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We study by molecular dynamics simulations the thermodynamics of an anomalous fluid confined in a slit pore with one wall structured and attractive and another unstructured and repulsive. We find that the phase diagram of the homogeneous…

Statistical Mechanics · Physics 2016-12-21 Fabio Leoni , Giancarlo Franzese

We use Molecular Dynamics simulations to study how the nanopore and the fluid structures affects the dynamic, thermodynamic and structural properties of a confined anomalous fluid. The fluid is modeled using an effective pair potential…

Soft Condensed Matter · Physics 2015-06-23 Leandro B. Krott , José Rafael Bordin , Ney Marçal Barraz , Marcia C. Barbosa

Using molecular dynamic simulations we study a waterlike model confined between two fixed hydrophobic plates. The system is tested for density, diffusion and structural anomalous behavior and compared with the bulk results. Within the range…

Chemical Physics · Physics 2013-03-06 Leandro Batirolla Krott , Marcia Cristina Bernardes Barbosa

We explore by molecular dynamic simulations the thermodynamical behavior of an anomalous fluid confined inside rigid and flexible nanopores. The fluid is modeled by a two length scale potential. In the bulk this system exhibits the density…

Soft Condensed Matter · Physics 2014-02-05 Jose Rafael Bordin , Leandro B. Krott , Marcia C. Barbosa

Through Monte Carlo simulations and the Associating Lattice Gas Model, the phases of a two-dimensional fluid under hydrophilic confinement are evaluated. The model, in its unconfined version, reproduces the anomalous behavior of water…

We study how confining the equilibrium hard-sphere fluid to restrictive one- and two-dimensional channels with smooth interacting walls modifies its structure, dynamics, and entropy using molecular dynamics and transition-matrix Monte Carlo…

Statistical Mechanics · Physics 2007-05-23 Jeetain Mittal , Jeffrey R. Errington , Thomas M. Truskett

Molecular dynamic simulations were employed to study a water-like model confined between hydrophobic and hydrophilic plates. The phase behavior of this system is obtained for different distances between the plates and particle-plate…

Soft Condensed Matter · Physics 2015-06-17 Leandro B. Krott , Marcia C. Barbosa

The wall cooling effect on the spectra and structures of thermodynamic variables are investigated in hypersonic turbulent boundary layers. The density and temperature can be divided into the acoustic and entropic modes based on the…

Fluid Dynamics · Physics 2023-05-19 Dehao Xu , Jianchun Wang , Shiyi Chen

We consider a model fluid with long-ranged, dispersion interparticle potentials confined between competing parallel walls. One wall is solvophilic and would be completely wet at bulk liquid-gas coexistence while the other is solvophobic and…

Soft Condensed Matter · Physics 2015-06-05 M. C. Stewart , R. Evans

The behavior of a confined spherical symmetric anomalous fluid under high external pressure was studied with Molecular Dynamics simulations. The fluid is modeled by a ore-softened potential with two characteristic length scales, which in…

Soft Condensed Matter · Physics 2014-08-21 José Rafael Bordin , Leandro B. Krott , Marcia C. B. Barbosa

Compressing or cooling a fluid typically enhances its static interparticle correlations. However, there are notable exceptions. Isothermal compression can reduce the translational order of fluids that exhibit anomalous waterlike trends in…

Soft Condensed Matter · Physics 2008-04-11 William P. Krekelberg , Jeetain Mittal , Venkat Ganesan , Thomas M. Truskett

We perform molecular dynamics simulations of 512 water-like molecules that interact via the TIP5P potential and are confined between two smooth hydrophobic plates that are separated by 1.10 nm. We find that the anomalous thermodynamic…

Soft Condensed Matter · Physics 2009-11-11 Pradeep Kumar , Sergey V. Buldyrev , Francis W. Starr , Nicolas Giovambattista , H. Eugene Stanley

Understanding heat transfer characteristics of phase change and enhancing thermal energy transport in nanoscale are of great interest in both theoretical and practical applications. In the present study, we investigated the nanoscale…

Computational Physics · Physics 2016-04-11 Li Li , Pengfei Ji , Yuwen Zhang

Using molecular dynamics simulations we study the dynamics of a water-like TIP5P model of water in hydrophilic and hydrophobic confinement. We find that in case of extreme nanocofinement such that there is only one molecular layer of water…

Soft Condensed Matter · Physics 2010-05-14 Pradeep Kumar

The mobility of water molecules confined in a silica pore is studied by computer simulation in the low hydration regime, where most of the molecules reside close to the hydrophilic substrate. A layer analysis of the single particle dynamics…

Statistical Mechanics · Physics 2009-11-10 P. Gallo , M. Rovere

The properties of liquid water are known to change drastically in confined geometries. A most interesting and intriguing phenomenon is that the diffusion of water is found to be strongly enhanced by the proximity of a hydrophobic confining…

Soft Condensed Matter · Physics 2024-12-06 Lorenzo Agosta , Kersti Hermansson , Mikhail Dzugutov

Confinement can significantly alter fluid properties, offering potential for specific technological applications. However, achieving precise control over the structural complexity of confined fluids and soft matter remains challenging, as…

Soft Condensed Matter · Physics 2024-11-20 Fabio Leoni , Erdal C. Oğuz , Giancarlo Franzese

We use grand canonical transition-matrix Monte Carlo and discontinuous molecular dynamics simulations to generate precise thermodynamic and kinetic data for the equilibrium hard-sphere fluid confined between smooth hard walls. These…

Soft Condensed Matter · Physics 2009-11-06 Jeetain Mittal , Jeffrey R. Errington , Thomas M. Truskett

Bulk water presents a large number of crystalline and amorphous ices. Hydrophobic nanoconfinement is known to affect the tendency of water to form ice and to reduce the melting temperature. However, a systematic study of the ice phases in…

Soft Condensed Matter · Physics 2011-02-15 Oriol Vilanova , Giancarlo Franzese

We report a molecular dynamics simulation of a supercooled simple monatomic glass-forming liquid. It is found that the onset of the supercooled regime results in formation of distinct domains of slow diffusion which are confined to the…

Disordered Systems and Neural Networks · Physics 2009-11-07 Mikhail Dzugutov , Sergei I. Simdyankin , Fredrik H. M. Zetterling
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