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We show that two graphene layers stacked directly on top of each other (AA stacking) form strong chemical bonds when the distance between planes is 0.156 nm. Simultaneously, C-C in-plane bonds are considerably weakened from partial…

Materials Science · Physics 2008-02-27 P. L. de Andres , R. Ramirez , J. A. Verges

We investigate a recently developed approach [P. L. Silvestrelli, Phys. Rev. Lett. 100, 053002 (2008); J. Phys. Chem. A 113, 5224 (2009)] that uses maximally localized Wannier functions to evaluate the van der Waals contribution to the…

Materials Science · Physics 2012-06-12 Lampros Andrinopoulos , Nicholas D. M. Hine , Arash A. Mostofi

An outstanding challenge of theoretical electronic structure is the description of van der Waals (vdW) interactions in molecules and solids. Renewed interest in resolving this is in part motivated by the technological promise of layered…

Materials Science · Physics 2016-01-20 Luke Shulenburger , Andrew D. Baczewski , Zhen Zhu , Jie Guan , David Tomanek

Graphene exhibits promise as a plasmonic material with high mode confinement that could enable efficient hot carrier extraction. We investigate the lifetimes and mean free paths of energetic carriers in free-standing graphene, graphite and…

Materials Science · Physics 2016-12-28 Prineha Narang , Litao Zhao , Steven Claybrook , Ravishankar Sundararaman

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

Materials Science · Physics 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli

'Magic'-angle twisted bilayer graphene has received a lot of interest due to its flat bands with potentially non-trivial topology that lead to intricate correlated phases. A spectrum with flat bands, however, does not require a twist…

Mesoscale and Nanoscale Physics · Physics 2021-07-07 Anastasiia Skurativska , Stepan S. Tsirkin , Fabian D Natterer , Titus Neupert , Mark H Fischer

The absorption energy of atomic hydrogen at rotated graphene bilayers is studied using ab initio methods based on the density functional theory including van der Waals interactions. We find that, due to the surface corrugation induced by…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Ivan Brihuega , Felix Yndurain

Layered materials have huge potential in various applications due to their extraordinary properties. To determine the interlayer interaction (or equivalently the layer spacing under different perturbations) is of critical importance. In…

Materials Science · Physics 2017-04-14 Y. W. Sun , D. Holec , Y. Xu , D. J. Dunstan

We carry out a computational study on the geometric and electronic properties of multi-layers of silicene in different stacking configurations using a state-of-art abinitio density functional theory based calculations. In this work we…

Materials Science · Physics 2015-02-26 C. Kamal , Aparna Chakrabarti , Arup Banerjee , S. K. Deb

The thermal free energy and pressure of dispersion interaction between two graphene sheets described by the Dirac model are calculated using the Lifshitz formula with reflection coefficients expressed via the polarization tensor. The…

Mesoscale and Nanoscale Physics · Physics 2013-02-28 G. L. Klimchitskaya , V. M. Mostepanenko

The study of moir\'e engineering started with the advent of van der Waals heterostructures in which stacking two-dimensional layers with different lattice constants leads to a moir\'e pattern controlling their electronic properties. The…

Mesoscale and Nanoscale Physics · Physics 2023-08-28 F. Mesple , N. R. Walet , G. Trambly de Laissardière , F. Guinea , D. Dosenovic , H. Okuno , C. Paillet , A. Michon , C. Chapelier , V. T. Renard

We performed density functional theory (DFT) calculations for a bi-layered heterostructure combining a graphene layer with a MoS2 layer with and without intercalated Li atoms. Our calculations demonstrate the importance of the van der Waals…

Materials Science · Physics 2015-02-27 Towfiq Ahmed , N. A. Modine , Jian-Xin Zhu

Bilayer graphene can exhibit deformations such that the two graphene sheets are locally detached from each other resulting in a structure consisting of domains with different inter-layer coupling. Here we investigate how the presence of…

Mesoscale and Nanoscale Physics · Physics 2017-10-10 Hasan M. Abdullah , B. Van Duppen , M. Zarenia , H. Bahlouli , F. M. Peeters

In two-dimensional van der Waals (vdWs) materials, the relative twist angle between adjacent layers not only controls their electronic properties, but also determines their stacking energy. This effect makes it much easier to realize…

Mesoscale and Nanoscale Physics · Physics 2021-04-06 Yi-Wen Liu , Chen-Yue Hao , Lin He

We show that the usual sum of $R^{-6}$ contributions from elements separated by distance $R$ can give \emph{qualitatively} wrong results for the electromagnetically non-retarded van der Waals interaction between non-overlapping bodies. This…

Soft Condensed Matter · Physics 2009-11-11 John F. Dobson , Angela White , Angel Rubio

Building on discoveries in graphene and two-dimensional (2D) transition metal dichalcogenides, van der Waals (VdW) layered heterostructures - stacks of such 2D materials - are being extensively explored with resulting new discoveries of…

Materials Science · Physics 2022-10-20 Nicholas Ng , Tyrel M. McQueen

In this study, we use first-principles calculations to investigate the stacking-dependent electronic properties of GaSe/GaTe van der Waals heterobilayers. By analyzing five representative stacking configurations--AA, AA$'$, A$'$C, A$'$B,…

Materials Science · Physics 2025-06-24 Hsin-Yi Liu , Jhao-Ying Wu

The interlayer gallery between two adjacent sheets of van der Waals materials is expected to modify properties of atoms and molecules confined at the atomic interfaces. Here, we directly image individual hydrogen atom intercalated between…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Wen-Xiao Wang , Yi-Wen Wei , Si-Yu Li , Xinqi Li , Xiaosong Wu , Ji Feng , Lin He

We study the electronic properties of commensurate faulted bilayer graphene by diagonalizing the one-particle Hamiltonian of the bilayer system in a complete basis of Bloch states of the individual graphene layers. Our novel approach is…

Mesoscale and Nanoscale Physics · Physics 2016-09-02 M. Van der Donck , C. De Beule , B. Partoens , F. M. Peeters , B. Van Duppen

The growing families of two-dimensional crystals derived from naturally occurring van der Waals materials offer an unprecedented platform to investigate elusive physical phenomena and could be of use in a diverse range of devices. Of…

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