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We study both the classical and quantum rotational dynamics of an asymmetric top molecule, controlled through three orthogonal electric fields that interact with its dipole moment. The main difficulties in studying the controllability of…

Mathematical Physics · Physics 2021-10-01 Eugenio Pozzoli

The two-dimensional electron-nuclear Schr\"odinger equation using soft-core Coulomb potentials has been a cornerstone for modeling and predicting the behavior of one-active-electron diatomic molecules, particularly for processes where both…

Chemical Physics · Physics 2020-07-01 Bo Y. Chang , Seokmin Shin , Vladimir S. Malinovsky , Ignacio R. Sola

We prove the finite-time collapse of a system of N classical fields, which are described by N coupled nonlinear Schrodinger equations. We derive the conditions under which all of the fields experiences this finite-time collapse. Finally,…

Other Condensed Matter · Physics 2009-11-11 D. C. Roberts , A. C. Newell

In the first days of quantum mechanics Dirac pointed out an analogy between the time-dependent coefficients of an expansion of the Schr\"odinger equation and the classical position and momentum variables solving Hamilton's equations. Here…

Quantum Physics · Physics 2012-05-18 J. S. Briggs , A. Eisfeld

The time-dependent variational principle using generalized Gaussian trial functions yields a finite dimensional approximation to the full quantum dynamics and is used in many disciplines. It is shown how these 'semi-quantum' dynamics may be…

chao-dyn · Physics 2009-10-22 Arjendu K. Pattanayak , William C. Schieve

In this and companion papers, we show that quantum field theories with gauge symmetries permit a broader class of classical dynamics than typically assumed. In this article, we show that the quantization of electromagnetism permits the…

High Energy Physics - Theory · Physics 2023-07-19 David E. Kaplan , Tom Melia , Surjeet Rajendran

We derive a "classical-quantum" approximation scheme for a broad class of bipartite quantum systems from fully quantum dynamics. In this approximation, one subsystem evolves via classical equations of motion with quantum corrections, and…

Quantum Physics · Physics 2023-06-05 Viqar Husain , Irfan Javed , Sanjeev S. Seahra , Nomaan X

In this article we study the nature of time in Mechanics. The fundamental principle, according to which a mechanical system evolves governed by a second order differential equation, implies the existence of an absolute time-duration in the…

Mathematical Physics · Physics 2018-09-21 J. Muñoz-Díaz , R. J. Alonso-Blanco

The formalism of generalized Wigner transformations developped in a previous paper, is applied to kinetic equations of the Lindblad type for quantum harmonic oscillator models. It is first applied to an oscillator coupled to an equilibrium…

Quantum Physics · Physics 2007-05-23 C. Tzanakis , A. P. Grecos , P. Hatjimanolaki

A quantization of field theory based on the DeDonder-Weyl covariant Hamiltonian formulation is discussed. A hypercomplex extension of quantum mechanics, in which the space-time Clifford algebra replaces that of the complex numbers, appears…

High Energy Physics - Theory · Physics 2009-10-31 I. V. Kanatchikov

Far out-of-equilibrium many-body quantum dynamics in isolated systems necessarily generate interferences beyond an Ehrenfest time scale, where quantum and classical expectation values diverge. Of great recent interest is the role these…

Quantum Physics · Physics 2018-06-20 Steven Tomsovic , Peter Schlagheck , Denis Ullmo , Juan Diego Urbina , Klaus Richter

We study the {\it quasi-classical limit} of a quantum system composed of finitely many non-relativistic particles coupled to a quantized field in Nelson-type models. We prove that, as the field becomes classical and the corresponding…

Mathematical Physics · Physics 2018-08-08 Michele Correggi , Marco Falconi

This work explores the intersection of quantum mechanics and curved spacetime by employing the Wigner formalism to investigate quantum systems in the vicinity of black holes. Specifically, we study the quantum dynamics of a probe particle…

General Relativity and Quantum Cosmology · Physics 2026-05-21 David Garcia-Garcia , Jose A. R. Cembranos

Quantum and classical systems evolving under the same formal Hamiltonian $H$ may dramatically differ after the Ehrenfest timescale $t_E \sim \log(\hbar^{-1})$, even as $\hbar \to 0$. Coupling the system to a Markovian environment results in…

Mathematical Physics · Physics 2025-05-20 Felipe Hernández , Daniel Ranard , C. Jess Riedel

The main ideas behind a research plan to use the Wigner formulation as a bridge between classical and quantum probabilistic algorithms are presented, focusing on a particular case: the Quantum analog of Stochastic Gradient Descent in its…

Quantum Physics · Physics 2025-10-31 Jose A. Morales Escalante

We developed a general theoretical approach and a user-ready computer code that permit to study the dynamics of collisional energy transfer and ro-vibrational energy exchange in complex molecule-molecule collisions. The method is a mixture…

Chemical Physics · Physics 2024-02-06 Carolin Joy , Bikramaditya Mandal , Dulat Bostan , Marie-Lise Dubernet , Dmitri Babikov

A discussion is given of the quantisation of a physical system with finite degrees of freedom subject to a Hamiltonian constraint by treating time as a constrained classical variable interacting with an unconstrained quantum state. This…

General Relativity and Quantum Cosmology · Physics 2009-11-10 Charles Wang

We discuss the evolution of purity in mixed quantum/classical approaches to electronic nonadiabatic dynamics in the context of the Ehrenfest model. As it is impossible to exactly determine initial conditions for a realistic system, we…

Chemical Physics · Physics 2012-09-07 J. L. Alonso , J. Clemente-Gallardo , J. C. Cuchí , P. Echenique , F. Falceto

We consider the problem of numerically solving the Schr\"odinger equation with a potential that is quasi periodic in space and time. We introduce a numerical scheme based on a newly developed multi-time scale and averaging technique. We…

Chaotic Dynamics · Physics 2016-07-26 Tal Kachman , Shmuel Fishman , Avy Soffer

The amplitude-phase formulation of the Schr\"{o}dinger equation is investigated within the context of uncoupled Ermakov systems, whereby the amplitude function is given by the auxiliary nonlinear equation. The classical limit of the…

Quantum Physics · Physics 2009-11-07 A. Matzkin