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The efficiencies of solar cells based on kesterite Cu$_2$ZnSnS$_4$ (CZTS) and Cu$_2$ZnSnSe$_4$ (CZTSe) are limited by a low open-circuit voltage due to high rates of non-radiative electron-hole recombination. To probe the origin of this…

Materials Science · Physics 2018-05-11 Bartomeu Monserrat , Ji-Sang Park , Sunghyun Kim , Aron Walsh

Flexible Cu2ZnSn(S, Se)4 (CZTSSe) solar cells take the advantages of environmental friendliness, low cost, and multi-scenario applications, and have drawn extensive attention in recent years. Compared with rigid devices, the lack of alkali…

The limiting factor preventing kesterite (CZTSSe) thin film solar cell performance further improvement is the large open-circuit voltage deficit (Voc,def) issue, which is 0.345V for the current world record device with an efficiency of…

Cu2ZnSnS(e)4 (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu2ZnSn(S,Se)4 (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se2…

Applied Physics · Physics 2018-03-14 Shoushuai Gao , Zhenwu Jiang , Li Wu , Jianping Ao , Yu Zeng , Yun Sun , Yi Zhang

In this work, first principle calculations of Cu$_2$ZnSnS$_4$ (CZTS), Cu$_2$ZnGeS$_4$ (CZGS) and Cu$_2$ZnSiS$_4$ (CZSS) are performed to highlight the impact of the cationic substitution on the structural, electronic and optical properties…

Applied Physics · Physics 2022-02-22 Thomas Ratz , Jean-Yves Raty , Guy Brammertz , Bart Vermang , Ngoc Duy Nguyen

Atomic disorder, a widespread problem in compound crystalline materials, is a imperative affecting the performance of multi-chalcogenide Cu2ZnSn(S, Se)4 (CZTSSe) photovoltaic device known for its low cost and environmental friendliness.…

Kesterite is a leading candidate among inorganic thin-film photovoltaic technologies, offering sustainable and environmentally friendly solutions without reliance on critical raw materials. This study investigates the performance of…

The open circuit voltage Voc and the corresponding charge carrier density were measured in dependence of temperature and illumination intensity by current-voltage and charge extraction measurements for P3HT:PCBM and P3HT:bisPCBM solar…

Materials Science · Physics 2011-10-05 Daniel Rauh , Alexander Wagenpfahl , Carsten Deibel , Vladimir Dyakonov

We report a charge based model to establish the analytical equation, describing the nature of capacitance-voltage ($C$-$V$) characteristics of organic solar cells under dark condition (or organic diodes) over a wide range of voltage,…

Applied Physics · Physics 2018-09-25 Prashanth Kumar Manda , Soumya Dutta

Analytic expressions are presented for the dark current-voltage relation $J(V)$ of a $pn^+$ junction with positively charged columnar grain boundaries with high defect density. These expressions apply to non-depleted grains with…

Materials Science · Physics 2016-12-20 Benoit Gaury , Paul M. Haney

Among the parameters determining the efficiency of an organic solar cell, the open-circuit voltage ($V_\text{OC}$) is the one with most room for improvement. Existing models for the description of $V_\text{OC}$ assume that photogenerated…

Applied Physics · Physics 2021-10-07 Tanvi Upreti , Sebastian Wilken , Huotian Zhang , Martijn Kemerink

Flexible photovoltaics with a lightweight and adaptable nature that allows for deployment on curved surfaces and in building facades have always been a goal vigorously pursued by researchers in thin-film solar cell technology. The recent…

We simulated photovoltaic characteristics of single heterojunction solar cell with Cu2ZnSnS4 and Cu2ZnSnSe4 absorber layer numerically using one dimensional solar cell capacitance simulator (SCAPS-1D). n-CdS/ZnO double buffer layer is used…

Applied Physics · Physics 2018-01-26 Goutam K Gupta , Ambesh Dixit

Despite the remarkable progress in emerging solar cell technologies such as hybrid organic-inorganic perovskites, there are still significant limitations related to the stability of the devices and their non-ideal electrical behavior under…

In organic bulk heterojunction solar cells, the open circuit voltage ($V_\mathrm{oc}$) suffers from an ultra-high loss at low temperatures. In this work we investigate the origin of the loss through calculating the $V_\mathrm{oc}-T$ plots…

Materials Science · Physics 2017-06-09 Wenchao Yang , Yongsong Luo , Pengfei Guo , Haibin Sun , Yao Yao

Thin-film solar cells based on kesterite (Cu2ZnSnSe4) material are a promising alternative for photovoltaic devices due to their composition consisting of earth abundant elements, ease of production at a relatively low temperatures and…

The current density-voltage characteristic (JV) is a critical tool for understanding the behaviour of solar cells. In this article, we present an overview of the key aspects of JV analysis and introduce a user-friendly flowchart that…

Materials Science · Physics 2024-04-17 Albert These , L. Jan Anton Koster , Christoph J. Brabec , Vincent M. Le Corre

We present evidence that band gap narrowing at the heterointerface may be a major cause of the large open circuit voltage deficit of Cu$_2$ZnSnS$_4$/CdS solar cells. Band gap narrowing is caused by surface states that extend the…

Mesoscale and Nanoscale Physics · Physics 2017-04-05 Andrea Crovetto , Mattias Palsgaard , Tue Gunst , Troels Markussen , Kurt Stokbro , Mads Brandbyge , Ole Hansen

Capacitance measurements as a function of voltage, frequency and temperature are useful tools to identify fundamental parameters that affect solar cell operation. Techniques such as capacitance-voltage (CV), Mott-Schottky analysis and…

Applied Physics · Physics 2021-12-23 Sandheep Ravishankar , Zhifa Liu , Uwe Rau , Thomas Kirchartz

The open circuit voltage to the state of charge (OCVSOC) characteristic is crucial for battery management systems. Using the OCV-SOC curve, the SOC and the battery capacity can be estimated in real-time. Accurate SOC and capacity…

Systems and Control · Electrical Eng. & Systems 2023-06-30 Prarthana Pillai , James Nguyen , Balakumar Balasingam
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