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Ultrafast processes in matter can be captured and even controlled by using sequences of few-cycle optical pulses, which need to be well characterized, both in amplitude and phase. The same degree of control has not yet been achieved for…

We predict a significant delay of two-electron photoemission from the helium atom after absorption of an attosecond XUV pulse. We establish this delay by solving the time dependent Schr\"odinger equation and by subsequent tracing the…

Atomic Physics · Physics 2026-03-03 A. S. Kheifets , I. A. Ivanov , Igor. Bray

Attosecond streaking, as a measurement technique, was originally conceived as a means to characterize attosecond light pulses, which is a good approximation if the relevant transition matrix elements are approximately constant within the…

Atomic Physics · Physics 2015-05-19 Vladislav S. Yakovlev , Justin Gagnon , Nicholas Karpowicz , Ferenc Krausz

We describe in detail how attosecond delays in laser-assisted photoionization can be computed using perturbation theory based on two-photon matrix elements. Special emphasis is laid on above-threshold ionization, where the electron…

Atomic Physics · Physics 2015-06-19 J. M. Dahlström , E. Lindroth

The measurement of the tunneling time in attosecond experiments, termed attoclock, triggered a hot debate about the tunneling time, the role of time in quantum mechanics, where the interaction with the laser pulse involves two regimes of a…

Quantum Physics · Physics 2023-03-06 Ossama Kullie , Igor Ivanov

The electronic structure of atomic quantum systems and their dynamical interaction with light is reflected in transition dipole matrix elements coupling the system's energy eigenstates. In this work, we measure phase shifts of the…

We report on the observation, characterization, and control of the electron dynamics in ionized argon atoms. We utilized an intense mid-infrared (MIR) pulse to create a coherent superposition of the spin-orbit split ground state of the ion.…

We present an interferometric pump-probe technique for the characterization of attosecond electron wave packets (WPs) that uses a free WP as a reference to measure a bound WP. We demonstrate our method by exciting helium atoms using an…

Attosecond streaking of atomic photoemission holds the promise to provide unprecedented information on the release time of the photoelectron. We show that attosecond streaking phase shifts indeed contain timing (or spectral phase)…

We theoretically study time-resolved photoemission in atoms as probed by attosecond streaking. We review recent advances in the study of the photoelectric effect in the time domain and show that the experimentally accessible time shifts can…

Atomic Physics · Physics 2015-03-06 Stefan Nagele , Renate Pazourek , Michael Wais , Georg Wachter , Joachim Burgdörfer

Based on numerical solutions of the time-dependent Schr\"odinger equation for either one or two active electrons, we propose a method for observing instantaneous level shifts in an oscillating strong infrared (IR) field in time, using a…

Atomic Physics · Physics 2015-05-28 Feng He , Camilo Ruiz , Andreas Becker , Uwe Thumm

Natively, atomic and molecular processes develop in a sub-femtosecond time scale. In order to, for instance, track and capture the electron motion in that scale we need suitable `probes'. Attosecond pulses configure the most appropriate…

Linear off-resonant X-ray Raman techniques are capable of detecting the ultrafast electronic coherences generated when a photoexcited wave packet passes through a conical intersection. A hybrid femtosecond or attosecond probe pulse is…

Chemical Physics · Physics 2022-11-07 Lorenzo Restaino , Deependra Jadoun , Markus Kowalewski

For the submillimeter band observations, we have been routinely adopting the calibration cycle time of 20-30 minutes, which is the same as any typical centimeter and millimeter band observations. This cycle time, largely corrects only the…

Astrophysics · Physics 2007-06-04 Dharam Vir Lal , Satoki Matsushita , Jeremy Lim

The blooming of attosecond science (1 as = $10^{-18}$ s) has raised the need to exquisitely control the delay between two ultrashort light pulses, one of them being intense and in the visible spectral range, while the second is weak and in…

Attosecond transient absorption spectroscopy (ATAS) has emerged as a powerful technique within the field of attosecond science, combining extremely high temporal and excellent spectral resolution. So far, ATAS has been implemented in…

Attosecond photoelectron spectroscopy is often performed with interferometric experimental setups that require outstanding stability. We demonstrate and characterize in detail an actively stabilized, versatile, high spectral resolution…

We present fully ab initio simulations of attosecond streaking for ionization of helium accompanied by shake-up of the second electron. This process represents a prototypical case for strongly correlated electron dynamics on the attosecond…

Atomic Physics · Physics 2013-05-24 Renate Pazourek , Stefan Nagele , Johannes Feist , Joachim Burgdörfer

We report attosecond-scale probing of the laser-induced dynamics in molecules. We apply the method of high-harmonic spectroscopy, where laser-driven recolliding electrons on various trajec- tories record the motion of their parent ion.…

If matter absorbs a photon of sufficient energy it emits an electron. The question of the duration of the emission process has intrigued scientists for decades. With the advent of attosecond metrology, experiments addressing such ultrashort…