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The electronic properties of polycrystalline lead oxide consisting of a network of single-crystalline $\alpha$-PbO platelets and the formation of the native point defects in $\alpha$-PbO crystal lattice are studied using first principles…

Materials Science · Physics 2015-06-11 J. Berashevich , O. Semeniuk , O. Rubel , J. A. Rowlands , A. Reznik

We describe the ground- and excited-state electronic structure of bulk MnO and NiO, two prototypical correlated electron materials, using coupled cluster theory with single and double excitations (CCSD). As a corollary, this work also…

In view of the long-standing controversy over the reversibility of transition metals in Sn-based alloys as anode for Li-ion batteries, an in situ real-time magnetic monitoring method was used to investigate the evolution of Sn-Co…

The phase transition behavior and charge storage mechanism of Pr$_2$MgZrO$_6$ (PMM), an oxygen-intercalated pseudocapacitor, were investigated through crystal structure analysis, Raman spectroscopy, ac conductivity spectroscopy, X ray…

Materials Science · Physics 2023-07-26 Moumin Rudra , S. Saha , T. P. Sinha

The mechanisms and efficiency of charge transport in lithium peroxide (Li2O2) are key factors in understanding the performance of non-aqueous Li-air batteries. Towards revealing these mechanisms, here we use first-principles calculations to…

Materials Science · Physics 2013-06-25 Maxwell D. Radin , Donald J. Siegel

Supercapacitors are energy storage devices able to deliver electricity with a high power. They consist of porous carbon electrodes in a concentrated electrolyte. Charged is stored by the adsorption of ions at the electrode surface.…

Chemical Physics · Physics 2018-11-26 Benjamin Rotenberg , Mathieu Salanne , Patrice Simon

The theory of thermodynamic properties of two-band superconductor with reduced density charge carriers is developed on the base of phonon superconducting mechanism with strong electron-phonon interaction. This theory is adapted to describe…

Superconductivity · Physics 2015-06-25 M. E. Palistrant , V. A. Ursu

This work explores the unique character of strongly correlated systems, specifically Mott-insulators, in the context of battery electrode materials. The study investigates the correlation between the proposed chemical potential evolution…

We describe Na0.67Mn0.625Fe0.25Co0.125O2 (NMFCO), a P2-type sodium-ion battery cathode. Our composition, with significantly less Co than in an earlier study, shows discharge capacity close to 190 mAhg-1 and specific energy density exceeding…

Materials Science · Physics 2024-08-06 William Rexhausen , Christian Parsons , Uma Garg , Deyang Qu , Prasenjit Guptasarma

The apparent contradiction between the recently observed weak charge disproportion and the traditional Mn$^{3+}$/Mn$^{4+}$ picture of the charge-orbital orders in half-doped manganites is resolved by a novel Wannier states analysis of the…

Strongly Correlated Electrons · Physics 2015-05-13 Dmitri Volja , Wei-Guo Yin , Wei Ku

Quantum batteries (QBs) exploit principles of quantum mechanics to accelerate the charging process and aim to achieve optimal energy storage. However, analytical results for investigating these problems remain lacking due to the challenges…

Quantum Physics · Physics 2025-02-11 Hui-Yu Yang , Kun Zhang , Xiao-Hui Wang , Hai-Long Shi

We carefully investigated the storage of lithium in titania films on various substrates as a function of thickness. The experiments enable us to precisely separate contributions from bulk and boundary storage. The battery capacity…

Chemical Physics · Physics 2023-03-24 Chuanlian Xiao , Hongguang Wang , Peter A. van Aken , Robert Usiskin , Joachim Maier

Electrolyte gating is widely used to induce large carrier density modulation on solid surfaces to explore various properties. Most of past works have attributed the charge modulation to electrostatic field effect. However, some recent…

Calculations of formation energies and charge transition levels of defects routinely rely on density functional theory (DFT) for describing the electronic structure. Since bulk band gaps of semiconductors and insulators are not well…

Materials Science · Physics 2012-04-19 Audrius Alkauskas , Alfredo Pasquarello

The non-equilibrium tunnel transport processes are considered in a square lattice of metallic nanogranules embedded into insulating host. Based on a simple model with three possible charging states (+,-, or 0) of a granule and three kinetic…

Materials Science · Physics 2007-05-23 Yu. G. Pogorelov , J. F. Polido

LiBO$_{2}$ is an electronic insulator and a promising surface coating for stabilizing high-voltage cathodes in lithium-ion batteries. Despite its potential, the functional mechanisms of this coating remain unclear, particularly the…

We studied the dynamics of entropic uncertainty in Markovian and non-Markovian systems during the charging of open quantum batteries (QBs) mediated by a common dissipation environment. In the non-Markovian regime, the battery is almost…

Quantum Physics · Physics 2022-11-07 Meng-Long Song , Li-Juan Li , Xue-Ke Song , Liu Ye , Dong Wang

Charge transport in MoS2 in the low carrier density regime is dominated by trap states and band edge disorder. The intrinsic transport properties of MoS2 emerge in the high density regime where conduction occurs via extended states. Here,…

Mesoscale and Nanoscale Physics · Physics 2014-12-08 Leiqiang Chu , Hennrik Schmidt , Jiang Pu , Shunfeng Wang , Barbaros Özyilmaz , Taishi Takenobu , Goki Eda

This study comprehensively examined the structural, electronic, electrochemical, and energy storage properties of boron-vacancy induced porous boron nitride monolayers (BN:VB) as multifunctional materials, anodes for MIBs and H2 storage…

Materials Science · Physics 2026-05-06 Wadha Alfalasi , Wael Othman , Tanveer Hussain , Nacir Tit

We fabricate nanolayer alumina capacitor and apply high electric fields, close to 1 GV/m, to inject charges in the dielectric. Asymmetric charge distributions have been achieved due to the selectivity of the quantum tunneling process.…

Mesoscale and Nanoscale Physics · Physics 2021-02-01 Eduard Ilin , Irina Burkova , Eugene V. Colla , Michael Pak , Alexey Bezryadin