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Nanoporous materials are a promising platform for thermoelectrics in that they offer high thermal conductivity tunability while preserving good electrical properties, a crucial requirement for high- effciency thermal energy conversion.…

Materials Science · Physics 2017-09-20 Giuseppe Romano , Jeffrey C. Grossman

Boundary-engineering in nanostructures has the potential to dramatically impact the development of materials for high-efficiency conversion of thermal energy directly into electricity. In particular, nanostructuring of semiconductors can…

Materials Science · Physics 2016-10-04 Giuseppe Romano , Alexie M. Kolpak

Achieving low thermal conductivity and good electrical properties is a crucial condition for thermal energy harvesting materials. Nanostructuring offers a very powerful tool to address both requirements: in nanostructured materials,…

Mesoscale and Nanoscale Physics · Physics 2018-09-14 Giuseppe Romano , Jesús Carrete , Alexie M. Kolpak , David Broido

Nanostructured materials exhibit low thermal conductivity because of the additional scattering due to phonon-boundary interactions. As these interactions are highly sensitive to the mean free path (MFP) of a given phonon mode, MFP…

Materials Science · Physics 2016-01-13 Giuseppe Romano , Keivan Esfarjani , David A. Strubbe , David Broido , Alexie M. Kolpak

We develop a computational framework, based on the Boltzmann transport equation, with the ability to compute the thermal transport in nanostructured materials of any geometry using as the only input the bulk thermal conductivity…

Mesoscale and Nanoscale Physics · Physics 2014-10-20 Giuseppe Romano , Jeffrey C. Grossman

While thermal anisotropicity is a desirable materials property for many applications, including transverse thermoelectrics and thermal management in electronic devices, it remains elusive in practical natural compounds. In this work, we…

Materials Science · Physics 2017-04-05 Giuseppe Romano , Alexie M. Kolpak

Introducing hierarchical disorder from multiple defects into materials through nanostructuring is one of the most promising directions to achieve extremely low thermal conductivities and thus improve thermoelectric performance. The success…

Materials Science · Physics 2019-09-16 Laura de Sousa Oliveira , Vassilios Vargiamidis , Neophytos Neophytou

Nanoporous materials are of broad interest for various applications, in particular advanced thermoelectric materials. The introduction of nanoscale porosity, even at modest levels, has been known to drastically reduce a materials thermal…

Mesoscale and Nanoscale Physics · Physics 2019-07-31 Laura de Sousa Oliveira , Neophytos Neophytou

In nanostructures phonon transport behaviour is distinctly different to transport in bulk materials such that materials with ultra low thermal conductivities and enhanced thermoelectric performance can be realized. Low thermal…

Materials Science · Physics 2019-03-01 Dhritiman Chakraborty , Samuel Foster , Neophytos Neophytou

This paper studies thermal transport in nanoporous silicon with a significant specific surface area. First, the equilibrium molecular dynamics approach was used to obtain the dependence of thermal conductivity on a specific surface area.…

Mesoscale and Nanoscale Physics · Physics 2023-05-15 Mykola Isaiev , Yuliia Mankovska , Vasyl Kuryliuk , David Lacroix

Nanostructured materials enable high thermal transport tunability, holding promises for thermal management and heat harvesting applications. Predicting the effect that nanostructuring has on thermal conductivity requires models, such as the…

Materials Science · Physics 2021-10-19 S. Aria Hosseini , Sarah Khanniche , P. Alex Greaney , Giuseppe Romano

Hierarchical material nanostructuring is considered to be a very promising direction for high performance thermoelectric materials. In this work we investigate thermal transport in hierarchically nanostructured silicon. We consider the…

Mesoscale and Nanoscale Physics · Physics 2018-10-17 Dhritiman Chakraborty , Samuel Foster , Neophytos Neophytou

Porous materials provide a large surface to volume ratio, thereby providing a knob to alter fundamental properties in unprecedented ways. In thermal transport, porous nanomaterials can reduce thermal conductivity by not only enhancing…

Predicting nanoscale thermal transport in dielectrics requires models, such as the Boltzmann transport equation (BTE), that account for phonon boundary scattering in structures with complex geometries. Although the BTE has been validated…

Materials Science · Physics 2023-08-03 S. Aria Hosseini , Alex Greaney , Giuseppe Romano

Tailoring thermal properties with nanostructured materials can be of vital importance for many applications. Generally classical phonon size effects are employed to reduce the thermal conductivity, where strong phonon scattering by…

Applied Physics · Physics 2019-10-14 Yue Xiao , Qiyu Chen , Dengke Ma , Nuo Yang , Qing Hao

Nanostructured semiconducting alloys obtain ultra-low thermal conductivity as a result of the scattering of phonons with a wide range of mean-free-paths (MFPs). In these materials, long-MFP phonons are scattered at the nanoscale boundaries…

Engineering materials to include nanoscale porosity or other nanoscale structures has become a well-established strategy for enhancing the thermoelectric performance of dielectrics. However, the approach is only considered beneficial for…

Materials Science · Physics 2021-10-14 Hosseini , S. Aria , Romano , Giuseppe , Greaney , P. Alex

First-principles calculations of thermal transport in homogeneous materials have reached remarkable predicting power. Modeling deterministically phonon transport in nanostructures, however, poses novel challenges; notably, it entails…

Materials Science · Physics 2021-06-08 Giuseppe Romano

We review experimental and theoretical results on thermal transport in semiconductor nanostructures (multilayer thin films, core/shell and segmented nanowires), single- and few-layer graphene, hexagonal boron nitride, molybdenum disulfide…

Mesoscale and Nanoscale Physics · Physics 2018-06-13 Alexandr I. Cocemasov , Calina I. Isacova , Denis L. Nika

A comprehensive rational thermal material design paradigm requires the ability to reduce and enhance the thermal conductivities of nanomaterials. In contrast to the existing ability to reduce the thermal conductivity, methods that allow to…

Mesoscale and Nanoscale Physics · Physics 2017-10-09 Abhinav Malhotra , Kartik Kothari , Martin Maldovan
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