Related papers: Semiclassical quantization of nonadiabatic systems…
In this work, we investigate the semiclassical limit of a simple bosonic quantum many-body system exhibiting both integrable and chaotic behavior. A classical Hamiltonian is derived using coherent states. The transition from regularity to…
Fewest-switches surface hopping is studied in the context of quantum-classical Liouville dynamics. Both approaches are mixed quantum-classical theories that provide a way to describe and simulate the nonadiabatic quantum dynamics of…
A new operator based condition for distinguishing classical from non-classical states of quantised radiation is developed. It exploits the fact that the normal ordering rule of correspondence to go from classical to quantum dynamical…
The transport of ultra-cold atoms in magneto-optical potentials provides a clean setting in which to investigate the distinct predictions of classical versus quantum dynamics for a system with coupled degrees of freedom. In this system,…
Quantum computation is an attractive front for many problems that are intractable for computers today. One such problem is nonadiabatic quantum molecular dynamics, where quantized internal states coupling to parameterized modes result in a…
We investigate quantum dynamics for an ion confined within an oscillating quadrupole field, starting from two well known and elegant approaches. It is established that the Hamilton equations of motion, in both Schr\"{o}dinger and Heisenberg…
Quantum polarization is investigated by means of a trajectory picture based on the Bohmian formulation of quantum mechanics. Relevant examples of classical-like two-mode field states are thus examined, namely Glauber and SU(2) coherent…
Homoclinic and heteroclinic orbits provide a skeleton of the full dynamics of a chaotic dynamical system and are the foundation of semiclassical sums for quantum wave packet, coherent state, and transport quantities. Here, the homoclinic…
We sketch the semiclassical core of a proof of the so-called Bohigas-Giannoni-Schmit conjecture: A dynamical system with full classical chaos has a quantum energy spectrum with universal fluctuations on the scale of the mean level spacing.…
The new phenomenon of semiquantum chaos is analyzed in a classically regular double-well oscillator model. Here it arises from a doubling of the number of effectively classical degrees of freedom, which are nonlinearly coupled in a Gaussian…
Gutzwiller's trace formula allows interpreting the density of states of a classically chaotic quantum system in terms of classical periodic orbits. It diverges when periodic orbits undergo bifurcations, and must be replaced with a uniform…
The article contains an overview of authors achievements in development of alternative quantum-chemical approaches oriented towards revival of the classical tradition of qualitative chemical thinking instead of obtaining numerical results.…
This paper provides the first ab-initio on-the-fly example of using the Quasi-Diabatic (QD) scheme for non-adiabatic simulations with diabatic dynamics approaches. The QD scheme provides a seamless interface between diabatic quantum…
We outline formal and physical similarities between the quantum dynamics of open systems, and the mesoscopic description of classical systems affected by weak noise. The main tool of our interest is the dissipative Wigner equation, that,…
The reliable quantification of nonclassicality in quantum states under realistic decoherence remains a central challenge in advancing quantum technologies. Conventional quantifiers such as Wigner negativity, Mandel's $Q$-parameter,…
We present a detailed derivation and numerical tests of a new mixed quantum-classical scheme to deal with non-adiabatic processes. The method is presented as the zero-th order approximation to the exact coupled dynamics of electrons and…
The dynamics of hybrid systems -- i.e. ones in which classical and quantum degrees of freedom co-exist and interact -- feature both diffusion in the classical sector and decoherence in the quantum state. In this article, we will consider…
A new form of quasiclassical space-time dynamics for constrained systems reveals how quantum effects can be derived systematically from canonical quantization of gravitational systems. These quasiclassical methods lead to additional fields,…
Semiclassical descriptions of a few-level system coupled to an electromagnetic field mode reduce the field to a time-dependent driving term. Although such methods are widely used, the underlying quantum character of the field generates…
We present a mixed quantum-classical approach to strong-field ionization - a semiclassical two-step model with quantum input. In this model the initial conditions for classical trajectories that simulate electron wave packet after…