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The discovery of a new family of high Tc materials, the iron arsenides (FeAs), has led to a resurgence of interest in superconductivity. Several important traits of these materials are now apparent, for example, layers of iron tetrahedrally…

We investigate the physical properties and electronic structure upon Cr-doping in the iron arsenide layers of BaFe2As2. This form of hole-doping leads to suppression of the magnetic/structural phase transition in BaFe2-xCrxAs2 for x > 0,…

The interplay between superconductivity and Eu$^{2+}$ magnetic ordering in Eu(Fe$_{1-x}$Ir$_{x}$)$_{2}$As$_{2}$ is studied by means of electrical transport and magnetic measurements. For the critically doped sample…

Superconductivity · Physics 2013-06-11 U. B. Paramanik , Debarchan Das , R. Prasad , Z. Hossain

CaFe$_2$As$_2$ has been synthesized and found to form in the tetragonal, ThCr$_2$Si$_2$ structure with lattice parameters $a = 3.912(68) \AA$ and $c = 11.667(45) \AA$. Upon cooling through 170 K, CaFe$_2$As$_2$ undergoes a first order,…

Strongly Correlated Electrons · Physics 2009-11-13 N. Ni , S. Nandi , A. Kreyssig , A. I. Goldman , E. D. Mun , S. L. Bud'ko , P. C. Canfield

CaFe$_2$As$_2$ has been found to be exceptionally sensitive to the application of hydrostatic pressure and superconductivity has been found to exist in a narrow pressure region that appears to be at the interface between two different phase…

Superconductivity · Physics 2009-11-13 Milton S. Torikachvili , Sergey L. Bud'ko , Ni Ni , Paul C. Canfield

Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the…

Recently, KFe$_2$As$_2$ was shown to exhibit a structural phase transition from a tetragonal to a collapsed tetragonal phase under applied pressure of about $15~\mathrm{GPa}$. Surprisingly, the collapsed tetragonal phase hosts a…

Superconductivity · Physics 2015-04-14 Daniel Guterding , Steffen Backes , Harald O. Jeschke , Roser Valenti

Compounds with a tetragonal ThCr$_{2}$Si$_{2}$-type structure are characterized by the possibility of the isostructural phase transition from the tetragonal phase to the collapsed tetragonal phase induced by the external pressure. An…

Superconductivity · Physics 2019-04-16 Andrzej Ptok , Małgorzata Sternik , Konrad Jerzy Kapcia , Przemysław Piekarz

In this paper we report the synthesis of iron-based superconductors CaFe2-xRhxAs2 using one-step solid state reaction method, which crystallizes in the ThCr2Si2-type structure with a space group I4/mmm. The systematic evolution of the…

Superconductivity · Physics 2015-05-19 Yanpeng Qi , Lei Wang , Zhaoshun Gao , Dongliang Wang , Xianping Zhang , Chunlei Wang , Chao Yao , Yanwei Ma

Polycrystalline samples of underdoped (Ba1-xKx)Fe2As2 (x<=0.4) were synthesized and studied by x-ray powder diffraction, magnetic susceptibility, specific heat and 57Fe-Moessbauer-spectroscopy. The structural phase transition from…

Application of pressures or electron-doping through Co substitution into Fe sites transforms the itinerant antiferromagnet BaFe(2)As(2) into a superconductor with the Tc exceeding 20K. We carried out systematic transport measurements of…

Superconductivity · Physics 2009-11-13 K. Ahilan , J. Balasubramaniam , F. L. Ning , T. Imai , A. S. Sefat , R. Jin , M. A. McGuire , B. C. Sales , D. Mandrus

We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of…

We report $^{75}$As NMR studies on single crystals of rare-earth doped iron pnictides superconductor Ca$_{1-x}$Pr$_{x}$Fe$_{2}$As$_{2}$ ($x$=0.075 and 0.15). The $^{75}$As spectra show a chemical pressure effect with doping and a first…

Superconductivity · Physics 2013-04-16 Long Ma , G. F. Ji , J. Dai , S. R. Saha , J. Paglione , Weiqiang Yu

A new hight Tc Fe-based compound system, AFe2As2 with A = K, Cs, K/Sr and Cs/Sr has been found. Through electron-doping, Tc of the A = K and Cs compounds rises to ~37 K, and finally enter a spin-density-wave state (SDW) through further…

Superconductivity · Physics 2008-09-09 K. Sasmal , B. Lv , B. Lorenz , A. Guloy , F. Chen , Y. Xue , C. W. Chu

We establish the phase diagram of Eu$_{1-x}$La$_x$Fe$_2$As$_2$ system as a function of doping level x and the pressure by measuring the resistivity and magnetic susceptibility. The pressure can suppress the spin density wave (SDW) and…

Superconductivity · Physics 2012-06-14 M. Zhang , J. J. Ying , Y. J. Yan , A. F. Wang , X. F. Wang , Z. J. Xiang , G. J. Ye , P. Cheng , X. G. Luo , Jiangping Hu , X. H. Chen

We report measurements of the pressure dependence of the superconducting transition temperature T_c in single crystal samples of the rare-earth doped superconductor Ca$_{0.73}$La$_{0.27}$Fe$_2$As$_2$. We track T_c with two techniques, via…

We have successfully synthesized the fluoride-arsenide compounds Ca$_{1-x}$RE$_x$FeAsF (RE=Nd, Pr; x=0, 0.6). The x-ray powder diffraction confirmed that the main phases of our samples are Ca$_{1-x}$RE$_x$FeAsF with the ZrCuSiAs structure.…

Superconductivity · Physics 2009-04-23 Peng Cheng , Bing Shen , Gang Mu , Xiyu Zhu , Fei Han , Bin Zeng , Hai-Hu Wen

High-resolution x-ray diffraction measurements reveal an unusually strong response of the lattice to superconductivity in Ba[Fe(1-x)Cox]2As2. The orthorhombic distortion of the lattice is suppressed and, for Co-doping near x = 0.063, the…

La-substituted CaFeAsH,(Ca1-xLax)FeAsH, were synthesized by the solid state reaction at 1173 K under high pressure of 2.5 GPa. The r-T anomaly corresponding to tetragonal to orthorhombic structural transition was suppressed by…

Superconductivity · Physics 2014-02-19 Yoshinori Muraba , Satoru Matsuishi , Hideo Hosono

The recently discovered LaFe2As2 superconducting compound, member of the 122 family of iron pnictide superconductors, becomes superconducting below Tc=13K, yet its nominal doping apparently places it in the extreme overdoped limit, where…

Superconductivity · Physics 2025-02-18 Ilaria Pallecchi , Akira Iyo , Hiraku Ogino , Marco Affronte , Marina Putti