Related papers: Interstellar and circumstellar fullerenes
In an effort to further our interest in understanding basic chemistry of interstellar molecules, we carry out here an extensive investigation of the stabilities of interstellar carbon chains; Cn, H2Cn, HCnN and CnX (X=N, O, Si, S, H, P, H-,…
Interstellar hydrides -- that is, molecules containing a single heavy element atom with one or more hydrogen atoms -- were among the first molecules detected outside the solar system. They lie at the root of interstellar chemistry, being…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…
Circumstellar envelopes (CEs) around evolved stars are an active site for the production of molecules. After evolving through the Asymptotic Giant Branch (AGB), proto-planetary nebula (PPN), to planetary nebula (PN) phases, CEs ultimately…
Molecular hydrogen is the most abundant molecule in the universe. It is the first one to form and survive photo-dissociation in tenuous environments. Its formation involves catalytic reactions on the surface of interstellar grains. The…
The petroleum and coal models of the unidentified infrared emissions (UIE), sometimes referred also as unidentified infrared bands (UIBs) has been reviewed mainly based on the work of the authors with the inclusion of unpublished results.…
A family of unusually stable boron cages was identified and examined using first-principles local density functional method. The structure of the fullerenes is similar to that of the B12 icosahedron and consists of six crossing…
It had been understood that astronomically observed infrared spectrum of carbon rich planetary nebula as like Tc 1 and Lin 49 comes from fullerene (C60). Also, it is well known that graphene is a raw material for synthesizing fullerene.…
Large numbers of small opaque dust clouds - termed 'globulettes' by Gahm et al - have been observed in the H II regions surrounding young stellar clusters. With masses typically in the planetary (or low mass brown dwarf) regime, these…
New research is presented, and previous research is reviewed, on the emission and absorption of interstellar aromatic hydrocarbons. Emission from aromatic hydrocarbons dominate the mid-infrared emission of many galaxies, including our own…
We report the first detection of buckminsterfullerene (C60) in a proto-planetary nebula (PPN). The vibrational transitions of C60 at 7.0, 17.4, and 18.9um are detected in the Spitzer/IRS spectrum of IRAS 01005+7910. This detection suggests…
Recent \herschel\ and \planck\ observations of submillimeter dust emission revealed the omnipresence of filamentary structures in the interstellar medium (ISM). The ubiquity of filaments in quiescent clouds as well as in star-forming…
There is accumulating evidence for the presence of complex molecules, including carbon-bearing and organic molecules, in the interstellar medium. Much of this evidence comes to us from studies of chemical composition, photo- and…
The chemistry of phosphorus (31P) in space is particularly significant due to the key role it plays in biochemistry on Earth. Utilising radio and infrared spectroscopic observations, several key phosphorus-containing molecules have been…
Polycyclic Aromatic Hydrocarbons (PAHs) have long been invoked in the study of interstellar and protostellar sources, but the unambiguous identification of any individual PAH has proven elusive until very recently. As a result, the…
The formation and evolution mechanism of fullerenes in the planetary nebula or in the interstellar medium are still not understood. Here we present the study on the cluster formation and the relative reactivity of fullerene cations (from…
Recent studies of the nearest star-forming clouds of the Galaxy at submillimeter wavelengths with the Herschel Space Observatory have provided us with unprecedented images of the initial conditions and early phases of the star formation…
Cool, evolved stars are the main source of chemical enrichment of the interstellar medium (ISM), and understanding their mass loss and structure offers a unique opportunity to study the cycle of matter in the Universe. Pulsation,…
Context. The circumstellar environment of evolved stars is generally rich in molecular gas and dust. Typically, the entire environment is either oxygen-rich or carbon-rich, depending on the evolution of the central star. Aims. In this paper…
With the well-established correlation between the relative stabilities of isomers and their interstellar abundances coupled with the prevalence of isomeric species among the interstellar molecular species, isomerization remains a plausible…