Related papers: Complete wetting near an edge of a rectangular-sha…
We study adsorption of liquid at a one-dimensional substrate composed of a single chemical inhomogeneity of width $2L$ placed on an otherwise homogeneous, planar, solid surface. The excess point free energy $\eta (L,T)$ associated with the…
Depletion of the liquid density near a solid surface with a weak long-range fluid-surface interaction was studied by computer simulations of the liquid-vapor coexistence of a LJ fluid confined in slitlike pores. In a wide temperature range…
Based on the thermodynamic variation to the free energy functional, we propose a sharp-interface model for simulating solid-state dewetting of thin films on rigid curved substrates in two dimensions. This model describes the interface…
We consider capillary condensation transitions occurring in open slits of width $L$ and finite height $H$ immersed in a reservoir of vapour. In this case the pressure at which condensation occurs is closer to saturation compared to that…
Wetting transitions have been predicted and observed to occur for various combinations of fluids and surfaces. This paper describes the origin of such transitions, for liquid films on solid surfaces, in terms of the gas-surface interaction…
Complete wetting is a universal phenomenon associated with interfaces separating coexisting phases. For example, in the pure gluon theory, at $T_c$ an interface separating two distinct high-temperature deconfined phases splits into two…
We consider an Ising model confined in an $L \times \infty$ geometry with identical surface fields at the boundaries. According to the Kelvin equation the bulk coexistence field scales as 1/L for large L; thermodynamics and scaling…
Dissociative adsorption onto a surface introduces dynamic correlations between neighboring sites not found in non-dissociative absorption. We study surface coverage dynamics where reversible dissociative adsorption of dimers occurs on a…
Using the self-consistent Hartree-Fock approximation for spinless electrons at zero temperature, we study tunneling of the interacting electron gas through a single delta-barrier in a finite one-dimensional (1D) wire connected to contacts.…
We use a simple generic model to study the desorption of atoms from a solid surface in contact with a liquid, by using a combination of Monte Carlo and molecular dynamics simulations. The behavior of the system depends on two parameters:…
We consider a simple fluid confined between two parallel walls (substrates), separated by a distance L. The walls exert competing surface fields so that one wall is attractive and may be completely wet by liquid (it is solvophilic) while…
In this paper, we study an interaction problem between an elastic plate and a compressible viscous fluid located between the rigid bottom $z=0$ and the plate. First, by utilizing the vertical fluid dissipation, we show that $\ln\eta(t) \in…
The wetting of solid surfaces by fluids is a problem of great practical importance that has been extensively studied over the years. Most often, the experimental work has involved measurements of the contact angle made by a liquid on the…
We present a simplified density functional theory (DFT) method to com- pute vertical electron and hole attachment energies to frontier orbitals of molecules absorbed on insulating films supported by a metal substrate. The adsorbate and the…
Using an interface displacement model derived from a microscopic density functional theory we investigate thin liquidlike wetting layers adsorbed on flat substrates with an embedded chemical heterogeneity forming a stripe. For a wide range…
We use density functional theory (DFT) with the generalized gradient approximation (GGA) and our first-principles extrapolation method for accurate chemisorption energies {[Mason {\em et al.}, Phys. Rev. B {\bf 69}, 161401R (2004)]} to…
We propose a physical picture based on the wormhole effect of the path-integral formulation to explain the mechanism of entanglement spectrum (ES), such that, our picture not only explains the topological state with bulk-edge correspondence…
We report an investigation of the suitability of quantum embedding for modeling the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride…
An accurate prediction of the surface potential at the air-water interface is critical to calculating ion hydration free energies and electrochemical half-cell potentials. Using Density Functional Theory (DFT), model interfacial…
We investigate the solvation of a hard spherical cavity, of radius $R$, immersed in a fluid for which the interparticle forces are short ranged. For thermodynamic states lying close to the liquid binodal, where the chemical potential…