , Helmuth Berger , Jochen Geck

In bulk samples and few layer flakes, the transition metal dichalcogenides NbS$_2$ and NbSe$_2$ assume the H polytype structure with trigonal prismatic coordination of the Nb atom. Recently, however, single and few layers of 1T-NbSe$_2$…

Strongly Correlated Electrons · Physics 2019-05-27 Cesare Tresca , Matteo Calandra

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic…

Charge density waves are emergent quantum states that spontaneously reduce crystal symmetry, drive metal-insulator transitions, and precede superconductivity. In low-dimensions, distinct quantum states arise, however, thermal fluctuations…

Charge density waves in transition metal dichalcogenides have been intensively studied for their close correlation with Mott insulator, charge-transfer insulator, and superconductor. VTe2 monolayer recently comes into sight because of its…

Strongly Correlated Electrons · Physics 2020-05-13 Qiucen Wu , Zhongjie Wang , Yucheng Guo , Fang Yang , Chunlei Gao

Using density functional theory with added on-site interactions (DFT+U), we study the electronic structure of bulk, monolayer, and bilayer of the layered transition-metal dichalcogenide $1T-TaS_2$. We show that a two-dimensional…

Materials Science · Physics 2015-06-18 Pierre Darancet , Andrew J. Millis , Chris A. Marianetti

Mott state in 1T-TaS2 is predicted to host quantum spin liquids (QSL). However, its insulating mechanism is controversial due to complications from interlayer coupling. Here, we study the Mott state in monolayer 1T-NbSe2, an electronic…

Mesoscale and Nanoscale Physics · Physics 2021-09-08 Zhen-Yu Liu , Shuang Qiao , Qiao-Yin Tang , Zi-Heng Ling , Wen-Hao Zhang , Hui-Nan Xia , Xin Liao , Wen-Hao Mao , Jing-Tao Lü , Bing Huang , Ying-Shuang Fu

Charge density wave (CDW) order is an emergent quantum phase that is characterized by a periodic lattice distortion and charge density modulation, often present near superconducting transitions. Here we uncover a novel inverted CDW state by…

A prototypical quasi-2D metallic compound, 1T-TaS_2 has been extensively studied due to an intricate interplay between a Mott-insulating ground state and a charge density-wave (CDW) order. In the low-temperature phase, 12 out of 13 Ta_{4+}…

Strongly Correlated Electrons · Physics 2017-09-29 Marie Kratochvilova , Adrian D. Hillier , Andrew R. Wildes , Lihai Wang , Sang-Wook Cheong , Je-Geun Park

Charge density waves (CDW) and their concomitant periodic lattice distortions (PLD) govern the electronic properties in many layered transition-metal dichalcogenides. In particular, 1T-TaS2 undergoes a metal-to-insulator phase transition as…

We study the coupling of light and the structural order parameter in the charge density wave (CDW) state of the layered transition-metal dichalcogenide, Tantalum Disulfide ($1T-\mathrm{TaS_2}$). Using time-dependent density functional…

Materials Science · Physics 2021-06-01 Anubhab Haldar , Cristian L. Cortes , Stephen K. Gray , Sahar Sharifzadeh , Pierre Darancet

Van der Waals (vdW) heterostructures continue to attract intense interest as a route of designing materials with novel properties that cannot be found in naturally occurring materials. Unfortunately, this approach is currently limited to…

Charge density waves (CDW) in single-layer 1$T$-MTe$_2$ (M= Nb, Ta) recently raised large attention because of the contrasting structural and physical behavior with the sulfide and selenide analogues. A first-principles study of fourteen…

Materials Science · Physics 2025-02-25 Jose Angel Silva-Guillén , Enric Canadell

Vertical charge order shapes the electronic properties in layered charge density wave (CDW) materials. Various stacking orders inevitably create nanoscale domains with distinct electronic structures inaccessible to bulk probes. Here, the…

Strongly Correlated Electrons · Physics 2024-06-17 Hyungryul Yang , Byeongin Lee , Junho Bang , Sunghun Kim , Dirk Wulferding , Sung-Hoon Lee , Doohee Cho

Strong electron-hole interactions in a semimetal or narrow-gap semiconductor may drive a ground state of condensed excitons. Monolayer WTe2 has been proposed as a host material for such an exciton condensate, but the order parameter - the…

Charge density waves (CDWs) underpin the electronic properties of many complex materials. Near-equilibrium CDW order is linearly coupled to a periodic, atomic-structural distortion, and the dynamics is understood in terms of amplitude and…

Charge density wave (CDW) and their interplay with correlated and topological quantum states are forefront of condensed matter research. The 4$H_{b}$-TaS$_2$ is a CDW ordered quantum heterostructure that is formed by alternative stacking of…

We study the structural, electronic and vibrational properties of single-layer 1TNbSe$_2$ from first principles. Within the generalized gradient approximation, the 1T polytype is highly unstable with respect to the 2H. The DFT+U method…

Materials Science · Physics 2018-07-18 Matteo Calandra

Layered transition metal dichalcogenide 1T-NbSe_2 is a good candidate to explore the charge density wave (CDW) and Mott physics. However, the effects of stacking orders and interlayer coupling in CDW 1T-NbSe_2 are still less explored and…

Strongly Correlated Electrons · Physics 2022-10-07 Tao Jiang , Haotian Wang , Heng Gao , Qinghe Zheng , Zhenya Li , Wei Ren