Related papers: Intermediate Mirrors to Reach Theoretical Efficien…
Photovoltaic materials are recognized for their potential as sustainable energy sources that enable the conversion between light and electrical energy. However, solar cells have been unable to surpass the theoretical limit of 32%, known as…
A coupled optoelectronic model was implemented along with the differential evolution algorithm to assess the efficacy of grading the bandgap of the CZTSSe layer for enhancing the power conversion efficiency of thin-film CZTSSe solar cells.…
The increase of cell efficiency resulting from using a diffraction grating as a back reflector is investigated. An enhancement coefficient is introduced as a figure of merit that accounts for the ability of the rear grating to increase the…
The Shockley-Queisser limit is one of the most fundamental results in the field of photovoltaics. Based on the principle of detailed balance, it defines an upper limit for a single junction solar cell that uses an absorber material with a…
Improving the conversion efficiency of solar energy to electricity is most important to mankind. For single-junction photovoltaic solar-cells, the Shockley-Queisser thermodynamic efficiency limit is extensively due to the heat dissipation,…
The power conversion efficiency of an ultrathin CIGS solar cell was maximized using a coupled optoelectronic model to determine the optimal bandgap grading of the nonhomogeneous CIGS layer in the thickness direction. The bandgap of the CIGS…
Absorbed sunlight in a solar cell produces electrons and holes. But, at the open circuit condition, the carriers have no place to go. They build up in density and, ideally, they emit external fluorescence that exactly balances the incoming…
Intermediate band solar cells (IBSCs) pursue the increase in efficiency by absorbing below-bandgap energy photons while preserving the output voltage. Experimental IBSCs based on quantum dots have already demonstrated that both…
We derive the photovoltaic conversion efficiency limit for two-terminal tandem solar cells with a perovskite top cell and silicon bottom cell with an embedded spectrum splitter. For large-bandgap top-cells a spectrum splitter strongly…
The ability to absorb light is indispensable for high efficient solar power generation. This places conflicting requirements on the structure of a solar cell: On one hand, it needs to have thick active layers to absorb more of the available…
Intermediate Band Solar Cell is an advanced concept for solar energy conversion in which two low-energy photons can promote an electron to the conduction band through a so-called intermediate band. To limit recombination and preserve the…
The spin-split indirect bandgap in hybrid-halide perovskites provides a momentum-space realisation of a photon-ratchet intermediate band. Excited electrons thermalise to recombination-protected Rashba pockets offset in momentum space,…
Thermophotovotaics convert thermal radiation from local heat sources to electricity. A new breakthrough in creating highly efficient thin-film solar cells can potentially enable thermophotovoltaic systems with unprecedented high efficiency.…
The theoretical maximum efficiency of a solar cell is typically characterized by a detailed balance of optical absorption and emission for a semiconductor in the limit of unity radiative efficiency and an ideal step-function response for…
Bifacial tandem cells promise to reduce three fundamental losses (above-bandgap, below bandgap, and the uncollected light between panels) inherent in classical single junction PV systems. The successive filtering of light through the…
We employ a detailed balance approach to model a single-junction solar cell with a realistic narrow-band, non-unity-quantum-yield upconverter. As upconverter bandwidths are increased from 0 to 0.5 eV, maximum cell efficiencies increase from…
Thermophotovoltaic (TPV) energy conversion efficiency has recently surpassed 30%. The key behind such high efficiency is the inclusion of a highly efficient mirror in the rear of the TPV cell that turns back to the thermal emitter the…
A new strategy for eliminating photocurrent losses due to the metal contacts on the front of a solar cell was proposed, simulated, and tested. By placing triangular cross-section lines of low refractive index on top of the contacts,…
The Shockley-Queisser (SQ) limit provides a convenient metric for predicting light-to-electricity conversion efficiency of a solar cell based on the band gap of the light-absorbing layer. In reality, few materials approach this radiative…
The fundamental efficiency limit of a single bandgap solar cell is about 31% at one sun with a bandgap of about Eg = 1.35 eV (1), determined by the trade-off of maximising current with a smaller bandgap and voltage with a larger bandgap.…